KALETA, Jiří, Zbyněk JANOUŠEK, Marek NEČAS a Ctibor MAZAL. Molecular Rods Combining o-Carborane and Bicyclo[1.1.1]pentane Cages: An Insertion of the Triple Bond Located Next to a Highly Strained Cage. Organometallics. Spojené státy americké: American Chemical Society, Washington DC, 2015, roč. 34, č. 5, s. 967-972. ISSN 0276-7333. Dostupné z: https://dx.doi.org/10.1021/acs.organomet.5b00002. |
Další formáty:
BibTeX
LaTeX
RIS
@article{1310471, author = {Kaleta, Jiří and Janoušek, Zbyněk and Nečas, Marek and Mazal, Ctibor}, article_location = {Spojené státy americké}, article_number = {5}, doi = {http://dx.doi.org/10.1021/acs.organomet.5b00002}, keywords = {KeyWords Plus:DEHYDROGENATIVE ALKYNE-INSERTION; DICOBALT OCTACARBONYL; POLYBORANE REACTIONS; IONIC LIQUIDS; ROTORS; MECHANISM; ARRAYS; DECABORANE; REDUCTION}, language = {eng}, issn = {0276-7333}, journal = {Organometallics}, title = {Molecular Rods Combining o-Carborane and Bicyclo[1.1.1]pentane Cages: An Insertion of the Triple Bond Located Next to a Highly Strained Cage}, url = {http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00002}, volume = {34}, year = {2015} }
TY - JOUR ID - 1310471 AU - Kaleta, Jiří - Janoušek, Zbyněk - Nečas, Marek - Mazal, Ctibor PY - 2015 TI - Molecular Rods Combining o-Carborane and Bicyclo[1.1.1]pentane Cages: An Insertion of the Triple Bond Located Next to a Highly Strained Cage JF - Organometallics VL - 34 IS - 5 SP - 967-972 EP - 967-972 PB - American Chemical Society, Washington DC SN - 02767333 KW - KeyWords Plus:DEHYDROGENATIVE ALKYNE-INSERTION KW - DICOBALT OCTACARBONYL KW - POLYBORANE REACTIONS KW - IONIC LIQUIDS KW - ROTORS KW - MECHANISM KW - ARRAYS KW - DECABORANE KW - REDUCTION UR - http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00002 L2 - http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00002 N2 - Octacarbonyl dicobalt and bis(dimethyl sulfide)decaborane B10H12(Me2S)2 were successfully added to 1,3-diethynylbicyclo[1.1.1]pentane in good yields. This is an interesting example of a cycloaddition reaction achieved next to the bicyclopentane cage that tends to rearrange in many other cases. It proves that both reagents attack the triple bond in a more or less concerted manner that prevents the rearrangement. Products of the latter reaction are of a particular interest because the bicyclopentane and o-carborane cages are immediately linked in their rodlike structures. The new kind of molecular rotors was thus constructed. 1H and 13C nuclear magnetic resonance spectra in solution reveal an averaged rotational symmetry of the molecules with a well-defined geometry that has been confirmed by X-ray structural analysis in several examples. ER -
KALETA, Jiří, Zbyněk JANOUŠEK, Marek NEČAS a Ctibor MAZAL. Molecular Rods Combining o-Carborane and Bicyclo[1.1.1]pentane Cages: An Insertion of the Triple Bond Located Next to a Highly Strained Cage. \textit{Organometallics}. Spojené státy americké: American Chemical Society, Washington DC, 2015, roč.~34, č.~5, s.~967-972. ISSN~0276-7333. Dostupné z: https://dx.doi.org/10.1021/acs.organomet.5b00002.
|