Feasibility of iodine determination in pellets with
Laser-Induced Breakdown Spectroscopy

a 2015

Feasibility of iodine determination in pellets with Laser-Induced Breakdown Spectroscopy

VITEŠNÍKOVÁ, Anna, Aleš HRDLIČKA, Karel NOVOTNÝ, Viktor KANICKÝ, Jozef KAISER et. al.

Základní údaje

Originální název

Feasibility of iodine determination in pellets with Laser-Induced Breakdown Spectroscopy

Autoři

VITEŠNÍKOVÁ, Anna (203 Česká republika, domácí), Aleš HRDLIČKA (203 Česká republika, garant, domácí), Karel NOVOTNÝ (203 Česká republika, domácí), Viktor KANICKÝ (203 Česká republika, domácí), Jozef KAISER (203 Česká republika), Jan NOVOTNÝ (203 Česká republika), David PROCHAZKA (203 Česká republika), Lucia SLÁDKOVÁ (703 Slovensko) a Pavel POŘÍZKA (203 Česká republika)

Vydání

8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy, 2015

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Rakousko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

stránka konference

Kód RIV

RIV/00216224:14740/15:00085382

Organizační jednotka

Středoevropský technologický institut

Klíčová slova anglicky

laser; induced; breakdown; spectroscopy; iodine; pellets; nanoparticles;

Příznaky

Mezinárodní význam

Změněno: 16. 2. 2016 15:25, doc. Mgr. Karel Novotný, Ph.D.

Anotace

V originále

The work is based on iodine detection in pressed pellets using LIBS. Generally, detection of halogens using such method has been regarded challenging1. For this study a double pulse (DP)-LIBS system was employed. It consists of a Nd: YAG 266 nm ablation laser and a Nd: YAG 1064 nm re-excitation laser, both arranged in orthogonal configuration. The mail goal was to compare different types of binders, non-conductive and conductive ones. From the first category, frequently used microcellulose and from the second one silver powder was used. We focused on the influence of the binder on sensitivity and changes in set of accessible lines of iodine. The observed iodine atomic and ionic lines fall to interval of 500-600 nm. Iodine emission was measured at LIBS of potassium iodide and potassium iodite salts mixed and pressed with a binder. The iodine content was in the range of several percents. Secondly we studied effect of nanoparticles on emission intensity enhancement. As previous studies proved2 Nanoparticle Enhanced Laser Induced Breakdown Spectroscopy (NELIBS) can increase the emission of some lines. Based on theoretical knowledge we assumed effect of a conductive binder on intensification of analytical signal at least in the presence of nanoparticles. The yielded results indicate that the intensification of the iodine signal depends not only on the nanoparticle presence but also on selected line, iodine matrix and the used binder. High excitation energies of iodine ionic lines, easy excitation of silver and different ablation rates of cellulose and silver play an important role. Careful selection of the above mentioned parameters can lead to sensitivity increase but also signal depression can occur when inappropriate conditions are applied.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

Citovat

VITEŠNÍKOVÁ, Anna, Aleš HRDLIČKA, Karel NOVOTNÝ, Viktor KANICKÝ, Jozef KAISER, Jan NOVOTNÝ, David PROCHAZKA, Lucia SLÁDKOVÁ a Pavel POŘÍZKA. Feasibility of iodine determination in pellets with Laser-Induced Breakdown Spectroscopy. In 8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy. 2015.

@proceedings{1322072,
   author = {Vitešníková, Anna and Hrdlička, Aleš and Novotný, Karel and Kanický, Viktor and Kaiser, Jozef and Novotný, Jan and Prochazka, David and Sládková, Lucia and Pořízka, Pavel},
   booktitle = {8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy},
   keywords = {laser; induced; breakdown; spectroscopy; iodine; pellets; nanoparticles;},
   language = {eng},
   title = {Feasibility of iodine determination in pellets with Laser-Induced Breakdown Spectroscopy},
   url = {http://emslibs2015.jku.at/},
   year = {2015}
}

TY  - CONF
ID  - 1322072
AU  - Vitešníková, Anna - Hrdlička, Aleš - Novotný, Karel - Kanický, Viktor - Kaiser, Jozef - Novotný, Jan - Prochazka, David - Sládková, Lucia - Pořízka, Pavel
PY  - 2015
TI  - Feasibility of iodine determination in pellets with Laser-Induced Breakdown Spectroscopy
KW  - laser
KW  - induced
KW  - breakdown
KW  - spectroscopy
KW  - iodine
KW  - pellets
KW  - nanoparticles;
UR  - http://emslibs2015.jku.at/
L2  - http://emslibs2015.jku.at/
N2  - The work is based on iodine detection in pressed pellets using LIBS. Generally, detection of halogens using such method has been regarded challenging1. For this study a double pulse (DP)-LIBS system was employed. It consists of a Nd: YAG 266 nm ablation laser and a Nd: YAG 1064 nm re-excitation laser, both arranged in orthogonal configuration. The mail goal was to compare different types of binders, non-conductive and conductive ones. From the first category, frequently used microcellulose and from the second one silver powder was used. We focused on the influence of the binder on sensitivity and changes in set of accessible lines of iodine. The observed iodine atomic and ionic lines fall to interval of 500-600 nm. Iodine emission was measured at LIBS of potassium iodide and potassium iodite salts mixed and pressed with a binder. The iodine content was in the range of several percents. Secondly we studied effect of nanoparticles on emission intensity enhancement. As previous studies proved2 Nanoparticle Enhanced Laser Induced Breakdown Spectroscopy (NELIBS) can increase the emission of some lines. Based on theoretical knowledge we assumed effect of a conductive binder on intensification of analytical signal at least in the presence of nanoparticles. The yielded results indicate that the intensification of the iodine signal depends not only on the nanoparticle presence but also on selected line, iodine matrix and the used binder. High excitation energies of iodine ionic lines, easy excitation of silver and different ablation rates of cellulose and silver play an important role. Careful selection of the above mentioned parameters can lead to sensitivity increase but also signal depression can occur when inappropriate conditions are applied.
ER  -

VITEŠNÍKOVÁ, Anna, Aleš HRDLIČKA, Karel NOVOTNÝ, Viktor KANICKÝ, Jozef KAISER, Jan NOVOTNÝ, David PROCHAZKA, Lucia SLÁDKOVÁ a Pavel POŘÍZKA. Feasibility of iodine determination in pellets with Laser-Induced Breakdown Spectroscopy. In \textit{8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy}. 2015.

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