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@proceedings{1323189,
author = {Yawer, Mirza Arfan and Havel, Václav and Šindelář, Vladimír},
booktitle = {6th French- Czech "Vltava" Chemistry Meeting, 27-28 August 2015, Brno Czech Republic},
keywords = {Bambusuril derivative, anion receptor},
title = {Synthesis and Supramoleculer properties of water soluble Bambusuril derivative},
year = {2015}
}
TY - CONF
ID - 1323189
AU - Yawer, Mirza Arfan - Havel, Václav - Šindelář, Vladimír
PY - 2015
TI - Synthesis and Supramoleculer properties of water soluble Bambusuril derivative
KW - Bambusuril derivative, anion receptor
N2 - Supramoleculer host that operates in “real life” environments are of great interest for biological and industrial chemist. Water is one of major environment in real life. Development of such a Supramoleculer host that serves as anion receptors in pure water is a challenging task for chemists.1 Previously only a few effective neutral anion receptors functioning in water are known. Herein we report an approach for the synthesis of a unique receptor bambusuril derivative 5 that shows strong associations toward several inorganic anions including iodide and perchlorate up to 107 M-1 in water.2 NMR titration method was applied for the determination of association constants of all investigated anions; furthermore the associations of halides with bambusuril 5 were also examined by ITC. We also demonstrate that bambusuril 5 can be used for the qualitative and quantitative detection of anions at micromolar concentrations in pure water at pH 7.1.3
ER -
YAWER, Mirza Arfan, Václav HAVEL a Vladimír ŠINDELÁŘ. Synthesis and Supramoleculer properties of water soluble Bambusuril derivative. In \textit{6th French- Czech ''Vltava'' Chemistry Meeting, 27-28 August 2015, Brno Czech Republic}. 2015.
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