Study of laser-matter interaction conditions and their impact
on classification of LIBS spectra

a 2015

Study of laser-matter interaction conditions and their impact on classification of LIBS spectra

VÍTKOVÁ, Gabriela; Pavel POŘÍZKA; Karel NOVOTNÝ; David PROCHAZKA; Jakub KLUS et. al.

Základní údaje

Originální název

Study of laser-matter interaction conditions and their impact on classification of LIBS spectra

Autoři

VÍTKOVÁ, Gabriela (203 Česká republika, domácí); Pavel POŘÍZKA (203 Česká republika); Karel NOVOTNÝ (203 Česká republika, garant, domácí); David PROCHAZKA (203 Česká republika); Jakub KLUS (203 Česká republika) a Jozef KAISER (203 Česká republika)

Vydání

8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy, 2015

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10406 Analytical chemistry

Stát vydavatele

Rakousko

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14740/15:00086563

Organizační jednotka

Středoevropský technologický institut

Klíčová slova anglicky

LIBS; laser-matter interaction; principal component analysis

Změněno: 12. 2. 2016 12:49, doc. Mgr. Karel Novotný, Ph.D.

Anotace

V originále

When performing LIBS measurement there is crucial role of so-called matrix effect. Matrix effect is a phenomenon where the chemical and physical properties of the material under study (its composition, type of molecules and the structure of their arrangement, types of bonds, etc.) have a significant effect on the ablation processes and consequent laser-induced plasma formation and evolution. This effect is most often perceived negatively, because it represents a major limitation of quantification. In this contribution varying of measurement conditions is studied in relation to its impact on the classification of materials. Utilization of advanced statistical methods enables classification and identification of materials on the basis of their spectra without the knowledge of absolute amounts of particular elements. However, for good results it is necessary to optimize the measurement conditions properly. This study was done using standardized materials of ores with different matrices. They were measured using LIBS system under various conditions (pulse energy, delay time) and the ideal conditions were chosen from signal to noise ratio (SNR). These spectra were then processed along with the spectra measured using ‘non-ideal’ conditions, thus more significantly suffering from matrix effect. Comparison was illustrated on the results of classification of samples according to their matrices.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

Citovat

VÍTKOVÁ, Gabriela; Pavel POŘÍZKA; Karel NOVOTNÝ; David PROCHAZKA; Jakub KLUS a Jozef KAISER. Study of laser-matter interaction conditions and their impact on classification of LIBS spectra. In 8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy. 2015.

@proceedings{1335220,
   author = {Vítková, Gabriela and Pořízka, Pavel and Novotný, Karel and Prochazka, David and Klus, Jakub and Kaiser, Jozef},
   booktitle = {8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy},
   keywords = {LIBS; laser-matter interaction; principal component analysis},
   language = {eng},
   title = {Study of laser-matter interaction conditions and their impact on classification of LIBS spectra},
   year = {2015}
}

TY  - CONF
ID  - 1335220
AU  - Vítková, Gabriela - Pořízka, Pavel - Novotný, Karel - Prochazka, David - Klus, Jakub - Kaiser, Jozef
PY  - 2015
TI  - Study of laser-matter interaction conditions and their impact on classification of LIBS spectra
KW  - LIBS
KW  - laser-matter interaction
KW  - principal component analysis
N2  - When performing LIBS measurement there is crucial role of so-called matrix effect. Matrix effect is a phenomenon where the chemical and physical properties of the material under study (its composition, type of molecules and the structure of their arrangement, types of bonds, etc.) have a significant effect on the ablation processes and consequent laser-induced plasma formation and evolution. This effect is most often perceived negatively, because it represents a major limitation of quantification. In this contribution varying of measurement conditions is studied in relation to its impact on the classification of materials. Utilization of advanced statistical methods enables classification and identification of materials on the basis of their spectra without the knowledge of absolute amounts of particular elements. However, for good results it is necessary to optimize the measurement conditions properly. This study was done using standardized materials of ores with different matrices. They were measured using LIBS system under various conditions (pulse energy, delay time) and the ideal conditions were chosen from signal to noise ratio (SNR). These spectra were then processed along with the spectra measured using ‘non-ideal’ conditions, thus more significantly suffering from matrix effect. Comparison was illustrated on the results of classification of samples according to their matrices.
ER  -

VÍTKOVÁ, Gabriela; Pavel POŘÍZKA; Karel NOVOTNÝ; David PROCHAZKA; Jakub KLUS a Jozef KAISER. Study of laser-matter interaction conditions and their impact on classification of LIBS spectra. In \textit{8th Euro-Mediterranean Symposium on Laser Induced Breakdown Spectroscopy}. 2015.

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