The internal heavy-atom effect on 3-phenylselanyl and
3-phenyltellanyl BODIPY derivatives studied by transient
absorption spectroscopy

J 2016

The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy

AL ANSHORI, Jamaludin; Tomáš SLANINA; Eduardo PALAO UTIEL and Petr KLÁN

Basic information

Original name

The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy

Authors

AL ANSHORI, Jamaludin; Tomáš SLANINA; Eduardo PALAO UTIEL and Petr KLÁN

Edition

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, CAMBRIDGE, ROYAL SOC CHEMISTRY, 2016, 1474-905X

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10403 Physical chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

References:

URL

Impact factor

Impact factor: 2.344

Marked to be transferred to RIV

Yes

RIV identification code

RIV/00216224:14310/16:00089981

Organization unit

Faculty of Science

Keywords in English

SINGLET OXYGEN GENERATION; TRIPLET EXCITED-STATE; FLUORESCENT-PROBE; LIVING CELLS; PHOTODYNAMIC THERAPY; UP-CONVERSION; DYES; PHOSPHORESCENCE; DESIGN; THIOLS

Abstract

In the original language

Three monosubstituted 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives were synthesized and their spectroscopic properties were characterized and compared to those of iodine and chlorine-atoms containing analogues as well as an unsubstituted BODIPY derivative. The fluorescence quantum yields were found to decrease, whereas the intersystem crossing quantum yields (Phi(ISC)), determined by transient spectroscopy, increased in the order of the H -> Cl -> Se/I -> Te substitution. The maximum Phi(ISC), found for the 3-phenyltellanyl derivative, was 59%. The results are interpreted in terms of the internal heavy-atom effect of the substituents.

Links

LM2011028, research and development project

Name: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí

Investor: Ministry of Education, Youth and Sports of the CR

LO1214, research and development project

Name: Centrum pro výzkum toxických látek v prostředí (Acronym: RECETOX)

Investor: Ministry of Education, Youth and Sports of the CR

Cite

AL ANSHORI, Jamaludin; Tomáš SLANINA; Eduardo PALAO UTIEL and Petr KLÁN. The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES. CAMBRIDGE: ROYAL SOC CHEMISTRY, 2016, vol. 15, No 2, p. 250-259. ISSN 1474-905X. Available from: https://doi.org/10.1039/c5pp00366k.

@article{1345762,
   author = {Al Anshori, Jamaludin and Slanina, Tomáš and Palao Utiel, Eduardo and Klán, Petr},
   article_location = {CAMBRIDGE},
   article_number = {2},
   doi = {https://doi.org/10.1039/c5pp00366k},
   keywords = {SINGLET OXYGEN GENERATION; TRIPLET EXCITED-STATE; FLUORESCENT-PROBE; LIVING CELLS; PHOTODYNAMIC THERAPY; UP-CONVERSION; DYES; PHOSPHORESCENCE; DESIGN; THIOLS},
   language = {eng},
   issn = {1474-905X},
   journal = {PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES},
   title = {The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy},
   url = {http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00366K#!divAbstract},
   volume = {15},
   year = {2016}
}

TY  - JOUR
ID  - 1345762
AU  - Al Anshori, Jamaludin - Slanina, Tomáš - Palao Utiel, Eduardo - Klán, Petr
PY  - 2016
TI  - The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy
JF  - PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
VL  - 15
IS  - 2
SP  - 250-259
EP  - 250-259
PB  - ROYAL SOC CHEMISTRY
SN  - 1474905X
KW  - SINGLET OXYGEN GENERATION
KW  - TRIPLET EXCITED-STATE
KW  - FLUORESCENT-PROBE
KW  - LIVING CELLS
KW  - PHOTODYNAMIC THERAPY
KW  - UP-CONVERSION
KW  - DYES
KW  - PHOSPHORESCENCE
KW  - DESIGN
KW  - THIOLS
UR  - http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00366K#!divAbstract
L2  - http://pubs.rsc.org/en/Content/ArticleLanding/2016/PP/C5PP00366K#!divAbstract
N2  - Three monosubstituted 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives were synthesized and their spectroscopic properties were characterized and compared to those of iodine and chlorine-atoms containing analogues as well as an unsubstituted BODIPY derivative. The fluorescence quantum yields were found to decrease, whereas the intersystem crossing quantum yields (Phi(ISC)), determined by transient spectroscopy, increased in the order of the H -> Cl -> Se/I -> Te substitution. The maximum Phi(ISC), found for the 3-phenyltellanyl derivative, was 59%. The results are interpreted in terms of the internal heavy-atom effect of the substituents.
ER  -

AL ANSHORI, Jamaludin; Tomáš SLANINA; Eduardo PALAO UTIEL and Petr KLÁN. The internal heavy-atom effect on 3-phenylselanyl and 3-phenyltellanyl BODIPY derivatives studied by transient absorption spectroscopy. \textit{PHOTOCHEMICAL \&{} PHOTOBIOLOGICAL SCIENCES}. CAMBRIDGE: ROYAL SOC CHEMISTRY, 2016, vol.~15, No~2, p.~250-259. ISSN~1474-905X. Available from: https://doi.org/10.1039/c5pp00366k.

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