| CIVIŠ, Svatopluk, Rafal Kazimierz SZABLA, Bartłomiej M. SZYJA, Daniel SMYKOWSKI, Ondřej IVANEK, Antonín KNÍŽEK, Petr KUBELÍK, Jiří ŠPONER, Martin FERUS a Judit ŠPONEROVÁ. TiO2-catalyzed synthesis of sugars from formaldehyde in extraterrestrial impacts on the early Earth. Scientific Reports. LONDON: NATURE PUBLISHING GROUP, 2016, roč. 6, March, s. nestránkováno, 7 s. ISSN 2045-2322. Dostupné z: https://dx.doi.org/10.1038/srep23199. |
Další formáty:
BibTeX
LaTeX
RIS
@article{1352741,
author = {Civiš, Svatopluk and Szabla, Rafal Kazimierz and Szyja, Bartłomiej M. and Smykowski, Daniel and Ivanek, Ondřej and Knížek, Antonín and Kubelík, Petr and Šponer, Jiří and Ferus, Martin and Šponerová, Judit},
article_location = {LONDON},
article_number = {March},
doi = {http://dx.doi.org/10.1038/srep23199},
keywords = {HIGH-ENERGY CHEMISTRY; CARBONACEOUS METEORITES; CHEMICAL-COMPOSITION; PREBIOTIC CONDITIONS; NUCLEOBASE FORMATION; MECHANISM; FORMAMIDE; GLYCOLALDEHYDE; COMETARY; SURFACE},
language = {eng},
issn = {2045-2322},
journal = {Scientific Reports},
title = {TiO2-catalyzed synthesis of sugars from formaldehyde in extraterrestrial impacts on the early Earth},
url = {http://www.nature.com/articles/srep23199},
volume = {6},
year = {2016}
}
TY - JOUR
ID - 1352741
AU - Civiš, Svatopluk - Szabla, Rafal Kazimierz - Szyja, Bartłomiej M. - Smykowski, Daniel - Ivanek, Ondřej - Knížek, Antonín - Kubelík, Petr - Šponer, Jiří - Ferus, Martin - Šponerová, Judit
PY - 2016
TI - TiO2-catalyzed synthesis of sugars from formaldehyde in extraterrestrial impacts on the early Earth
JF - Scientific Reports
VL - 6
IS - March
SP - nestránkováno
EP - nestránkováno
PB - NATURE PUBLISHING GROUP
SN - 20452322
KW - HIGH-ENERGY CHEMISTRY
KW - CARBONACEOUS METEORITES
KW - CHEMICAL-COMPOSITION
KW - PREBIOTIC CONDITIONS
KW - NUCLEOBASE FORMATION
KW - MECHANISM
KW - FORMAMIDE
KW - GLYCOLALDEHYDE
KW - COMETARY
KW - SURFACE
UR - http://www.nature.com/articles/srep23199
L2 - http://www.nature.com/articles/srep23199
N2 - Recent synthetic efforts aimed at reconstructing the beginning of life on our planet point at the plausibility of scenarios fueled by extraterrestrial energy sources. In the current work we show that beyond nucleobases the sugar components of the first informational polymers can be synthesized in this way. We demonstrate that a laser-induced high-energy chemistry combined with TiO2 catalysis readily produces a mixture of pentoses, among them ribose, arabinose and xylose. This chemistry might be highly relevant to the Late Heavy Bombardment period of Earth's history about 4-3.85 billion years ago. In addition, we present an in-depth theoretical analysis of the most challenging step of the reaction pathway, i.e., the TiO2-catalyzed dimerization of formaldehyde leading to glycolaldehyde.
ER -
CIVIŠ, Svatopluk, Rafal Kazimierz SZABLA, Bartłomiej M. SZYJA, Daniel SMYKOWSKI, Ondřej IVANEK, Antonín KNÍŽEK, Petr KUBELÍK, Jiří ŠPONER, Martin FERUS a Judit ŠPONEROVÁ. TiO2-catalyzed synthesis of sugars from formaldehyde in extraterrestrial impacts on the early Earth. \textit{Scientific Reports}. LONDON: NATURE PUBLISHING GROUP, 2016, roč.~6, March, s.~nestránkováno, 7 s. ISSN~2045-2322. Dostupné z: https://dx.doi.org/10.1038/srep23199.
|
