Self-crosslinking acrylic latexes with copolymerized flame
retardant based on halogenophosphazene derivative

J 2016

Self-crosslinking acrylic latexes with copolymerized flame retardant based on halogenophosphazene derivative

MACHOTOVÁ, Jana; Lucie ZÁRYBNICKÁ; Radka BAČOVSKÁ; Josef VRAŠTIL; Martina HUDÁKOVÁ et al.

Základní údaje

Originální název

Self-crosslinking acrylic latexes with copolymerized flame retardant based on halogenophosphazene derivative

Autoři

MACHOTOVÁ, Jana; Lucie ZÁRYBNICKÁ; Radka BAČOVSKÁ; Josef VRAŠTIL; Martina HUDÁKOVÁ a Jaromír ŠŇUPÁREK

Vydání

Progress in Organic Coatings, 2016, 0300-9440

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 2.858

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/16:00090856

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Emulsion polymerisation; Core-shell latex; Diacetone acrylamide; Flame retardant; Phosphazene; Cone calorimeter

Štítky

AKR, rivok

Změněno: 13. 4. 2017 21:50, Ing. Andrea Mikešková

Anotace

V originále

In this study the synthesis of a novel flame retardant based on halogenophosphazene derivative and its application in waterborne coatings based on self-crosslinking latexes was investigated. Hexaallylamino-cyclo-triphosphazene was synthesized by nucleophilic substitution of hexachloro-cyclo-triphosphazene with allyl amine. Latexes of functionalized core-shell particles bearing in the structure hexaallylamino-cyclo-triphosphazene molecules were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. For interfacial crosslinking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, toughness and adhesive properties of resulting coatings. Moreover, the presence of the novel flame retardant decreased water sensitivity and increased the flame stability of coatings in terms of reduced total heat release, decreased amount of released smoke and drop in maximum average rate of heat emission which indicates a slower flame spread during the material combustion.

Citovat

MACHOTOVÁ, Jana; Lucie ZÁRYBNICKÁ; Radka BAČOVSKÁ; Josef VRAŠTIL; Martina HUDÁKOVÁ a Jaromír ŠŇUPÁREK. Self-crosslinking acrylic latexes with copolymerized flame retardant based on halogenophosphazene derivative. Progress in Organic Coatings. 2016, roč. 101, December, s. 322 - 330. ISSN 0300-9440. Dostupné z: https://doi.org/10.1016/j.porgcoat.2016.09.007.

@article{1354522,
   author = {Machotová, Jana and Zárybnická, Lucie and Bačovská, Radka and Vraštil, Josef and Hudáková, Martina and Šňupárek, Jaromír},
   article_number = {December},
   doi = {https://doi.org/10.1016/j.porgcoat.2016.09.007},
   keywords = {Emulsion polymerisation; Core-shell latex; Diacetone acrylamide; Flame retardant; Phosphazene; Cone calorimeter},
   language = {eng},
   issn = {0300-9440},
   journal = {Progress in Organic Coatings},
   title = {Self-crosslinking acrylic latexes with copolymerized flame retardant based on halogenophosphazene derivative},
   volume = {101},
   year = {2016}
}

TY  - JOUR
ID  - 1354522
AU  - Machotová, Jana - Zárybnická, Lucie - Bačovská, Radka - Vraštil, Josef - Hudáková, Martina - Šňupárek, Jaromír
PY  - 2016
TI  - Self-crosslinking acrylic latexes with copolymerized flame retardant based on halogenophosphazene derivative
JF  - Progress in Organic Coatings
VL  - 101
IS  - December
SP  - 322 - 330
EP  - 322 - 330
SN  - 03009440
KW  - Emulsion polymerisation
KW  - Core-shell latex
KW  - Diacetone acrylamide
KW  - Flame retardant
KW  - Phosphazene
KW  - Cone calorimeter
N2  - In this study the synthesis of a novel flame retardant based on halogenophosphazene derivative and its application in waterborne coatings based on self-crosslinking latexes was investigated. Hexaallylamino-cyclo-triphosphazene was synthesized by nucleophilic substitution of hexachloro-cyclo-triphosphazene with allyl amine. Latexes of functionalized core-shell particles bearing in the structure hexaallylamino-cyclo-triphosphazene molecules were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. For interfacial crosslinking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The incorporation hexaallylamino-cyclo-triphosphazene did not affect transparency, flexibility, toughness and adhesive properties of resulting coatings. Moreover, the presence of the novel flame retardant decreased water sensitivity and increased the flame stability of coatings in terms of reduced total heat release, decreased amount of released smoke and drop in maximum average rate of heat emission which indicates a slower flame spread during the material combustion.
ER  -

MACHOTOVÁ, Jana; Lucie ZÁRYBNICKÁ; Radka BAČOVSKÁ; Josef VRAŠTIL; Martina HUDÁKOVÁ a Jaromír ŠŇUPÁREK. Self-crosslinking acrylic latexes with copolymerized flame retardant based on halogenophosphazene derivative. \textit{Progress in Organic Coatings}. 2016, roč.~101, December, s.~322 - 330. ISSN~0300-9440. Dostupné z: https://doi.org/10.1016/j.porgcoat.2016.09.007.

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