Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight
Mass Spectrometry of AumFen+/– Clusters Generated from
Gold-Iron Nanoparticles and their Giant Nanoflowers.
Electrochemical and/or Plasma Assisted Synthesis

J 2017

Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of AumFen+/– Clusters Generated from Gold-Iron Nanoparticles and their Giant Nanoflowers. Electrochemical and/or Plasma Assisted Synthesis

MAWALE, Ravi; Mayuri Vilas AUSEKAR; David PAVLIŇÁK; Oleksandr GALMIZ; Pavel KUBÁČEK et al.

Základní údaje

Originální název

Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of AumFen+/– Clusters Generated from Gold-Iron Nanoparticles and their Giant Nanoflowers. Electrochemical and/or Plasma Assisted Synthesis

Autoři

MAWALE, Ravi; Mayuri Vilas AUSEKAR; David PAVLIŇÁK; Oleksandr GALMIZ; Pavel KUBÁČEK a Josef HAVEL

Vydání

Journal of The American Society for Mass Spectrometry, New York, Springer, 2017, 1044-0305

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

odkaz na článek

Impakt faktor

Impact factor: 2.869

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/17:00094575

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Mass spectrometry;Nanoparticles;Nanoflowers;Plasma-assisted;Stainless steel;Laser desorption ionization

Štítky

NZ, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 6. 4. 2018 11:02, Ing. Nicole Zrilić

Anotace

V originále

Gold nanoparticles (NP) with average diameter 100 nm synthesized from tetrachloroauric acid solution using stainless steel as a reducing agent were found to contain iron. Applying simultaneously high frequency (HF) plasma discharge in solution during the electrochemical reduction, giant gold-iron nanoflowers with average size 1000–5000 nm were formed. Scanning electron microscopy (SEM) shows the morphology of the nanopowders produced as polygonal yet nearly spherical, whereas iron content in both products determined by energy dispersive X-ray analysis (EDX) was found to be at 2.5 at%. Laser desorption ionization (LDI) of both nanomaterials and mass spectrometric analysis show the formation of AumFen+/– (m = 1–35; n = 1–3) clusters. Structure of few selected clusters in neutral or monocharged forms were computed by density functional theory (DFT) calculations and it was found that typical distances of an iron nucleus from adjacent gold nuclei lie in the interval 2.5 to 2.7 A. Synthetized Au-Fe nanoparticles were found stable for at least 2 mo at room temperature (even in aqueous solution) without any stabilizing agent. Produced Au-Fe nanoparticles in combination with standard MALDI matrices enhance ionization of peptides and might find use in nanomedicine.

Návaznosti

ED2.1.00/03.0086, projekt VaV

Název: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

GA13-05082S, projekt VaV

Název: Analýza a aplikace plazmatických procesů pro přípravu tenkých vrstev amorfních chalkogenidů

Investor: Grantová agentura ČR, Analýza a aplikace plazmatických procesů pro přípravu tenkých vrstev amorfních chalkogenidů

LO1411, projekt VaV

Název: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Akronym: CEPLANT plus)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

MAWALE, Ravi; Mayuri Vilas AUSEKAR; David PAVLIŇÁK; Oleksandr GALMIZ; Pavel KUBÁČEK a Josef HAVEL. Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of AumFen+/– Clusters Generated from Gold-Iron Nanoparticles and their Giant Nanoflowers. Electrochemical and/or Plasma Assisted Synthesis. Journal of The American Society for Mass Spectrometry. New York: Springer, 2017, roč. 28, č. 2, s. 215-223. ISSN 1044-0305. Dostupné z: https://doi.org/10.1007/s13361-016-1547-1.

@article{1361772,
   author = {Mawale, Ravi and Ausekar, Mayuri Vilas and Pavliňák, David and Galmiz, Oleksandr and Kubáček, Pavel and Havel, Josef},
   article_location = {New York},
   article_number = {2},
   doi = {https://doi.org/10.1007/s13361-016-1547-1},
   keywords = {Mass spectrometry;Nanoparticles;Nanoflowers;Plasma-assisted;Stainless steel;Laser desorption ionization},
   language = {eng},
   issn = {1044-0305},
   journal = {Journal of The American Society for Mass Spectrometry},
   title = {Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of AumFen+/– Clusters Generated from Gold-Iron Nanoparticles and their Giant Nanoflowers. Electrochemical and/or Plasma Assisted Synthesis},
   url = {http://link.springer.com/article/10.1007/s13361-016-1547-1},
   volume = {28},
   year = {2017}
}

TY  - JOUR
ID  - 1361772
AU  - Mawale, Ravi - Ausekar, Mayuri Vilas - Pavliňák, David - Galmiz, Oleksandr - Kubáček, Pavel - Havel, Josef
PY  - 2017
TI  - Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of AumFen+/– Clusters Generated from Gold-Iron Nanoparticles and their Giant Nanoflowers. Electrochemical and/or Plasma Assisted Synthesis
JF  - Journal of The American Society for Mass Spectrometry
VL  - 28
IS  - 2
SP  - 215-223
EP  - 215-223
PB  - Springer
SN  - 10440305
KW  - Mass spectrometry;Nanoparticles;Nanoflowers;Plasma-assisted;Stainless steel;Laser desorption ionization
UR  - http://link.springer.com/article/10.1007/s13361-016-1547-1
L2  - http://link.springer.com/article/10.1007/s13361-016-1547-1
N2  - Gold nanoparticles (NP) with average diameter 100 nm synthesized from tetrachloroauric acid solution using stainless steel as a reducing agent were found to contain iron. Applying simultaneously high frequency (HF) plasma discharge in solution during the electrochemical reduction, giant gold-iron nanoflowers with average size 1000–5000 nm were formed. Scanning electron microscopy (SEM) shows the morphology of the nanopowders produced as polygonal yet nearly spherical, whereas iron content in both products determined by energy dispersive X-ray analysis (EDX) was found to be at 2.5 at%. Laser desorption ionization (LDI) of both nanomaterials and mass spectrometric analysis show the formation of AumFen+/– (m = 1–35; n = 1–3) clusters. Structure of few selected clusters in neutral or monocharged forms were computed by density functional theory (DFT) calculations and it was found that typical distances of an iron nucleus from adjacent gold nuclei lie in the interval 2.5 to 2.7 A. Synthetized Au-Fe nanoparticles were found stable for at least 2 mo at room temperature (even in aqueous solution) without any stabilizing agent. Produced Au-Fe nanoparticles in combination with standard MALDI matrices enhance ionization of peptides and might find use in nanomedicine.
ER  -

MAWALE, Ravi; Mayuri Vilas AUSEKAR; David PAVLIŇÁK; Oleksandr GALMIZ; Pavel KUBÁČEK a Josef HAVEL. Laser Desorption Ionization Quadrupole Ion Trap Time-of-Flight Mass Spectrometry of AumFen+/– Clusters Generated from Gold-Iron Nanoparticles and their Giant Nanoflowers. Electrochemical and/or Plasma Assisted Synthesis. \textit{Journal of The American Society for Mass Spectrometry}. New York: Springer, 2017, roč.~28, č.~2, s.~215-223. ISSN~1044-0305. Dostupné z: https://doi.org/10.1007/s13361-016-1547-1.

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