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@article{1371893,
author = {Degrendele, Celine and Audy, Ondřej and Hofman, Jakub and Kucerik, Jiří and Kukučka, Petr and Mulder, Marie Daniëlle and Přibylová, Petra and Prokeš, Roman and Sáňka, Milan and Schaumann, Gabriele E. and Lammel, Gerhard},
article_location = {WASHINGTON},
article_number = {8},
doi = {http://dx.doi.org/10.1021/acs.est.5b05671},
keywords = {POLYCYCLIC AROMATIC-HYDROCARBONS; POLYBROMINATED DIPHENYL ETHERS; CENTRAL TIBETAN PLATEAU; ORGANOCHLORINE PESTICIDES; POLYCHLORINATED-BIPHENYLS; PARTITION-COEFFICIENTS; SURFACE SOIL; BLACK CARBON; SPATIAL-DISTRIBUTION; ATMOSPHERIC CONCENTRATIONS},
language = {eng},
issn = {0013-936X},
journal = {ENVIRONMENTAL SCIENCE & TECHNOLOGY},
title = {Diurnal Variations of Air-Soil Exchange of Semivolatile Organic Compounds (PAHs, PCBs, OCPs, and PBDEs) in a Central European Receptor Area},
url = {http://pubs.acs.org/doi/abs/10.1021/acs.est.5b05671},
volume = {50},
year = {2016}
}
TY - JOUR
ID - 1371893
AU - Degrendele, Celine - Audy, Ondřej - Hofman, Jakub - Kucerik, Jiří - Kukučka, Petr - Mulder, Marie Daniëlle - Přibylová, Petra - Prokeš, Roman - Sáňka, Milan - Schaumann, Gabriele E. - Lammel, Gerhard
PY - 2016
TI - Diurnal Variations of Air-Soil Exchange of Semivolatile Organic Compounds (PAHs, PCBs, OCPs, and PBDEs) in a Central European Receptor Area
JF - ENVIRONMENTAL SCIENCE & TECHNOLOGY
VL - 50
IS - 8
SP - 4278-4288
EP - 4278-4288
PB - AMER CHEMICAL SOC
SN - 0013936X
KW - POLYCYCLIC AROMATIC-HYDROCARBONS
KW - POLYBROMINATED DIPHENYL ETHERS
KW - CENTRAL TIBETAN PLATEAU
KW - ORGANOCHLORINE PESTICIDES
KW - POLYCHLORINATED-BIPHENYLS
KW - PARTITION-COEFFICIENTS
KW - SURFACE SOIL
KW - BLACK CARBON
KW - SPATIAL-DISTRIBUTION
KW - ATMOSPHERIC CONCENTRATIONS
UR - http://pubs.acs.org/doi/abs/10.1021/acs.est.5b05671
L2 - http://pubs.acs.org/doi/abs/10.1021/acs.est.5b05671
N2 - Concentrations of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polybrominated diphenyl ethers (PBDEs) in air and soil, their fugacities, and the experimental soil-air partitioning coefficient (K-SA) were determined at two background sites in the Gt. Hungarian Plain in August 2013. The concentrations of the semivolatile organic compounds (SOCs) in the soil were not correlated with the organic carbon content but with two indirect parameters of mineralization and aromaticity, suggesting that soil organic matter quality is an important parameter affecting the sorption of SOCs onto soils. Predictions based on the assumption that absorption is the dominant process were in good agreement with the measurements for PAHs, OCPs, and the low chlorinated PCBs. In general, soils were found to be a source of PAHs, high chlorinated PCBs, the majority of OCPs and PBDEs, and a sink for the low chlorinated PCBs and gamma-hexachlorocyclohexane. Diurnal variations in the direction of the soil-air exchange were found for two compounds (i.e., pentachlorobenzene and p,p'-dichlorodiphenyldichloroethane), with volatilization during the day and deposition in the night. The concentrations of most SOCs in the near-ground atmosphere were dominated by revolatilization from the soil.
ER -
DEGRENDELE, Celine, Ondřej AUDY, Jakub HOFMAN, Jiří KUCERIK, Petr KUKUČKA, Marie Dani$\backslash$''elle MULDER, Petra PŘIBYLOVÁ, Roman PROKEŠ, Milan SÁŇKA, Gabriele E. SCHAUMANN a Gerhard LAMMEL. Diurnal Variations of Air-Soil Exchange of Semivolatile Organic Compounds (PAHs, PCBs, OCPs, and PBDEs) in a Central European Receptor Area. \textit{ENVIRONMENTAL SCIENCE \&{}amp; TECHNOLOGY}. WASHINGTON: AMER CHEMICAL SOC, 2016, roč.~50, č.~8, s.~4278-4288. ISSN~0013-936X. Dostupné z: https://dx.doi.org/10.1021/acs.est.5b05671.
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