2016
Laser-induced breakdown spectroscopy 2d distribution mapping of quantum dots
ŠKARKOVÁ, Pavlína, Karel NOVOTNÝ, Přemysl LUBAL, Alžběta JEBAVÁ, Pavel POŘÍZKA et. al.Základní údaje
Originální název
Laser-induced breakdown spectroscopy 2d distribution mapping of quantum dots
Autoři
ŠKARKOVÁ, Pavlína (203 Česká republika, garant), Karel NOVOTNÝ (203 Česká republika, domácí), Přemysl LUBAL (203 Česká republika, domácí), Alžběta JEBAVÁ (203 Česká republika, domácí), Pavel POŘÍZKA (203 Česká republika), David PROCHAZKA (203 Česká republika), Aleš HRDLIČKA (203 Česká republika, domácí) a Jozef KAISER (203 Česká republika)
Vydání
European symposium on atomic spectrometry ESAS 2016, 2016
Další údaje
Jazyk
angličtina
Typ výsledku
Prezentace na konferencích
Obor
10402 Inorganic and nuclear chemistry
Stát vydavatele
Maďarsko
Utajení
není předmětem státního či obchodního tajemství
Odkazy
Kód RIV
RIV/00216224:14740/16:00093812
Organizační jednotka
Středoevropský technologický institut
ISBN
978-963-9970-65-6
Klíčová slova česky
laserem buzené; mikroplazma; spektroskopie; kvantové tečky; mapování; nanočástice
Klíčová slova anglicky
Laser; induced; breakdown; spectroscopy; quantum dots; mapping; nanoparticle;
Příznaky
Mezinárodní význam
Změněno: 7. 3. 2017 12:39, Mgr. Aleš Hrdlička, Ph.D.
Anotace
V originále
Laser-Induced Breakdown Spectroscopy (LIBS) has been widely used in modern analytical chemistry, it shown the growing number of users in different fields of element study from using at cultural heritage, geochemistry, remote sensing, industrial process monitoring, the analysis of bio-samples and recycling to environmental monitoring. This method is so popular because it offers a series of advantages such as fast response, applicability to any type of sample, practically no sample preparation, remote sensing capability, speed of analysis and the main advantage is the possibility of investigation of the elemental spatial distribution. The use of quantum dots (QDs) as probes for bioanalytical applications is a highly promising technique because fluorescence-based techniques are very sensitive. QDs seem to show the greatest promise as labels for tagging and imaging in biological systems. In our study suitable procedure for injection of QDs onto a different substrate and optimization of these particles detection using LIBS was focused to achieve the best spatial resolution and the lowest detection limits. Dependence of the LIBS signal intensity on the different parameters was investigated. The technique described in this poster presentation allows detection of QDs injected on the silica gel spread on aluminum foil or filtration paper. Commercially available table-top LIBS system with software controlled stages in x and y directions was used. The prepared substrates with injected QDs were placed into a lab-made holder. Experimental conditions, as gate delay, gate width, used energy of the laser, volume of applied suspension of QDs and their proper pretreatment and drying were studied. The feasibility of their 2D distribution mapping on the substrate by LIBS was examined in connection with the separation (or pre concentration) possibilities. LIBS can serve not only for detection of fluorescent QDs but also for nanoparticles which do not show any visible luminescence.
Návaznosti
ED1.1.00/02.0068, projekt VaV |
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