Carboxyl-rich coatings deposited by atmospheric plasma
co-polymerization of maleic anhydride and acetylene

J 2016

Carboxyl-rich coatings deposited by atmospheric plasma co-polymerization of maleic anhydride and acetylene

MANAKHOV, Anton; Miroslav MICHLÍČEK; David NEČAS; Josef POLCAK; Ekaterina MAKHNEVA et al.

Základní údaje

Originální název

Carboxyl-rich coatings deposited by atmospheric plasma co-polymerization of maleic anhydride and acetylene

Autoři

MANAKHOV, Anton; Miroslav MICHLÍČEK; David NEČAS; Josef POLCAK; Ekaterina MAKHNEVA; Marek ELIÁŠ a Lenka ZAJÍČKOVÁ

Vydání

SURFACE & COATINGS TECHNOLOGY, LAUSANNE, ELSEVIER SCIENCE SA, 2016, 0257-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10302 Condensed matter physics

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.589

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14740/16:00093847

Organizační jednotka

Středoevropský technologický institut

Klíčová slova anglicky

Plasma co-polymerization; Carboxyl films; Maleic anhydride; XPS; Derivatization

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 31. 10. 2017 09:44, Mgr. Miroslav Michlíček, Ph.D.

Anotace

V originále

Carboxyl coatings are extensively used for adhesion promotion, bio-immobilization and surface reactions thanks to their reactivity towards nucleophilic groups and high wettability. The deposition of relatively stable carboxyl rich coatings using low-cost atmospheric pressure plasma processes is still challenging. This work is aimed at the investigation of the plasma copolymerization of maleic anhydride (MA) and C2H2 by atmospheric pressure dielectric barrier discharge. The quantification of the carboxyl groups is performed by X-ray photoelectron spectroscopy (XPS) C1s curve fitting and by derivatization with trifluoroethanol. The layer synthesized at optimized monomer flow rate and plasma power contains 5 at.% of carboxyl groups (determined by derivatization combined with XPS) and exhibits the thickness loss below 5% after 128 h in water. The influence of the MA:C2H2 ratio on the layer chemistry, morphology and stability is analyzed. (C) 2015 Elsevier B.V. All rights reserved.

Návaznosti

ED1.1.00/02.0068, projekt VaV

Název: CEITEC - central european institute of technology

LD14036, projekt VaV

Název: Příprava biokompatibilních nanovlákenných materiálů pomocí plazmových procesů za atmosférického tlaku (Akronym: BioNanoPlas)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Příprava biokompatibilních nanovlákenných materiálů pomocí plazmových procesů za atmosférického tlaku

LM2011020, projekt VaV

Název: CEITEC ? open access

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC - open access

Citovat

MANAKHOV, Anton; Miroslav MICHLÍČEK; David NEČAS; Josef POLCAK; Ekaterina MAKHNEVA; Marek ELIÁŠ a Lenka ZAJÍČKOVÁ. Carboxyl-rich coatings deposited by atmospheric plasma co-polymerization of maleic anhydride and acetylene. SURFACE & COATINGS TECHNOLOGY. LAUSANNE: ELSEVIER SCIENCE SA, 2016, roč. 295, June, s. 37-45. ISSN 0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2015.11.039.

@article{1375040,
   author = {Manakhov, Anton and Michlíček, Miroslav and Nečas, David and Polcak, Josef and Makhneva, Ekaterina and Eliáš, Marek and Zajíčková, Lenka},
   article_location = {LAUSANNE},
   article_number = {June},
   doi = {https://doi.org/10.1016/j.surfcoat.2015.11.039},
   keywords = {Plasma co-polymerization; Carboxyl films; Maleic anhydride; XPS; Derivatization},
   language = {eng},
   issn = {0257-8972},
   journal = {SURFACE & COATINGS TECHNOLOGY},
   title = {Carboxyl-rich coatings deposited by atmospheric plasma co-polymerization of maleic anhydride and acetylene},
   url = {http://www.sciencedirect.com/science/article/pii/S0257897215304138},
   volume = {295},
   year = {2016}
}

TY  - JOUR
ID  - 1375040
AU  - Manakhov, Anton - Michlíček, Miroslav - Nečas, David - Polcak, Josef - Makhneva, Ekaterina - Eliáš, Marek - Zajíčková, Lenka
PY  - 2016
TI  - Carboxyl-rich coatings deposited by atmospheric plasma co-polymerization of maleic anhydride and acetylene
JF  - SURFACE & COATINGS TECHNOLOGY
VL  - 295
IS  - June
SP  - 37-45
EP  - 37-45
PB  - ELSEVIER SCIENCE SA
SN  - 02578972
KW  - Plasma co-polymerization
KW  - Carboxyl films
KW  - Maleic anhydride
KW  - XPS
KW  - Derivatization
UR  - http://www.sciencedirect.com/science/article/pii/S0257897215304138
L2  - http://www.sciencedirect.com/science/article/pii/S0257897215304138
N2  - Carboxyl coatings are extensively used for adhesion promotion, bio-immobilization and surface reactions thanks to their reactivity towards nucleophilic groups and high wettability. The deposition of relatively stable carboxyl rich coatings using low-cost atmospheric pressure plasma processes is still challenging. This work is aimed at the investigation of the plasma copolymerization of maleic anhydride (MA) and C2H2 by atmospheric pressure dielectric barrier discharge. The quantification of the carboxyl groups is performed by X-ray photoelectron spectroscopy (XPS) C1s curve fitting and by derivatization with trifluoroethanol. The layer synthesized at optimized monomer flow rate and plasma power contains 5 at.% of carboxyl groups (determined by derivatization combined with XPS) and exhibits the thickness loss below 5% after 128 h in water. The influence of the MA:C2H2 ratio on the layer chemistry, morphology and stability is analyzed. (C) 2015 Elsevier B.V. All rights reserved.
ER  -

MANAKHOV, Anton; Miroslav MICHLÍČEK; David NEČAS; Josef POLCAK; Ekaterina MAKHNEVA; Marek ELIÁŠ a Lenka ZAJÍČKOVÁ. Carboxyl-rich coatings deposited by atmospheric plasma co-polymerization of maleic anhydride and acetylene. \textit{SURFACE \&{} COATINGS TECHNOLOGY}. LAUSANNE: ELSEVIER SCIENCE SA, 2016, roč.~295, June, s.~37-45. ISSN~0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2015.11.039.

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