| KUBÁČEK, Pavel, Lubomír PROKEŠ, Annapurna PAMREDDY, Eladia Maria PEÑA‐MÉNDEZ, José Elias CONDE, Milan ALBERTI a Josef HAVEL. Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer. Rapid Communications in Mass Spectrometry. Wiley, 2018, roč. 32, č. 10, s. 789-800. ISSN 0951-4198. Dostupné z: https://dx.doi.org/10.1002/rcm.8106. |
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@article{1413396,
author = {Kubáček, Pavel and Prokeš, Lubomír and Pamreddy, Annapurna and Peña‐Méndez, Eladia Maria and Conde, José Elias and Alberti, Milan and Havel, Josef},
article_number = {10},
doi = {http://dx.doi.org/10.1002/rcm.8106},
keywords = {arsenic; phosphorus; LDi-TOF; clusters},
language = {eng},
issn = {0951-4198},
journal = {Rapid Communications in Mass Spectrometry},
title = {Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer},
url = {https://doi.org/10.1002/rcm.8106},
volume = {32},
year = {2018}
}
TY - JOUR
ID - 1413396
AU - Kubáček, Pavel - Prokeš, Lubomír - Pamreddy, Annapurna - Peña‐Méndez, Eladia Maria - Conde, José Elias - Alberti, Milan - Havel, Josef
PY - 2018
TI - Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer
JF - Rapid Communications in Mass Spectrometry
VL - 32
IS - 10
SP - 789-800
EP - 789-800
PB - Wiley
SN - 09514198
KW - arsenic
KW - phosphorus
KW - LDi-TOF
KW - clusters
UR - https://doi.org/10.1002/rcm.8106
L2 - https://doi.org/10.1002/rcm.8106
N2 - Only a few arsenic phosphides are known. High potential for the generation of new compounds is offered by Laser Ablation Synthesis and when Laser Desorption Ionization is coupled with simultaneous Time of Flight Mass Spectrometry, immediate identification of the clusters can be achieved. LAS was used for the generation of arsenic phosphides via laser ablation of phosphorus arsenic mixtures while quadrupole ion trap time of flight mass spectrometry was used to acquire the mass spectra. Many new AsmPn clusters not yet described in the literature were generated in the gas phase and their stoichiometry determined. The likely structures for some of the observed clusters arbitrary selected were computed by DFT optimization. LAS is an advantageous approach for the generation of new AsmPn clusters, while mass spectrometry was found to be an efficient technique for the determination of cluster stoichiometry. The results achieved might inspire the synthesis of new materials.
ER -
KUBÁČEK, Pavel, Lubomír PROKEŠ, Annapurna PAMREDDY, Eladia Maria PEÑA‐MÉNDEZ, José Elias CONDE, Milan ALBERTI a Josef HAVEL. Laser ablation synthesis of arsenic phosphides AsmPn clusters from As P mixtures. Laser desorption ionisation with quadrupole ion trap time of flight mass spectrometry. Mass spectrometer as a synthesizer. \textit{Rapid Communications in Mass Spectrometry}. Wiley, 2018, roč.~32, č.~10, s.~789-800. ISSN~0951-4198. Dostupné z: https://dx.doi.org/10.1002/rcm.8106.
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