Determination of deuterium oxide content in water based on
luminescence quenching

J 2018

Determination of deuterium oxide content in water based on luminescence quenching

KUČERA, Josef; Přemysl LUBAL; S. LIS a Petr TÁBORSKÝ

Základní údaje

Originální název

Determination of deuterium oxide content in water based on luminescence quenching

Autoři

KUČERA, Josef; Přemysl LUBAL; S. LIS a Petr TÁBORSKÝ

Vydání

Talanta, AMSTERDAM, Elsevier, 2018, 0039-9140

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.916

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/18:00102949

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Deuterium oxide determination; Time-Resolved Luminescence Spectroscopy; Luminescence quenching; Ln(III) luminescence; Organic compounds luminescence

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 3. 2019 16:41, prof. RNDr. Přemysl Lubal, Ph.D.

Anotace

V originále

Water molecules (H2O) often reduce luminescence lifetimes of various luminescence probes. The change of lifetime is usually caused by dynamic luminescence quenching induced by O-H oscillators which effectively take away energy from excited molecule. The process can be described by Stern-Volmer equation. We have studied selected luminescence systems where it is possible to detect considerable changes of lifetime in presence/absence of H2O and D2O in this work for analytical purposes. We have tested both, inorganic (Ln(3+)) and organic compounds using three different instrumentation in order to find the largest change between tau(H) and tau(D). The Ln(3+) containing systems have shown considerable increase/decrease of lifetimes in the presence/absence of D2O (Eu3+ : tau(D)/tau(H) = 34.5) whereas organic systems gave significantly lower values of tau(D)/tau(H) (coumarin 123 lifetime ratio, tau(D)/tau(H) = 1.94). The calculated LOD varied from 0.04 mol l(-1) (samarium nitrate) to 6.55 mol l(-1) (riboflavin).

Citovat

KUČERA, Josef; Přemysl LUBAL; S. LIS a Petr TÁBORSKÝ. Determination of deuterium oxide content in water based on luminescence quenching. Talanta. AMSTERDAM: Elsevier, 2018, roč. 184, JUL, s. 364-368. ISSN 0039-9140. Dostupné z: https://doi.org/10.1016/j.talanta.2018.03.016.

@article{1419964,
   author = {Kučera, Josef and Lubal, Přemysl and Lis, S. and Táborský, Petr},
   article_location = {AMSTERDAM},
   article_number = {JUL},
   doi = {https://doi.org/10.1016/j.talanta.2018.03.016},
   keywords = {Deuterium oxide determination; Time-Resolved Luminescence Spectroscopy; Luminescence quenching; Ln(III) luminescence; Organic compounds luminescence},
   language = {eng},
   issn = {0039-9140},
   journal = {Talanta},
   title = {Determination of deuterium oxide content in water based on luminescence quenching},
   url = {https://www.sciencedirect.com/science/article/pii/S0039914018302534},
   volume = {184},
   year = {2018}
}

TY  - JOUR
ID  - 1419964
AU  - Kučera, Josef - Lubal, Přemysl - Lis, S. - Táborský, Petr
PY  - 2018
TI  - Determination of deuterium oxide content in water based on luminescence quenching
JF  - Talanta
VL  - 184
IS  - JUL
SP  - 364-368
EP  - 364-368
PB  - Elsevier
SN  - 00399140
KW  - Deuterium oxide determination
KW  - Time-Resolved Luminescence Spectroscopy
KW  - Luminescence quenching
KW  - Ln(III) luminescence
KW  - Organic compounds luminescence
UR  - https://www.sciencedirect.com/science/article/pii/S0039914018302534
L2  - https://www.sciencedirect.com/science/article/pii/S0039914018302534
N2  - Water molecules (H2O) often reduce luminescence lifetimes of various luminescence probes. The change of lifetime is usually caused by dynamic luminescence quenching induced by O-H oscillators which effectively take away energy from excited molecule. The process can be described by Stern-Volmer equation. We have studied selected luminescence systems where it is possible to detect considerable changes of lifetime in presence/absence of H2O and D2O in this work for analytical purposes. We have tested both, inorganic (Ln(3+)) and organic compounds using three different instrumentation in order to find the largest change between tau(H) and tau(D). The Ln(3+) containing systems have shown considerable increase/decrease of lifetimes in the presence/absence of D2O (Eu3+ : tau(D)/tau(H) = 34.5) whereas organic systems gave significantly lower values of tau(D)/tau(H) (coumarin 123 lifetime ratio, tau(D)/tau(H) = 1.94). The calculated LOD varied from 0.04 mol l(-1) (samarium nitrate) to 6.55 mol l(-1) (riboflavin).
ER  -

KUČERA, Josef; Přemysl LUBAL; S. LIS a Petr TÁBORSKÝ. Determination of deuterium oxide content in water based on luminescence quenching. \textit{Talanta}. AMSTERDAM: Elsevier, 2018, roč.~184, JUL, s.~364-368. ISSN~0039-9140. Dostupné z: https://doi.org/10.1016/j.talanta.2018.03.016.

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