Real-Time Structural and Optical Study of Growth and Packing
Behavior of Perylene Diimide Derivative Thin Films: Influence
of Side-Chain Modification

J 2018

Real-Time Structural and Optical Study of Growth and Packing Behavior of Perylene Diimide Derivative Thin Films: Influence of Side-Chain Modification

BELOVA, Valentina; Benjamin WAGNER; Berthold REISZ; Clemens ZEISER; Giuliano DUVA et al.

Základní údaje

Originální název

Real-Time Structural and Optical Study of Growth and Packing Behavior of Perylene Diimide Derivative Thin Films: Influence of Side-Chain Modification

Název česky

Studium strukturních a optických vlastností a molekulárního uspořádání v tenkých vrstvách derivátů perilenu diimidu: vliv modifikace bočního řetězce

Autoři

BELOVA, Valentina; Benjamin WAGNER; Berthold REISZ; Clemens ZEISER; Giuliano DUVA; Jakub ROZBOŘIL; Jiří NOVÁK; Alexander GERLACH; Alexander HINDERHOFER a Frank SCHREIBERT

Vydání

Journal of Physical Chemistry C, Washington D.C. American Chemical Society, 2018, 1932-7447

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10302 Condensed matter physics

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Full Text

Impakt faktor

Impact factor: 4.309

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/18:00103115

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova česky

organické polovodiče; deriváty perylen diimidu; tenké vrstvy; polymorfizmus; rtg difrakce; mikroskopie atomových sil; diferenční spektroskopie v odrazu; elipsometrie; teplotně závislá fotoluminiscence

Klíčová slova anglicky

organic semiconductors; perylene diimide derivatives; thin films; polymorphism; X-ray diffraction; atomic force microscopy; differential reflectance spectroscopy; ellipsometry; temperature-dependent photoluminescence

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 20. 1. 2020 17:04, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

We study the growth of two n-type small-molecule organic semiconductors from the perylene diimide family: N,N'-bis-(2-ethylhexyl)dicyanoperylene-3,4:9,10-bis(dicarboximide) (PDIR-CN2) and N,N'-1H,1H-perfluorobutyl-dicjyanoperylene-3,4: 9,10-bis (dicarboximide) (PDIF-CN2) whose chemical structures differ only in the imide substituents, branched alkyl chains -C8H16 and linear fluoroalkyl chains -C4F7H2, respectively. Both types of substituents introduce some degree of steric hindrance for intermolecular interactions, affecting solid-state packing during thin film formation, and thus induce specific structure-dependent optoelectronic properties in thin films. The transition from an amorphous structure to crystalline domains with strong intermolecular coupling was followed in situ and in real time during growth. We investigated the structural and morphological properties by X-ray diffraction and atomic force microscopy as a function of the substrate temperature and chemical structure. We examined the relationship between the structural properties and thin film optical signatures probed via differential reflectance spectroscopy, ellipsometry, and temperature-dependent photoluminescence. A new crystalline PDIR-CN2 polymorph at high temperatures emerges. In addition, we observed in PDIF-CN2 that the fluorinated chains contribute to crystallization inhibition because of the higher overall steric hindrance compared to the alkyl chains.

Návaznosti

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

7AMB16DE006, projekt VaV

Název: Studium struktur binárních směsí organických polovodičů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Studium struktur binárních směsí molekul organických polovodičů

Citovat

BELOVA, Valentina; Benjamin WAGNER; Berthold REISZ; Clemens ZEISER; Giuliano DUVA; Jakub ROZBOŘIL; Jiří NOVÁK; Alexander GERLACH; Alexander HINDERHOFER a Frank SCHREIBERT. Real-Time Structural and Optical Study of Growth and Packing Behavior of Perylene Diimide Derivative Thin Films: Influence of Side-Chain Modification. Journal of Physical Chemistry C. Washington D.C.: American Chemical Society, 2018, roč. 122, č. 15, s. 8589-8601. ISSN 1932-7447. Dostupné z: https://doi.org/10.1021/acs.jpcc.8b00787.

@article{1422235,
   author = {Belova, Valentina and Wagner, Benjamin and Reisz, Berthold and Zeiser, Clemens and Duva, Giuliano and Rozbořil, Jakub and Novák, Jiří and Gerlach, Alexander and Hinderhofer, Alexander and Schreibert, Frank},
   article_location = {Washington D.C.},
   article_number = {15},
   doi = {https://doi.org/10.1021/acs.jpcc.8b00787},
   keywords = {organic semiconductors; perylene diimide derivatives; thin films; polymorphism; X-ray diffraction; atomic force microscopy; differential reflectance spectroscopy; ellipsometry; temperature-dependent photoluminescence},
   language = {eng},
   issn = {1932-7447},
   journal = {Journal of Physical Chemistry C},
   title = {Real-Time Structural and Optical Study of Growth and Packing Behavior of Perylene Diimide Derivative Thin Films: Influence of Side-Chain Modification},
   url = {https://pubs.acs.org/doi/10.1021/acs.jpcc.8b00787},
   volume = {122},
   year = {2018}
}

TY  - JOUR
ID  - 1422235
AU  - Belova, Valentina - Wagner, Benjamin - Reisz, Berthold - Zeiser, Clemens - Duva, Giuliano - Rozbořil, Jakub - Novák, Jiří - Gerlach, Alexander - Hinderhofer, Alexander - Schreibert, Frank
PY  - 2018
TI  - Real-Time Structural and Optical Study of Growth and Packing Behavior of Perylene Diimide Derivative Thin Films: Influence of Side-Chain Modification
JF  - Journal of Physical Chemistry C
VL  - 122
IS  - 15
SP  - 8589-8601
EP  - 8589-8601
PB  - American Chemical Society
SN  - 19327447
KW  - organic semiconductors
KW  - perylene diimide derivatives
KW  - thin films
KW  - polymorphism
KW  - X-ray diffraction
KW  - atomic force microscopy
KW  - differential reflectance spectroscopy
KW  - ellipsometry
KW  - temperature-dependent photoluminescence
UR  - https://pubs.acs.org/doi/10.1021/acs.jpcc.8b00787
L2  - https://pubs.acs.org/doi/10.1021/acs.jpcc.8b00787
N2  - We study the growth of two n-type small-molecule organic semiconductors from the perylene diimide family: N,N'-bis-(2-ethylhexyl)dicyanoperylene-3,4:9,10-bis(dicarboximide) (PDIR-CN2) and N,N'-1H,1H-perfluorobutyl-dicjyanoperylene-3,4: 9,10-bis (dicarboximide) (PDIF-CN2) whose chemical structures differ only in the imide substituents, branched alkyl chains -C8H16 and linear fluoroalkyl chains -C4F7H2, respectively. Both types of substituents introduce some degree of steric hindrance for intermolecular interactions, affecting solid-state packing during thin film formation, and thus induce specific structure-dependent optoelectronic properties in thin films. The transition from an amorphous structure to crystalline domains with strong intermolecular coupling was followed in situ and in real time during growth. We investigated the structural and morphological properties by X-ray diffraction and atomic force microscopy as a function of the substrate temperature and chemical structure. We examined the relationship between the structural properties and thin film optical signatures probed via differential reflectance spectroscopy, ellipsometry, and temperature-dependent photoluminescence. A new crystalline PDIR-CN2 polymorph at high temperatures emerges. In addition, we observed in PDIF-CN2 that the fluorinated chains contribute to crystallization inhibition because of the higher overall steric hindrance compared to the alkyl chains.
ER  -

BELOVA, Valentina; Benjamin WAGNER; Berthold REISZ; Clemens ZEISER; Giuliano DUVA; Jakub ROZBOŘIL; Jiří NOVÁK; Alexander GERLACH; Alexander HINDERHOFER a Frank SCHREIBERT. Real-Time Structural and Optical Study of Growth and Packing Behavior of Perylene Diimide Derivative Thin Films: Influence of Side-Chain Modification. \textit{Journal of Physical Chemistry C}. Washington D.C.: American Chemical Society, 2018, roč.~122, č.~15, s.~8589-8601. ISSN~1932-7447. Dostupné z: https://doi.org/10.1021/acs.jpcc.8b00787.

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