Analysis of the products of a negative corona discharge in a
N-2-CH4 mixture with added CO2 used as a laboratory mimic of a
prebiotic atmosphere

J 2018

Analysis of the products of a negative corona discharge in a N-2-CH4 mixture with added CO2 used as a laboratory mimic of a prebiotic atmosphere

MAZÁNKOVÁ, Věra, Lucie TÖRÖKOVÁ, Ladislav MORAVSKÝ, Štefan MATEJČÍK, David TRUNEC et. al.

Základní údaje

Originální název

Analysis of the products of a negative corona discharge in a N-2-CH4 mixture with added CO2 used as a laboratory mimic of a prebiotic atmosphere

Název česky

Analýza produktů negativního koronového výboje ve směsi N2 - CH4 s přidaným CO2 použitým jako simulace prebiotické atmosféry

Autoři

MAZÁNKOVÁ, Věra (203 Česká republika), Lucie TÖRÖKOVÁ (203 Česká republika), Ladislav MORAVSKÝ (703 Slovensko), Štefan MATEJČÍK (703 Slovensko), David TRUNEC (203 Česká republika, garant, domácí), Zdeněk NAVRÁTIL (203 Česká republika, domácí) a Nigel MASON (826 Velká Británie a Severní Irsko)

Vydání

Contributions to Plasma Physics, WEINHEIM, GERMANY, WILEY-VCH Verlag GmbH & Co. KGaA, 2018, 0863-1042

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 1.234

Kód RIV

RIV/00216224:14310/18:00104753

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1002/ctpp.201700089

UT WoS

000450012400008

Klíčová slova anglicky

FTIR spectroscopy; negative corona discharge; prebiotic atmosphere

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 4. 2024 12:43, Mgr. Michal Petr

Anotace

V originále

A negative corona discharge operating at atmospheric pressure has been used to initiate chemical reactions in a gaseous mixture of nitrogen, methane, and carbon dioxide. Such a mixture simulates the composition of the early Earth's atmosphere. This work extends our previous experimental studies of the chemistry of prebiotic atmospheres generated in an atmospheric-pressure glow discharge. The present work is devoted to the study of the role of CO2 in prebiotic atmospheric chemistry. The gas mixture was composed of nitrogen with 2-4% methane and 1% CO2. The corona discharge was characterized by electrical measurements and optical emission spectroscopy. The reaction products from the discharge were further analysed by Fourier transform infrared (FTIR) spectroscopy. The composition of solid products deposited on the electrode tip was obtained by energy dispersive X-ray (EDX) analysis. The specific input energy was altered during the experiments, and the concentration of all products was found to increase with its increase. It is further shown that while the addition of the CO2 admixture leads to the generation of CO and H2O, no other compounds containing oxygen were detected. The energy yields of products were calculated, and good agreement was found with the values obtained in previous experiments.

Návaznosti

LO1411, projekt VaV

Název: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Akronym: CEPLANT plus)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

MAZÁNKOVÁ, Věra, Lucie TÖRÖKOVÁ, Ladislav MORAVSKÝ, Štefan MATEJČÍK, David TRUNEC, Zdeněk NAVRÁTIL a Nigel MASON. Analysis of the products of a negative corona discharge in a N-2-CH4 mixture with added CO2 used as a laboratory mimic of a prebiotic atmosphere. Contributions to Plasma Physics. WEINHEIM, GERMANY: WILEY-VCH Verlag GmbH & Co. KGaA, 2018, roč. 58, č. 10, s. 995-1004. ISSN 0863-1042. Dostupné z: https://dx.doi.org/10.1002/ctpp.201700089.

@article{1474536,
   author = {Mazánková, Věra and Töröková, Lucie and Moravský, Ladislav and Matejčík, Štefan and Trunec, David and Navrátil, Zdeněk and Mason, Nigel},
   article_location = {WEINHEIM, GERMANY},
   article_number = {10},
   doi = {http://dx.doi.org/10.1002/ctpp.201700089},
   keywords = {FTIR spectroscopy; negative corona discharge; prebiotic atmosphere},
   language = {eng},
   issn = {0863-1042},
   journal = {Contributions to Plasma Physics},
   title = {Analysis of the products of a negative corona discharge in a N-2-CH4 mixture with added CO2 used as a laboratory mimic of a prebiotic atmosphere},
   url = {http://dx.doi.org/10.1002/ctpp.201700089},
   volume = {58},
   year = {2018}
}

TY  - JOUR
ID  - 1474536
AU  - Mazánková, Věra - Töröková, Lucie - Moravský, Ladislav - Matejčík, Štefan - Trunec, David - Navrátil, Zdeněk - Mason, Nigel
PY  - 2018
TI  - Analysis of the products of a negative corona discharge in a N-2-CH4 mixture with added CO2 used as a laboratory mimic of a prebiotic atmosphere
JF  - Contributions to Plasma Physics
VL  - 58
IS  - 10
SP  - 995-1004
EP  - 995-1004
PB  - WILEY-VCH Verlag GmbH & Co. KGaA
SN  - 08631042
KW  - FTIR spectroscopy
KW  - negative corona discharge
KW  - prebiotic atmosphere
UR  - http://dx.doi.org/10.1002/ctpp.201700089
N2  - A negative corona discharge operating at atmospheric pressure has been used to initiate chemical reactions in a gaseous mixture of nitrogen, methane, and carbon dioxide. Such a mixture simulates the composition of the early Earth's atmosphere. This work extends our previous experimental studies of the chemistry of prebiotic atmospheres generated in an atmospheric-pressure glow discharge. The present work is devoted to the study of the role of CO2 in prebiotic atmospheric chemistry. The gas mixture was composed of nitrogen with 2-4% methane and 1% CO2. The corona discharge was characterized by electrical measurements and optical emission spectroscopy. The reaction products from the discharge were further analysed by Fourier transform infrared (FTIR) spectroscopy. The composition of solid products deposited on the electrode tip was obtained by energy dispersive X-ray (EDX) analysis. The specific input energy was altered during the experiments, and the concentration of all products was found to increase with its increase. It is further shown that while the addition of the CO2 admixture leads to the generation of CO and H2O, no other compounds containing oxygen were detected. The energy yields of products were calculated, and good agreement was found with the values obtained in previous experiments.
ER  -

MAZÁNKOVÁ, Věra, Lucie TÖRÖKOVÁ, Ladislav MORAVSKÝ, Štefan MATEJČÍK, David TRUNEC, Zdeněk NAVRÁTIL a Nigel MASON. Analysis of the products of a negative corona discharge in a N-2-CH4 mixture with added CO2 used as a laboratory mimic of a prebiotic atmosphere. \textit{Contributions to Plasma Physics}. WEINHEIM, GERMANY: WILEY-VCH Verlag GmbH \&{} Co. KGaA, 2018, roč.~58, č.~10, s.~995-1004. ISSN~0863-1042. Dostupné z: https://dx.doi.org/10.1002/ctpp.201700089.

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