Effect of bonding structure on hardness and fracture resistance
of W-B-C coatings with varying B/W ratio

J 2019

Effect of bonding structure on hardness and fracture resistance of W-B-C coatings with varying B/W ratio

MIRZAEI, Saeed; Mostafa ALISHAHI; Pavel SOUČEK; Lukáš ZÁBRANSKÝ; Vilma BURŠÍKOVÁ et al.

Základní údaje

Originální název

Effect of bonding structure on hardness and fracture resistance of W-B-C coatings with varying B/W ratio

Autoři

MIRZAEI, Saeed; Mostafa ALISHAHI; Pavel SOUČEK; Lukáš ZÁBRANSKÝ; Vilma BURŠÍKOVÁ; Monika STUPAVSKÁ; Vratislav PEŘINA; Katalin BALÁZSI; Zsolt CZIGÁNY a Petr VAŠINA

Vydání

Surface & coatings technology, Lausanne, Elsevier, 2019, 0257-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Full Text

Impakt faktor

Impact factor: 3.784

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/19:00107207

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Magnetron sputtering Protective coating Nanocomposite Hardness

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 11. 3. 2020 15:54, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Low ductility and brittle deformation behaviors are major drawbacks of currently used commercial hard ceramic-based protective coatings. Recent ab-initio calculations revealed that the coexistence of metallic, boride and carbide bonds in a nanolaminate structure of crystalline W2BC system provides a combination of high hardness together with moderate ductility. The present paper deals with coatings containing W, B and C with different compositions and investigates the effect of the boron to tungsten ratio (B/W) on the structural and mechanical properties of W-B-C coatings prepared by pulsed-DC magnetron sputtering at a moderate temperature. Coatings with low B/W were deposited in a nanocomposite structure, whereas coatings with high B/W ratios were near-amorphous. The structure of the coatings was not a decisive factor in determining their mechanical properties. These were, however, directly correlated with the chemical bonds present. All the coatings exhibited high fracture resistance. These properties together with good adhesion to cemented tungsten carbides make W-B-C coatings promising candidates for the future protective coatings of tools which undergo large deformation in their working cycle.

Návaznosti

ED2.1.00/03.0086, projekt VaV

Název: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

GA15-17875S, projekt VaV

Název: Lokální mikrostrukturní změny vyvolané statickou a dynamickou indentací nanostrukturovaných a nanolaminovaných povlaků

Investor: Grantová agentura ČR, Lokální mikrostrukturní změny vyvolané statickou a dynamickou indentací nanostrukturovaných a nanolaminovaných povlaků

LO1411, projekt VaV

Název: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Akronym: CEPLANT plus)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

MIRZAEI, Saeed; Mostafa ALISHAHI; Pavel SOUČEK; Lukáš ZÁBRANSKÝ; Vilma BURŠÍKOVÁ; Monika STUPAVSKÁ; Vratislav PEŘINA; Katalin BALÁZSI; Zsolt CZIGÁNY a Petr VAŠINA. Effect of bonding structure on hardness and fracture resistance of W-B-C coatings with varying B/W ratio. Surface & coatings technology. Lausanne: Elsevier, 2019, roč. 358, January, s. 843-849. ISSN 0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2018.12.007.

@article{1477417,
   author = {Mirzaei, Saeed and Alishahi, Mostafa and Souček, Pavel and Zábranský, Lukáš and Buršíková, Vilma and Stupavská, Monika and Peřina, Vratislav and Balázsi, Katalin and Czigány, Zsolt and Vašina, Petr},
   article_location = {Lausanne},
   article_number = {January},
   doi = {https://doi.org/10.1016/j.surfcoat.2018.12.007},
   keywords = {Magnetron sputtering Protective coating Nanocomposite Hardness},
   language = {eng},
   issn = {0257-8972},
   journal = {Surface & coatings technology},
   title = {Effect of bonding structure on hardness and fracture resistance of W-B-C coatings with varying B/W ratio},
   url = {https://www.sciencedirect.com/science/article/pii/S0257897218313185},
   volume = {358},
   year = {2019}
}

TY  - JOUR
ID  - 1477417
AU  - Mirzaei, Saeed - Alishahi, Mostafa - Souček, Pavel - Zábranský, Lukáš - Buršíková, Vilma - Stupavská, Monika - Peřina, Vratislav - Balázsi, Katalin - Czigány, Zsolt - Vašina, Petr
PY  - 2019
TI  - Effect of bonding structure on hardness and fracture resistance of W-B-C coatings with varying B/W ratio
JF  - Surface & coatings technology
VL  - 358
IS  - January
SP  - 843-849
EP  - 843-849
PB  - Elsevier
SN  - 02578972
KW  - Magnetron sputtering Protective coating Nanocomposite Hardness
UR  - https://www.sciencedirect.com/science/article/pii/S0257897218313185
L2  - https://www.sciencedirect.com/science/article/pii/S0257897218313185
N2  - Low ductility and brittle deformation behaviors are major drawbacks of currently used commercial hard ceramic-based protective coatings. Recent ab-initio calculations revealed that the coexistence of metallic, boride and carbide bonds in a nanolaminate structure of crystalline W2BC system provides a combination of high hardness together with moderate ductility. The present paper deals with coatings containing W, B and C with different compositions and investigates the effect of the boron to tungsten ratio (B/W) on the structural and mechanical properties of W-B-C coatings prepared by pulsed-DC magnetron sputtering at a moderate temperature. Coatings with low B/W were deposited in a nanocomposite structure, whereas coatings with high B/W ratios were near-amorphous. The structure of the coatings was not a decisive factor in determining their mechanical properties. These were, however, directly correlated with the chemical bonds present. All the coatings exhibited high fracture resistance. These properties together with good adhesion to cemented tungsten carbides make W-B-C coatings promising candidates for the future protective coatings of tools which undergo large deformation in their working cycle.
ER  -

MIRZAEI, Saeed; Mostafa ALISHAHI; Pavel SOUČEK; Lukáš ZÁBRANSKÝ; Vilma BURŠÍKOVÁ; Monika STUPAVSKÁ; Vratislav PEŘINA; Katalin BALÁZSI; Zsolt CZIGÁNY a Petr VAŠINA. Effect of bonding structure on hardness and fracture resistance of W-B-C coatings with varying B/W ratio. \textit{Surface \&{} coatings technology}. Lausanne: Elsevier, 2019, roč.~358, January, s.~843-849. ISSN~0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2018.12.007.

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