Distinct Speciation of Naphthalene Vapor Deposited on Ice
Surfaces at 253 or 77 K: Formation of Submicrometer-Sized
Crystals or an Amorphous Layer

J 2018

Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer

ONDRUŠKOVÁ, Gabriela; Ján KRAUSKO; Josef N. STERN; Astrid HAUPTMANN; Thomas LOERTING et. al.

Základní údaje

Originální název

Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer

Autoři

ONDRUŠKOVÁ, Gabriela; Ján KRAUSKO; Josef N. STERN; Astrid HAUPTMANN; Thomas LOERTING a Dominik HEGER

Vydání

Journal of Physical Chemistry C, Washington D.C. American Chemical Society, 2018, 1932-7447

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.309

Kód RIV

RIV/00216224:14310/18:00101696

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1021/acs.jpcc.8b03972

UT WoS

000435020300039

EID Scopus

2-s2.0-85046978766

Klíčová slova anglicky

POLYCYCLIC AROMATIC-HYDROCARBONS; EXPERIMENTAL-COMPUTATIONAL APPROACH; ACETIC-ACID; NITRIC-ACID; SPECTROSCOPIC PROPERTIES; HYDROGEN-CHLORIDE; ATMOSPHERIC CHEMISTRY; FLUORESCENCE-SPECTRA; PHYSICAL ADSORPTION; ORGANIC-MOLECULES

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 9. 2. 2019 11:43, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Naphthalene was deposited from the vapor phase on ice surfaces at 77 or 253 K to yield strongly distinct behavior, forming either an amorphous glass layer or submicrometer-sized crystals, respectively. The results stand upon optical emission spectroscopy combined with differential scanning calorimetry and X-ray analysis. The amorphous layer of naphthalene on the ice behaves in the same manner as on an inert metallic support: it starts to relax at 105 K and crystallizes at 185 K. The formed microcrystals exhibit distinct absorption behavior on the ice surface and are thus expected to have a photokinetic profile varying from freeze-concentrated solutions. The observations bring implications toward environmental and extraterrestrial ice sciences.

Návaznosti

CZ.02.1.01/0.0/0.0/16_013/0001761, interní kód MU

Název: RECETOX RI - OP VVV (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, RECETOX RI - OP VVV, PO 1 Posilování kapacit pro kvalitní výzkum

GA15-12386S, projekt VaV

Název: Dynamika a (foto)chemie polutantů na rozhraních led/vzduch a voda/vzduch z experimentu i teorie

Investor: Grantová agentura ČR, Dynamika a (foto)chemie polutantů na rozhraních led/vzduch a voda/vzduch z experimentu i teorie

LM2015051, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX RI)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Výzkumná infrastruktura RECETOX

Citovat

ONDRUŠKOVÁ, Gabriela; Ján KRAUSKO; Josef N. STERN; Astrid HAUPTMANN; Thomas LOERTING a Dominik HEGER. Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer. Journal of Physical Chemistry C. Washington D.C.: American Chemical Society, 2018, roč. 122, č. 22, s. 11945-11953. ISSN 1932-7447. Dostupné z: https://doi.org/10.1021/acs.jpcc.8b03972.

@article{1495400,
   author = {Ondrušková, Gabriela and Krausko, Ján and Stern, Josef N. and Hauptmann, Astrid and Loerting, Thomas and Heger, Dominik},
   article_location = {Washington D.C.},
   article_number = {22},
   doi = {https://doi.org/10.1021/acs.jpcc.8b03972},
   keywords = {POLYCYCLIC AROMATIC-HYDROCARBONS; EXPERIMENTAL-COMPUTATIONAL APPROACH; ACETIC-ACID; NITRIC-ACID; SPECTROSCOPIC PROPERTIES; HYDROGEN-CHLORIDE; ATMOSPHERIC CHEMISTRY; FLUORESCENCE-SPECTRA; PHYSICAL ADSORPTION; ORGANIC-MOLECULES},
   language = {eng},
   issn = {1932-7447},
   journal = {Journal of Physical Chemistry C},
   title = {Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer},
   url = {https://pubs.acs.org/doi/10.1021/acs.jpcc.8b03972},
   volume = {122},
   year = {2018}
}

TY  - JOUR
ID  - 1495400
AU  - Ondrušková, Gabriela - Krausko, Ján - Stern, Josef N. - Hauptmann, Astrid - Loerting, Thomas - Heger, Dominik
PY  - 2018
TI  - Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer
JF  - Journal of Physical Chemistry C
VL  - 122
IS  - 22
SP  - 11945-11953
EP  - 11945-11953
PB  - American Chemical Society
SN  - 19327447
KW  - POLYCYCLIC AROMATIC-HYDROCARBONS
KW  - EXPERIMENTAL-COMPUTATIONAL APPROACH
KW  - ACETIC-ACID
KW  - NITRIC-ACID
KW  - SPECTROSCOPIC PROPERTIES
KW  - HYDROGEN-CHLORIDE
KW  - ATMOSPHERIC CHEMISTRY
KW  - FLUORESCENCE-SPECTRA
KW  - PHYSICAL ADSORPTION
KW  - ORGANIC-MOLECULES
UR  - https://pubs.acs.org/doi/10.1021/acs.jpcc.8b03972
L2  - https://pubs.acs.org/doi/10.1021/acs.jpcc.8b03972
N2  - Naphthalene was deposited from the vapor phase on ice surfaces at 77 or 253 K to yield strongly distinct behavior, forming either an amorphous glass layer or submicrometer-sized crystals, respectively. The results stand upon optical emission spectroscopy combined with differential scanning calorimetry and X-ray analysis. The amorphous layer of naphthalene on the ice behaves in the same manner as on an inert metallic support: it starts to relax at 105 K and crystallizes at 185 K. The formed microcrystals exhibit distinct absorption behavior on the ice surface and are thus expected to have a photokinetic profile varying from freeze-concentrated solutions. The observations bring implications toward environmental and extraterrestrial ice sciences.
ER  -

ONDRUŠKOVÁ, Gabriela; Ján KRAUSKO; Josef N. STERN; Astrid HAUPTMANN; Thomas LOERTING a Dominik HEGER. Distinct Speciation of Naphthalene Vapor Deposited on Ice Surfaces at 253 or 77 K: Formation of Submicrometer-Sized Crystals or an Amorphous Layer. \textit{Journal of Physical Chemistry C}. Washington D.C.: American Chemical Society, 2018, roč.~122, č.~22, s.~11945-11953. ISSN~1932-7447. Dostupné z: https://doi.org/10.1021/acs.jpcc.8b03972.

Přehled o publikaci