Alumazene Reactivity with Quinolinols - Addition and
Substitution Reactions on the Al3N3 Ring

J 2018

Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring

KOLLHAMMEROVÁ, Iva; Michal BABIAK; Marek NEČAS; Petr TÁBORSKÝ; Josef KUČERA et. al.

Základní údaje

Originální název

Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring

Autoři

KOLLHAMMEROVÁ, Iva; Michal BABIAK; Marek NEČAS; Petr TÁBORSKÝ; Josef KUČERA a Jiří PINKAS

Vydání

Acta Chimica Slovenica, LJUBLJANA, SLOVENSKO KEMIJSKO DRUSTVO, 2018, 1318-0207

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Slovinsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 1.076

Kód RIV

RIV/00216224:14310/18:00106568

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.17344/acsi.2018.4624

UT WoS

000453240200020

EID Scopus

2-s2.0-85061330652

Klíčová slova anglicky

Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence

Štítky

CF SAXS, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 23. 4. 2024 14:28, Mgr. Michal Petr

Anotace

V originále

Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.

Návaznosti

LM2015043, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

Citovat

KOLLHAMMEROVÁ, Iva; Michal BABIAK; Marek NEČAS; Petr TÁBORSKÝ; Josef KUČERA a Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. Acta Chimica Slovenica. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, roč. 65, č. 4, s. 955-963. ISSN 1318-0207. Dostupné z: https://doi.org/10.17344/acsi.2018.4624.

@article{1504916,
   author = {Kollhammerová, Iva and Babiak, Michal and Nečas, Marek and Táborský, Petr and Kučera, Josef and Pinkas, Jiří},
   article_location = {LJUBLJANA},
   article_number = {4},
   doi = {https://doi.org/10.17344/acsi.2018.4624},
   keywords = {Alumazene; crystal structure; quinolin-8-ol; 2-methylquinolin-8-ol; luminescence},
   language = {eng},
   issn = {1318-0207},
   journal = {Acta Chimica Slovenica},
   title = {Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring},
   url = {http://dx.doi.org/10.17344/acsi.2018.4624},
   volume = {65},
   year = {2018}
}

TY  - JOUR
ID  - 1504916
AU  - Kollhammerová, Iva - Babiak, Michal - Nečas, Marek - Táborský, Petr - Kučera, Josef - Pinkas, Jiří
PY  - 2018
TI  - Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring
JF  - Acta Chimica Slovenica
VL  - 65
IS  - 4
SP  - 955-963
EP  - 955-963
PB  - SLOVENSKO KEMIJSKO DRUSTVO
SN  - 13180207
KW  - Alumazene
KW  - crystal structure
KW  - quinolin-8-ol
KW  - 2-methylquinolin-8-ol
KW  - luminescence
UR  - http://dx.doi.org/10.17344/acsi.2018.4624
N2  - Molecular structures of two compounds obtained in reactions of alumazene [DippNAIMe](3) (1, Dipp = 2,6-i-Pr2C6H3) with substituted quinolinols have been elucidated by the single-crystal X-ray diffraction analysis. Quinolin-8-ol (Hq) provides a dinuclear complex [(DippNH)(2)Al2Me2(q)(2)] (2) with a central Al2O2 ring and five-coordinate Al atoms. The compound 2 center dot THF crystallizes in the orthorhombic Pbca space group. The molecular structure of a mononuclear complex [(DippNH)Al(Meq)(2)] (3) obtained in the reaction of 1 with 2-methylquinolin-8-ol (HMeq) possesses a five-coordinate Al center. The structure was solved in a triclinic cell P-1. The dinuclear complex 2 can be considered as a model product of alcohol addition on the formal Al-N double bond, while the mononuclear complex 3 represents subsequent reaction of remaining Al-Me moiety with proton. Both complexes 2 and 3 are highly luminescent showing emission around 500 nm in solid state.
ER  -

KOLLHAMMEROVÁ, Iva; Michal BABIAK; Marek NEČAS; Petr TÁBORSKÝ; Josef KUČERA a Jiří PINKAS. Alumazene Reactivity with Quinolinols - Addition and Substitution Reactions on the Al3N3 Ring. \textit{Acta Chimica Slovenica}. LJUBLJANA: SLOVENSKO KEMIJSKO DRUSTVO, 2018, roč.~65, č.~4, s.~955-963. ISSN~1318-0207. Dostupné z: https://doi.org/10.17344/acsi.2018.4624.

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