J 2019

Jahnsite-(MnMnZn), a new jahnsite-group mineral, and formal approval of the jahnsite group

KAMPF, Anthony R.; Pedro ALVES; Anatoly KASATKIN a Radek ŠKODA

Základní údaje

Originální název

Jahnsite-(MnMnZn), a new jahnsite-group mineral, and formal approval of the jahnsite group

Autoři

KAMPF, Anthony R.; Pedro ALVES; Anatoly KASATKIN a Radek ŠKODA

Vydání

European Journal of Mineralogy, Stuttgart, E SCHWEIZERBARTSCHE VERLAGSBUCHHANDLUNG, 2019, 0935-1221

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Impakt faktor

Impact factor: 1.665

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/19:00111302

Organizační jednotka

Přírodovědecká fakulta

EID Scopus

Klíčová slova anglicky

Jahnsite-(MnMnZn); new mineral; jahnsite-group; crystal structure; Raman spectroscopy; Herdade dos Pendoes mine; Portugal

Štítky

Příznaky

Mezinárodní význam, Recenzováno
Změněno: 26. 3. 2020 13:47, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Jahnsite-(MnNInZn) (IMA2017-113), Mn(2)(2+)Zn2Fe(3)(2+)(PO4)(4)(OH)(2) center dot 8H(2)O, is a new member of the jahnsite group from the Herdade dos Pendries mine, Beja district, southwest Portugal. It formed in a highly altered gossan in association with Zn-bearing libethenite, quartz, rhodochrosite and santabarbaraite. It occurs in sub-parallel bundles of light golden brown prisms up to 0.3 mm long. Crystals are transparent with vitreous to silky lustre and white streak. The mineral is brittle with irregular, splintery fracture, good cleavage parallel to {001} and Mohs' hardness of about 4. The measured density is 2.89(2) g cm(-3). Optically, it is biaxial (+), with alpha = 1.655(2), beta = 1.662(2), gamma = 1.673(2) (white light); 2V = 78(1)degrees; pleochroism: X nearly colourless, Y and Z beige; X < Y approximate to Z. Electron microprobe analyses gave the empirical formula (Mn0.712+Na0.15Ca0.10)Sigma(0.96) (Mn-1.00(2+)) (Zn1.00Mn0.662+Fe0.212+Mg0.10Fe0.033+)(Sigma 2.00)(Fe1.993+Al0.01)(Sigma 2.00)(P1.01O4)(4)(OH)(2) center dot 8H(2)O. Jahnsite-(MnMnZn) is monoclinic, P2/a, a = 15.222(6), b = 7.187(6), c = 10.028(5) angstrom, beta = 111.746(16)degrees, V = 1019.0(11) angstrom(3) and Z = 2. The eight strongest lines in the X-ray powder diffraction pattern are [d(obs)/angstrom (I) (hkl)]: 9.25 (63) (001), 5.00 (40) (210,21 (1) over bar ,111), 4.648 (33) (002), 3.509 (41) (40 (2) over bar), 2.842 (100) (022), 1.9984 (37) (422,42 (4) over bar), 1.9506 (30) (024) and 1.5853 (33) (820,82 (4) over bar). The jahnsite group has now been officially established by the Commission on New Minerals, Nomenclature and Classification. The general formula for jahnsite-group minerals is XM1M2(2)M3(2)(H2O)(8)(OH)(2)(PO4)(4); the ionic radii for the cation sites generally increase as follows: M3 < M2 < M1 < X, and the M3 site determines whether the species belongs to the jahnsite subgroup (M3 = Fe3+) or the whiteite subgroup (M3 = Al). The subgroup name is generally used as the species root name to be followed by a suffix of the form-(XM1M2). Using this as a guide for the jahnsite described herein results in the following site assignments: X = Mn, M1 = Mn, M2 = Zn, and M3 = Fe; and the name jahnsite-(MnMnZn).