Cubane Arrives on the Cucurbituril Scene

J 2017

Cubane Arrives on the Cucurbituril Scene

JELINKOVA, Kristyna, Heda SURMOVA, Alena MATELOVA, Michal ROUCHAL, Zdenka PRUCKOVA et. al.

Základní údaje

Originální název

Cubane Arrives on the Cucurbituril Scene

Autoři

JELINKOVA, Kristyna, Heda SURMOVA, Alena MATELOVA, Michal ROUCHAL, Zdenka PRUCKOVA, Lenka DASTYCHOVA, Marek NEČAS (203 Česká republika, domácí) a Robert VICHA (garant)

Vydání

Organic Letters, WASHINGTON, American Chemical Society, 2017, 1523-7060

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10401 Organic chemistry

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Full Text

Impakt faktor

Impact factor: 6.492

Kód RIV

RIV/00216224:14310/17:00111640

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1021/acs.orglett.7b01029

UT WoS

000402023500061

Klíčová slova anglicky

Cubane; Wales; Molecular dynamics

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 11. 12. 2019 15:40, Mgr. Marie Šípková, DiS.

Anotace

V originále

Cubane, an intriguing chemical curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds. The first dicationic supramolecular guest 5 is prepared and derived from a 1,4-disubstituted cubane moiety, and its binding behavior toward cucurbit[n]urils (CBn) and cyclodextrins (CD) is studied. The bisimidazolium salt 5 forms 1:1 inclusion complexes with CB7, CB8, and beta-CD with the respective association constants (6.7 +/- 0.5) X 10(11) M-1, (1.5 +/- 0.2) X 109 M-1, and <10(2) M-1 in water. The solid-state structures of the 5@CB7 and 5@CB8 complexes are also reported.

Návaznosti

LM2015043, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

Citovat

JELINKOVA, Kristyna, Heda SURMOVA, Alena MATELOVA, Michal ROUCHAL, Zdenka PRUCKOVA, Lenka DASTYCHOVA, Marek NEČAS a Robert VICHA. Cubane Arrives on the Cucurbituril Scene. Organic Letters. WASHINGTON: American Chemical Society, 2017, roč. 19, č. 10, s. 2698-2701. ISSN 1523-7060. Dostupné z: https://dx.doi.org/10.1021/acs.orglett.7b01029.

@article{1590621,
   author = {Jelinkova, Kristyna and Surmova, Heda and Matelova, Alena and Rouchal, Michal and Pruckova, Zdenka and Dastychova, Lenka and Nečas, Marek and Vicha, Robert},
   article_location = {WASHINGTON},
   article_number = {10},
   doi = {http://dx.doi.org/10.1021/acs.orglett.7b01029},
   keywords = {Cubane; Wales; Molecular dynamics},
   language = {eng},
   issn = {1523-7060},
   journal = {Organic Letters},
   title = {Cubane Arrives on the Cucurbituril Scene},
   url = {https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.7b01029},
   volume = {19},
   year = {2017}
}

TY  - JOUR
ID  - 1590621
AU  - Jelinkova, Kristyna - Surmova, Heda - Matelova, Alena - Rouchal, Michal - Pruckova, Zdenka - Dastychova, Lenka - Nečas, Marek - Vicha, Robert
PY  - 2017
TI  - Cubane Arrives on the Cucurbituril Scene
JF  - Organic Letters
VL  - 19
IS  - 10
SP  - 2698-2701
EP  - 2698-2701
PB  - American Chemical Society
SN  - 15237060
KW  - Cubane
KW  - Wales
KW  - Molecular dynamics
UR  - https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.7b01029
L2  - https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.7b01029
N2  - Cubane, an intriguing chemical curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds. The first dicationic supramolecular guest 5 is prepared and derived from a 1,4-disubstituted cubane moiety, and its binding behavior toward cucurbit[n]urils (CBn) and cyclodextrins (CD) is studied. The bisimidazolium salt 5 forms 1:1 inclusion complexes with CB7, CB8, and beta-CD with the respective association constants (6.7 +/- 0.5) X 10(11) M-1, (1.5 +/- 0.2) X 109 M-1, and <10(2) M-1 in water. The solid-state structures of the 5@CB7 and 5@CB8 complexes are also reported.
ER  -

JELINKOVA, Kristyna, Heda SURMOVA, Alena MATELOVA, Michal ROUCHAL, Zdenka PRUCKOVA, Lenka DASTYCHOVA, Marek NEČAS a Robert VICHA. Cubane Arrives on the Cucurbituril Scene. \textit{Organic Letters}. WASHINGTON: American Chemical Society, 2017, roč.~19, č.~10, s.~2698-2701. ISSN~1523-7060. Dostupné z: https://dx.doi.org/10.1021/acs.orglett.7b01029.

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