Layer-by-layer assembly of thin organic films on PTFE activated
by cold atmospheric plasma

J 2015

Layer-by-layer assembly of thin organic films on PTFE activated by cold atmospheric plasma

TÓTH, Andras; Klára SZENTMIHÁLYI; Zsófia KERESZTES; Imola SZIGYÁRTÓ; Dušan KOVÁČIK et al.

Základní údaje

Originální název

Layer-by-layer assembly of thin organic films on PTFE activated by cold atmospheric plasma

Autoři

TÓTH, Andras; Klára SZENTMIHÁLYI; Zsófia KERESZTES; Imola SZIGYÁRTÓ; Dušan KOVÁČIK; Mirko ČERNÁK a Kinga KUTASI

Vydání

Open chemistry, Warsaw, DE GRUYTER OPEN LTD, 2015, 2391-5420

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Polsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

Full Text

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/15:00112265

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

DCSBD plasma; Polytetrafluoroethylene surface; Polyvinylpyrrolidone and tannic acid layers; ATR-FTIR; XPS; AFM

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 11. 5. 2020 10:34, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

An air diffuse coplanar surface barrier discharge is used to activate the surface of polytetrafluoroethylene (PTFE) samples, which are subsequently coated with polyvinylpyrrolidone (PVP) and tannic acid (TAN) single, bi- and multilayers, respectively, using the dip-coating method. The surfaces are characterized by X-ray Photoelectron Spectroscopy (XPS), Attenuated Total Reflection - Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Atomic Force Microscopy (AFM). The XPS measurements show that with plasma treatment the F/C atomic ratio in the PTFE surface decreases, due to the diminution of the concentration of CF2 moieties, and also oxygen incorporation through formation of new C-O, C=O and O=C-O bonds can be observed. In the case of coated samples, the new bonds indicated by XPS show the bonding between the organic layer and the surface, and thus the stability of layers, while the gradual decrease of the concentration of F atoms with the number of deposited layers proves the creation of PVP/TAN bi- and multi-layers. According to the ATR-FTIR spectra, in the case of PVP/TAN multilayer hydrogen bonding develops between the PVP and TAN, which assures the stability of the multilayer. The AFM lateral friction measurements show that the macromolecular layers homogeneously coat the plasma treated PTFE surface.

Citovat

TÓTH, Andras; Klára SZENTMIHÁLYI; Zsófia KERESZTES; Imola SZIGYÁRTÓ; Dušan KOVÁČIK; Mirko ČERNÁK a Kinga KUTASI. Layer-by-layer assembly of thin organic films on PTFE activated by cold atmospheric plasma. Open chemistry. Warsaw: DE GRUYTER OPEN LTD, 2015, roč. 13, č. 1, s. 557-563. ISSN 2391-5420. Dostupné z: https://doi.org/10.1515/chem-2015-0072.

@article{1601756,
   author = {Tóth, Andras and Szentmihályi, Klára and Keresztes, Zsófia and Szigyártó, Imola and Kováčik, Dušan and Černák, Mirko and Kutasi, Kinga},
   article_location = {Warsaw},
   article_number = {1},
   doi = {https://doi.org/10.1515/chem-2015-0072},
   keywords = {DCSBD plasma; Polytetrafluoroethylene surface; Polyvinylpyrrolidone and tannic acid layers; ATR-FTIR; XPS; AFM},
   language = {eng},
   issn = {2391-5420},
   journal = {Open chemistry},
   title = {Layer-by-layer assembly of thin organic films on PTFE activated by cold atmospheric plasma},
   url = {https://www.degruyter.com/downloadpdf/j/chem.2015.13.issue-1/chem-2015-0072/chem-2015-0072.pdf},
   volume = {13},
   year = {2015}
}

TY  - JOUR
ID  - 1601756
AU  - Tóth, Andras - Szentmihályi, Klára - Keresztes, Zsófia - Szigyártó, Imola - Kováčik, Dušan - Černák, Mirko - Kutasi, Kinga
PY  - 2015
TI  - Layer-by-layer assembly of thin organic films on PTFE activated by cold atmospheric plasma
JF  - Open chemistry
VL  - 13
IS  - 1
SP  - 557-563
EP  - 557-563
PB  - DE GRUYTER OPEN LTD
SN  - 23915420
KW  - DCSBD plasma
KW  - Polytetrafluoroethylene surface
KW  - Polyvinylpyrrolidone and tannic acid layers
KW  - ATR-FTIR
KW  - XPS
KW  - AFM
UR  - https://www.degruyter.com/downloadpdf/j/chem.2015.13.issue-1/chem-2015-0072/chem-2015-0072.pdf
L2  - https://www.degruyter.com/downloadpdf/j/chem.2015.13.issue-1/chem-2015-0072/chem-2015-0072.pdf
N2  - An air diffuse coplanar surface barrier discharge is used to activate the surface of polytetrafluoroethylene (PTFE) samples, which are subsequently coated with polyvinylpyrrolidone (PVP) and tannic acid (TAN) single, bi- and multilayers, respectively, using the dip-coating method. The surfaces are characterized by X-ray Photoelectron Spectroscopy (XPS), Attenuated Total Reflection - Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Atomic Force Microscopy (AFM). The XPS measurements show that with plasma treatment the F/C atomic ratio in the PTFE surface decreases, due to the diminution of the concentration of CF2 moieties, and also oxygen incorporation through formation of new C-O, C=O and O=C-O bonds can be observed. In the case of coated samples, the new bonds indicated by XPS show the bonding between the organic layer and the surface, and thus the stability of layers, while the gradual decrease of the concentration of F atoms with the number of deposited layers proves the creation of PVP/TAN bi- and multi-layers. According to the ATR-FTIR spectra, in the case of PVP/TAN multilayer hydrogen bonding develops between the PVP and TAN, which assures the stability of the multilayer. The AFM lateral friction measurements show that the macromolecular layers homogeneously coat the plasma treated PTFE surface.
ER  -

TÓTH, Andras; Klára SZENTMIHÁLYI; Zsófia KERESZTES; Imola SZIGYÁRTÓ; Dušan KOVÁČIK; Mirko ČERNÁK a Kinga KUTASI. Layer-by-layer assembly of thin organic films on PTFE activated by cold atmospheric plasma. \textit{Open chemistry}. Warsaw: DE GRUYTER OPEN LTD, 2015, roč.~13, č.~1, s.~557-563. ISSN~2391-5420. Dostupné z: https://doi.org/10.1515/chem-2015-0072.

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