Deducing rotational quantum-state distributions from
overlapping molecular spectra

J 2019

Deducing rotational quantum-state distributions from overlapping molecular spectra

VORÁČ, Jan; Lukáš KUSÝN a Petr SYNEK

Základní údaje

Originální název

Deducing rotational quantum-state distributions from overlapping molecular spectra

Autoři

VORÁČ, Jan (203 Česká republika, garant, domácí); Lukáš KUSÝN (203 Česká republika, domácí) a Petr SYNEK (203 Česká republika, domácí)

Vydání

REVIEW OF SCIENTIFIC INSTRUMENTS, AMER INST PHYSICS, 2019, 0034-6748

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Spojené státy

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 1.480

Kód RIV

RIV/00216224:14310/19:00108103

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1063/1.5128455

UT WoS

000504106500006

EID Scopus

2-s2.0-85075910227

Klíčová slova anglicky

DIELECTRIC BARRIER DISCHARGE; ATOMIC-ABSORPTION-SPECTROMETRY; TRANSITION-PROBABILITIES; TEMPERATURE; RATIO; AIR; 1ST

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 31. 3. 2020 20:47, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

A novel method for fast and robust calculation of Boltzmann plots from molecular spectra is presented. Its use is demonstrated on the OH(A-X) spectrum near 310 nm. A limitation of the method is identified: for overlapping spectra of the OH(A-X) and N-2(C-B, Delta v = 1) band sequence, the calculation may often fail due to insufficient number of measured points. This is solved by introducing experimentally determined bounds for the N-2(C) rotational distribution. Three cases are presented: (i) with undisturbed OH(A-X) emission, (ii) with strong emission of N-2(C-B) in the said spectral range, and (iii) with weak but not negligible nitrogen emission. In case (ii), the data in the spectral range 306-320 nm are sufficient for the analysis. In case (iii), information from another spectral range with undisturbed N-2(C-B) emission is necessary. These illustrate all relevant cases often encountered in laboratory plasmas. The calculated Boltzmann plots are not further analyzed in this article but can be used for development and validation of kinetic models with rotational resolution. The implementation of the reported method using the massiveOES software package written in the Python language is available in the https://doi.org/10.1063/1.5128455#suppl supplementary material.

Návaznosti

GA17-04329S, projekt VaV

Název: Atomizátory hydridů pro atomovou absorpční a atomovou fluorescenční spektrometrii - nové horizonty

Investor: Grantová agentura ČR, Atomizátory hydridů pro pro atomovou absorpční a atomovou fluorescenční spektrometrii - nové horizonty

LO1411, projekt VaV

Název: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Akronym: CEPLANT plus)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

VORÁČ, Jan; Lukáš KUSÝN a Petr SYNEK. Deducing rotational quantum-state distributions from overlapping molecular spectra. REVIEW OF SCIENTIFIC INSTRUMENTS. AMER INST PHYSICS, 2019, roč. 90, č. 12, s. 1-10. ISSN 0034-6748. Dostupné z: https://doi.org/10.1063/1.5128455.

@article{1608219,
   author = {Voráč, Jan and Kusýn, Lukáš and Synek, Petr},
   article_number = {12},
   doi = {https://doi.org/10.1063/1.5128455},
   keywords = {DIELECTRIC BARRIER DISCHARGE; ATOMIC-ABSORPTION-SPECTROMETRY; TRANSITION-PROBABILITIES; TEMPERATURE; RATIO; AIR; 1ST},
   language = {eng},
   issn = {0034-6748},
   journal = {REVIEW OF SCIENTIFIC INSTRUMENTS},
   title = {Deducing rotational quantum-state distributions from overlapping molecular spectra},
   url = {https://doi.org/10.1063/1.5128455},
   volume = {90},
   year = {2019}
}

TY  - JOUR
ID  - 1608219
AU  - Voráč, Jan - Kusýn, Lukáš - Synek, Petr
PY  - 2019
TI  - Deducing rotational quantum-state distributions from overlapping molecular spectra
JF  - REVIEW OF SCIENTIFIC INSTRUMENTS
VL  - 90
IS  - 12
SP  - 1-10
EP  - 1-10
PB  - AMER INST PHYSICS
SN  - 00346748
KW  - DIELECTRIC BARRIER DISCHARGE
KW  - ATOMIC-ABSORPTION-SPECTROMETRY
KW  - TRANSITION-PROBABILITIES
KW  - TEMPERATURE
KW  - RATIO
KW  - AIR
KW  - 1ST
UR  - https://doi.org/10.1063/1.5128455
L2  - https://doi.org/10.1063/1.5128455
N2  - A novel method for fast and robust calculation of Boltzmann plots from molecular spectra is presented. Its use is demonstrated on the OH(A-X) spectrum near 310 nm. A limitation of the method is identified: for overlapping spectra of the OH(A-X) and N-2(C-B, Delta v = 1) band sequence, the calculation may often fail due to insufficient number of measured points. This is solved by introducing experimentally determined bounds for the N-2(C) rotational distribution. Three cases are presented: (i) with undisturbed OH(A-X) emission, (ii) with strong emission of N-2(C-B) in the said spectral range, and (iii) with weak but not negligible nitrogen emission. In case (ii), the data in the spectral range 306-320 nm are sufficient for the analysis. In case (iii), information from another spectral range with undisturbed N-2(C-B) emission is necessary. These illustrate all relevant cases often encountered in laboratory plasmas. The calculated Boltzmann plots are not further analyzed in this article but can be used for development and validation of kinetic models with rotational resolution. The implementation of the reported method using the massiveOES software package written in the Python language is available in the https://doi.org/10.1063/1.5128455#suppl supplementary material.
ER  -

VORÁČ, Jan; Lukáš KUSÝN a Petr SYNEK. Deducing rotational quantum-state distributions from overlapping molecular spectra. \textit{REVIEW OF SCIENTIFIC INSTRUMENTS}. AMER INST PHYSICS, 2019, roč.~90, č.~12, s.~1-10. ISSN~0034-6748. Dostupné z: https://doi.org/10.1063/1.5128455.

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