Analysis of alkylphenols and bisphenols in soils using liquid
chromatography-tandem mass spectrometry

J 2021

Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry

PERNICA, Marek; Romana LESNIÁKOVÁ; Denisa DOLEŽALOVÁ a Zdeněk ŠIMEK

Základní údaje

Originální název

Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry

Autoři

PERNICA, Marek; Romana LESNIÁKOVÁ; Denisa DOLEŽALOVÁ a Zdeněk ŠIMEK

Vydání

International Journal of Environmental Analytical Chemistry, Abingdon, Taylor & Francis, 2021, 0306-7319

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.731

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/21:00118726

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Alkylphenols; bisphenols; soil; extraction techniques; derivatisation; LC-MS; MS

Štítky

143180, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 4. 6. 2025 20:18, Mgr. Michaela Hylsová, Ph.D.

Anotace

V originále

Methods useful for the extraction of alkylphenols from soil samples were assessed. A comparison is made of the four extraction techniques that are most commonly used to extract phenolic compounds from soil, such as bisphenol A, bisphenol F and alkylphenols (4-t-OP, iso-NP, 4-OP and 4-n-NP). Soxhlet extraction, ultrasonic-assisted extraction (USE), accelerated solvent extraction (ASE) and the so-called Quick, Easy, Cheap, Effective, Rugged and Safe extraction (QuEChERS) were included. Modifications of the QuEChERS technique such as original, citrate and acetate were investigated. The effects of basic purification sorbents used for QuEChERS extracts such as a primary and secondary amine (PSA), C18 endcapped sorbents and graphitised carbon black (GCB) were tested. A derivatisation step prior to the final analyses by liquid chromatography coupled to a triple quadrupole analyser operating in tandem mass spectrometry (LC-MS/MS) was performed by using dansyl chloride (DNSC). The best extraction of the monitored compounds from spiked soil was obtained using QuEChERS extraction. Recoveries of phenolic compounds using the QuEChERS technique were in the range from 67% to 114%. The lowest extraction recoveries (16-73%) were obtained using ultrasonic extraction. The QuEChERS method was successfully applied for the analysis of alkylphenols in soil samples. Instrumental limits of quantification and limits of detection ranged from 0.08 to 0.83 pg per injection and 0.02 to 0.25 pg per injection, respectively.

Návaznosti

GA13-20357S, projekt VaV

Název: Studium distribuce steroidních látek ve složkách pevných environmentálních matric.

Investor: Grantová agentura ČR, Studium distribuce steroidních látek ve složkách pevných environmentálních matric

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

90028, velká výzkumná infrastruktura

Název: RECETOX

Citovat

PERNICA, Marek; Romana LESNIÁKOVÁ; Denisa DOLEŽALOVÁ a Zdeněk ŠIMEK. Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry. International Journal of Environmental Analytical Chemistry. Abingdon: Taylor & Francis, 2021, roč. 101, č. 9, s. 1287-1301. ISSN 0306-7319. Dostupné z: https://doi.org/10.1080/03067319.2019.1679804.

@article{1639998,
   author = {Pernica, Marek and Lesniáková, Romana and Doležalová, Denisa and Šimek, Zdeněk},
   article_location = {Abingdon},
   article_number = {9},
   doi = {https://doi.org/10.1080/03067319.2019.1679804},
   keywords = {Alkylphenols; bisphenols; soil; extraction techniques; derivatisation; LC-MS; MS},
   language = {eng},
   issn = {0306-7319},
   journal = {International Journal of Environmental Analytical Chemistry},
   title = {Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry},
   url = {https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1679804},
   volume = {101},
   year = {2021}
}

TY  - JOUR
ID  - 1639998
AU  - Pernica, Marek - Lesniáková, Romana - Doležalová, Denisa - Šimek, Zdeněk
PY  - 2021
TI  - Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry
JF  - International Journal of Environmental Analytical Chemistry
VL  - 101
IS  - 9
SP  - 1287-1301
EP  - 1287-1301
PB  - Taylor & Francis
SN  - 03067319
KW  - Alkylphenols
KW  - bisphenols
KW  - soil
KW  - extraction techniques
KW  - derivatisation
KW  - LC-MS
KW  - MS
UR  - https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1679804
L2  - https://www.tandfonline.com/doi/full/10.1080/03067319.2019.1679804
N2  - Methods useful for the extraction of alkylphenols from soil samples were assessed. A comparison is made of the four extraction techniques that are most commonly used to extract phenolic compounds from soil, such as bisphenol A, bisphenol F and alkylphenols (4-t-OP, iso-NP, 4-OP and 4-n-NP). Soxhlet extraction, ultrasonic-assisted extraction (USE), accelerated solvent extraction (ASE) and the so-called Quick, Easy, Cheap, Effective, Rugged and Safe extraction (QuEChERS) were included. Modifications of the QuEChERS technique such as original, citrate and acetate were investigated. The effects of basic purification sorbents used for QuEChERS extracts such as a primary and secondary amine (PSA), C18 endcapped sorbents and graphitised carbon black (GCB) were tested. A derivatisation step prior to the final analyses by liquid chromatography coupled to a triple quadrupole analyser operating in tandem mass spectrometry (LC-MS/MS) was performed by using dansyl chloride (DNSC). The best extraction of the monitored compounds from spiked soil was obtained using QuEChERS extraction. Recoveries of phenolic compounds using the QuEChERS technique were in the range from 67% to 114%. The lowest extraction recoveries (16-73%) were obtained using ultrasonic extraction. The QuEChERS method was successfully applied for the analysis of alkylphenols in soil samples. Instrumental limits of quantification and limits of detection ranged from 0.08 to 0.83 pg per injection and 0.02 to 0.25 pg per injection, respectively.
ER  -

PERNICA, Marek; Romana LESNIÁKOVÁ; Denisa DOLEŽALOVÁ a Zdeněk ŠIMEK. Analysis of alkylphenols and bisphenols in soils using liquid chromatography-tandem mass spectrometry. \textit{International Journal of Environmental Analytical Chemistry}. Abingdon: Taylor \&{} Francis, 2021, roč.~101, č.~9, s.~1287-1301. ISSN~0306-7319. Dostupné z: https://doi.org/10.1080/03067319.2019.1679804.

Přehled o publikaci