Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy
Massif, Southern Siberia, Russia

J 2019

Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy Massif, Southern Siberia, Russia

KASATKIN, A.V.; F. CAMARA; N.V. CHUKANOV; Radek ŠKODA; F. NESTOLA et al.

Základní údaje

Originální název

Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy Massif, Southern Siberia, Russia

Autoři

KASATKIN, A.V.; F. CAMARA; N.V. CHUKANOV; Radek ŠKODA; F. NESTOLA; A.A. AGAKHANOV; D.I. BELAKOVSKIY a V.S. LEDNYOV

Vydání

International Mining and Minerals, London, IMM, 2019, 2075-163X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.380

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/19:00113458

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

patynite; new mineral; Patynskiy massif; chemistry; new structure type; tubular silicate radical

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 11. 5. 2020 18:11, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

The new mineral patynite was discovered at the massif of Patyn Mt. (Patynskiy massif), Tashtagolskiy District, Kemerovo (Kemerovskaya) Oblast', Southern Siberia, Russia. Patynite forms lamellae up to 1 x 0.5 cm and is closely intergrown with charoite, tokkoite, diopside, and graphite. Other associated minerals include monticellite, wollastonite, pectolite, calcite, and orthoclase. Patynite is colorless in individual lamellae to white and white-brownish in aggregates. It has vitreous to silky luster, white streaks, brittle tenacity, and stepped fractures. Its density measured by flotation in Clerici solution is 2.70(2) g/cm(3); density calculated from the empirical formula is 2.793 g/cm(3). The Mohs' hardness is 6. Optically, patynite is biaxial (-) with alpha = 1.568(2), beta = 1.580(2), and gamma = 1.582(2) (589 nm). The 2V (measured) = 40(10)degrees and 2V (calculated) = 44.1 degrees. The Raman and IR spectra shows the absence in the mineral of H2O, OH-, and CO32- groups and B-O bonds. The chemical composition is (electron microprobe, wt.%): Na2O 3.68, K2O 5.62, CaO 26.82, SiO2 64.27, total 100.39. The empirical formula based on 23 O apfu is Na1.00K1.00Ca4.02Si8.99O23. Patynite is triclinic, space group P (1) over bar. The unit-cell parameters are: a = 7.27430(10), b = 10.5516(2), c = 13.9851(3) angstrom, alpha = 104.203(2)degrees, beta = 104.302(2)degrees, gamma = 92.0280(10)degrees, V = 1003.07(3) angstrom(3), Z = 2. The crystal structure was solved by direct methods and refined to R-1 = 0.032. Patynite is an inosilicate with a new type of sextuple branched tubular chain [(Si9O23)(10-)](infinity) with an internal channel and [(Si18O46)(20-)] as the repeat unit. The strongest lines of the powder X-ray diffraction pattern [d(obs), angstrom (I, %) (hkl)] are: 3.454 (100) (2-1-1), 3.262 (66) (2-1-2), 3.103 (64) (02-4), 2.801 (21), 1.820 (28) (40-2). Type material is deposited in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia with the registration number 5369/1.

Citovat

KASATKIN, A.V.; F. CAMARA; N.V. CHUKANOV; Radek ŠKODA; F. NESTOLA; A.A. AGAKHANOV; D.I. BELAKOVSKIY a V.S. LEDNYOV. Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy Massif, Southern Siberia, Russia. International Mining and Minerals. London: IMM, 2019, roč. 9, č. 10, s. 1-19. ISSN 2075-163X. Dostupné z: https://doi.org/10.3390/min9100611.

@article{1641637,
   author = {Kasatkin, A.V. and Camara, F. and Chukanov, N.V. and Škoda, Radek and Nestola, F. and Agakhanov, A.A. and Belakovskiy, D.I. and Lednyov, V.S.},
   article_location = {London},
   article_number = {10},
   doi = {https://doi.org/10.3390/min9100611},
   keywords = {patynite; new mineral; Patynskiy massif; chemistry; new structure type; tubular silicate radical},
   language = {eng},
   issn = {2075-163X},
   journal = {International Mining and Minerals},
   title = {Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy Massif, Southern Siberia, Russia},
   url = {https://www.mdpi.com/2075-163X/9/10/611},
   volume = {9},
   year = {2019}
}

TY  - JOUR
ID  - 1641637
AU  - Kasatkin, A.V. - Camara, F. - Chukanov, N.V. - Škoda, Radek - Nestola, F. - Agakhanov, A.A. - Belakovskiy, D.I. - Lednyov, V.S.
PY  - 2019
TI  - Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy Massif, Southern Siberia, Russia
JF  - International Mining and Minerals
VL  - 9
IS  - 10
SP  - 1-19
EP  - 1-19
PB  - IMM
SN  - 2075163X
KW  - patynite
KW  - new mineral
KW  - Patynskiy massif
KW  - chemistry
KW  - new structure type
KW  - tubular silicate radical
UR  - https://www.mdpi.com/2075-163X/9/10/611
L2  - https://www.mdpi.com/2075-163X/9/10/611
N2  - The new mineral patynite was discovered at the massif of Patyn Mt. (Patynskiy massif), Tashtagolskiy District, Kemerovo (Kemerovskaya) Oblast', Southern Siberia, Russia. Patynite forms lamellae up to 1 x 0.5 cm and is closely intergrown with charoite, tokkoite, diopside, and graphite. Other associated minerals include monticellite, wollastonite, pectolite, calcite, and orthoclase. Patynite is colorless in individual lamellae to white and white-brownish in aggregates. It has vitreous to silky luster, white streaks, brittle tenacity, and stepped fractures. Its density measured by flotation in Clerici solution is 2.70(2) g/cm(3); density calculated from the empirical formula is 2.793 g/cm(3). The Mohs' hardness is 6. Optically, patynite is biaxial (-) with alpha = 1.568(2), beta = 1.580(2), and gamma = 1.582(2) (589 nm). The 2V (measured) = 40(10)degrees and 2V (calculated) = 44.1 degrees. The Raman and IR spectra shows the absence in the mineral of H2O, OH-, and CO32- groups and B-O bonds. The chemical composition is (electron microprobe, wt.%): Na2O 3.68, K2O 5.62, CaO 26.82, SiO2 64.27, total 100.39. The empirical formula based on 23 O apfu is Na1.00K1.00Ca4.02Si8.99O23. Patynite is triclinic, space group P (1) over bar. The unit-cell parameters are: a = 7.27430(10), b = 10.5516(2), c = 13.9851(3) angstrom, alpha = 104.203(2)degrees, beta = 104.302(2)degrees, gamma = 92.0280(10)degrees, V = 1003.07(3) angstrom(3), Z = 2. The crystal structure was solved by direct methods and refined to R-1 = 0.032. Patynite is an inosilicate with a new type of sextuple branched tubular chain [(Si9O23)(10-)](infinity) with an internal channel and [(Si18O46)(20-)] as the repeat unit. The strongest lines of the powder X-ray diffraction pattern [d(obs), angstrom (I, %) (hkl)] are: 3.454 (100) (2-1-1), 3.262 (66) (2-1-2), 3.103 (64) (02-4), 2.801 (21), 1.820 (28) (40-2). Type material is deposited in the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia with the registration number 5369/1.
ER  -

KASATKIN, A.V.; F. CAMARA; N.V. CHUKANOV; Radek ŠKODA; F. NESTOLA; A.A. AGAKHANOV; D.I. BELAKOVSKIY a V.S. LEDNYOV. Patynite, NaKCa4[Si9O23], a New Mineral from the Patynskiy Massif, Southern Siberia, Russia. \textit{International Mining and Minerals}. London: IMM, 2019, roč.~9, č.~10, s.~1-19. ISSN~2075-163X. Dostupné z: https://doi.org/10.3390/min9100611.

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