Deposition Penetration Depth and Sticking Probability in Plasma
Polymerization of Cyclopropylamine

J 2021

Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine

MICHLÍČEK, Miroslav; Lucie BLAHOVÁ; Eva DVOŘÁKOVÁ; David NEČAS; Lenka ZAJÍČKOVÁ et. al.

Základní údaje

Originální název

Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine

Autoři

MICHLÍČEK, Miroslav; Lucie BLAHOVÁ; Eva DVOŘÁKOVÁ; David NEČAS a Lenka ZAJÍČKOVÁ

Vydání

Applied Surface Science, Amsterdam, Elsevier Science, 2021, 0169-4332

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 7.392

Kód RIV

RIV/00216224:14310/21:00118778

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1016/j.apsusc.2020.147979

UT WoS

000598377000006

EID Scopus

2-s2.0-85096645921

Klíčová slova anglicky

plasma polymerization; 3D structured substrates; bioactive functional coating; penetration depth; sticking probability

Štítky

14312020, 14312030, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 6. 3. 2024 14:54, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Understanding the role of substrate geometry is vital for a successful optimization of low-pressure plasma polymerization on non-planar substrates used in bioapplications, such as porous materials or well plates. We investigated the altered transport of film-forming species and properties of the coatings for a cyclopropylamine and argon discharge using a combined analysis of the plasma polymer deposition on flat Si pieces, culture wells, microtrenches, a macrocavity, porous hydroxyapatite scaffolds and electrospun polycaprolactone nanofibrous mats. The aspect ratio of the well structures impacted mainly the deposition rate, whereas the film chemistry was affected only moderately. A large deposition penetration depth into the porous media indicated a relatively low sticking probability of film-forming species. A detailed analysis of microtrench step coverage and macrocavity deposition disproved the model of film-forming species with a single overall sticking probability. At least two populations with two different sticking probabilities were required to fit the experimental data. A majority of the film-forming species (76%) has a large sticking probability of 0.20±0.01, while still a significant part (24%) has a relatively small sticking probability of 0.0015±0.0002. The presented methodology is widely applicable for understanding the details of plasma-surface interaction and successful applications of plasma polymerization onto complex substrates.

Návaznosti

GA18-12774S, projekt VaV

Název: Plazmové polymery připravené na nanovlákenných membránách pro inženýrství cévní tkáně

Investor: Grantová agentura ČR, Plazmové polymery připravené na nanovlákenných membránách pro inženýrství cévní tkáně

LQ1601, projekt VaV

Název: CEITEC 2020 (Akronym: CEITEC2020)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, CEITEC 2020

90110, velká výzkumná infrastruktura

Název: CzechNanoLab

Citovat

MICHLÍČEK, Miroslav; Lucie BLAHOVÁ; Eva DVOŘÁKOVÁ; David NEČAS a Lenka ZAJÍČKOVÁ. Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine. Applied Surface Science. Amsterdam: Elsevier Science, 2021, roč. 540, February 2021, s. 1-10. ISSN 0169-4332. Dostupné z: https://doi.org/10.1016/j.apsusc.2020.147979.

@article{1689016,
   author = {Michlíček, Miroslav and Blahová, Lucie and Dvořáková, Eva and Nečas, David and Zajíčková, Lenka},
   article_location = {Amsterdam},
   article_number = {February 2021},
   doi = {https://doi.org/10.1016/j.apsusc.2020.147979},
   keywords = {plasma polymerization; 3D structured substrates; bioactive functional coating; penetration depth; sticking probability},
   language = {eng},
   issn = {0169-4332},
   journal = {Applied Surface Science},
   note = {doc. Zajíčková - dle rozhodnutí ředitelů 5.3.2024},
   title = {Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine},
   url = {https://www.sciencedirect.com/science/article/pii/S0169433220327367},
   volume = {540},
   year = {2021}
}

TY  - JOUR
ID  - 1689016
AU  - Michlíček, Miroslav - Blahová, Lucie - Dvořáková, Eva - Nečas, David - Zajíčková, Lenka
PY  - 2021
TI  - Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine
JF  - Applied Surface Science
VL  - 540
IS  - February 2021
SP  - 1-10
EP  - 1-10
PB  - Elsevier Science
SN  - 01694332
N1  - doc. Zajíčková - dle rozhodnutí ředitelů 5.3.2024
KW  - plasma polymerization
KW  - 3D structured substrates
KW  - bioactive functional coating
KW  - penetration depth
KW  - sticking probability
UR  - https://www.sciencedirect.com/science/article/pii/S0169433220327367
L2  - https://www.sciencedirect.com/science/article/pii/S0169433220327367
N2  - Understanding the role of substrate geometry is vital for a successful optimization of low-pressure plasma polymerization on non-planar substrates used in bioapplications, such as porous materials or well plates. We investigated the altered transport of film-forming species and properties of the coatings for a cyclopropylamine and argon discharge using a combined analysis of the plasma polymer deposition on flat Si pieces, culture wells, microtrenches, a macrocavity, porous hydroxyapatite scaffolds and electrospun polycaprolactone nanofibrous mats. The aspect ratio of the well structures impacted mainly the deposition rate, whereas the film chemistry was affected only moderately. A large deposition penetration depth into the porous media indicated a relatively low sticking probability of film-forming species. A detailed analysis of microtrench step coverage and macrocavity deposition disproved the model of film-forming species with a single overall sticking probability. At least two populations with two different sticking probabilities were required to fit the experimental data. A majority of the film-forming species (76%) has a large sticking probability of 0.20±0.01, while still a significant part (24%) has a relatively small sticking probability of 0.0015±0.0002. The presented methodology is widely applicable for understanding the details of plasma-surface interaction and successful applications of plasma polymerization onto complex substrates.
ER  -

MICHLÍČEK, Miroslav; Lucie BLAHOVÁ; Eva DVOŘÁKOVÁ; David NEČAS a Lenka ZAJÍČKOVÁ. Deposition Penetration Depth and Sticking Probability in Plasma Polymerization of Cyclopropylamine. \textit{Applied Surface Science}. Amsterdam: Elsevier Science, 2021, roč.~540, February 2021, s.~1-10. ISSN~0169-4332. Dostupné z: https://doi.org/10.1016/j.apsusc.2020.147979.

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