Atomization of lead hydride in a dielectric barrier discharge
atomizer: Optimized for atomic absorption spectrometry and
studied by laser-induced fluorescence

J 2020

Atomization of lead hydride in a dielectric barrier discharge atomizer: Optimized for atomic absorption spectrometry and studied by laser-induced fluorescence

ALBRECHT, Michal; Martina MRKVIČKOVÁ; Milan SVOBODA; Jakub HRANÍČEK; Jan VORÁČ et al.

Základní údaje

Originální název

Atomization of lead hydride in a dielectric barrier discharge atomizer: Optimized for atomic absorption spectrometry and studied by laser-induced fluorescence

Autoři

ALBRECHT, Michal; Martina MRKVIČKOVÁ; Milan SVOBODA; Jakub HRANÍČEK; Jan VORÁČ; Pavel DVOŘÁK; Jiří DĚDINA a Jan KRATZER

Vydání

Spectrochimica Acta, Part B: Atomic Spectroscopy, Oxford, Pergamon-Elsevier Science Ltd, 2020, 0584-8547

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

21100 2.11 Other engineering and technologies

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 3.752

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/20:00114469

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Dielectric barrier discharge; Lead; Hydride generation atomic absorption spectrometry; Laser-induced fluorescence

Štítky

14312030, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 11. 2020 14:35, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Atomization of lead hydride in a plane-parallel volume dielectric barrier discharge (DBD) atomizer coupled to a high voltage power supply source with sinusoidal waveform (28.5 kHz) was optimized with detection by atomic absorption spectrometry. Argon was found as the best discharge gas under a flow rate of 175 mL min(-1) while the DBD optimum peak-to-peak high voltage was 25 kV. The performance of the novel DBD atomizer was compared to that of a conventional externally heated quartz tube atomizer (QTA) operating at 900 degrees C and 100 mL min(-1) Ar carrier gas flow rate. Sensitivity and limit of detection (LOD) in QTA reached 0.21 s ng(-1) Pb and 0.6 ng mL(-1) Pb, respectively, while they reached 0.04 s ng(-1) Pb and 2.3 ng mL(-1) Pb in DBD. Laser-induced fluorescence (LIF) was employed to investigate the spatial distribution of free Pb atoms as well as to quantify lead hydride atomization efficiency in both atomizers. Free Pb atoms were present only in a central region of DBD atomizer. Atomization efficiency of lead hydride was quantified by LIF to be 23 +/- 7%. On the contrary, free Pb atoms were distributed homogeneously along the whole optical arm in the QTA with atomization efficiency reaching 88 +/- 18%.

Návaznosti

ED2.1.00/03.0086, projekt VaV

Název: Regionální VaV centrum pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

GA17-04329S, projekt VaV

Název: Atomizátory hydridů pro atomovou absorpční a atomovou fluorescenční spektrometrii - nové horizonty

Investor: Grantová agentura ČR, Atomizátory hydridů pro pro atomovou absorpční a atomovou fluorescenční spektrometrii - nové horizonty

LO1411, projekt VaV

Název: Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy (Akronym: CEPLANT plus)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Rozvoj centra pro nízkonákladové plazmové a nanotechnologické povrchové úpravy

Citovat

ALBRECHT, Michal; Martina MRKVIČKOVÁ; Milan SVOBODA; Jakub HRANÍČEK; Jan VORÁČ; Pavel DVOŘÁK; Jiří DĚDINA a Jan KRATZER. Atomization of lead hydride in a dielectric barrier discharge atomizer: Optimized for atomic absorption spectrometry and studied by laser-induced fluorescence. Spectrochimica Acta, Part B: Atomic Spectroscopy. Oxford: Pergamon-Elsevier Science Ltd, 2020, roč. 166, APR 2020, s. 1-8. ISSN 0584-8547. Dostupné z: https://doi.org/10.1016/j.sab.2020.105819.

@article{1693656,
   author = {Albrecht, Michal and Mrkvičková, Martina and Svoboda, Milan and Hraníček, Jakub and Voráč, Jan and Dvořák, Pavel and Dědina, Jiří and Kratzer, Jan},
   article_location = {Oxford},
   article_number = {APR 2020},
   doi = {https://doi.org/10.1016/j.sab.2020.105819},
   keywords = {Dielectric barrier discharge; Lead; Hydride generation atomic absorption spectrometry; Laser-induced fluorescence},
   language = {eng},
   issn = {0584-8547},
   journal = {Spectrochimica Acta, Part B: Atomic Spectroscopy},
   title = {Atomization of lead hydride in a dielectric barrier discharge atomizer: Optimized for atomic absorption spectrometry and studied by laser-induced fluorescence},
   url = {https://doi.org/10.1016/j.sab.2020.105819},
   volume = {166},
   year = {2020}
}

TY  - JOUR
ID  - 1693656
AU  - Albrecht, Michal - Mrkvičková, Martina - Svoboda, Milan - Hraníček, Jakub - Voráč, Jan - Dvořák, Pavel - Dědina, Jiří - Kratzer, Jan
PY  - 2020
TI  - Atomization of lead hydride in a dielectric barrier discharge atomizer: Optimized for atomic absorption spectrometry and studied by laser-induced fluorescence
JF  - Spectrochimica Acta, Part B: Atomic Spectroscopy
VL  - 166
IS  - APR 2020
SP  - 1-8
EP  - 1-8
PB  - Pergamon-Elsevier Science Ltd
SN  - 05848547
KW  - Dielectric barrier discharge
KW  - Lead
KW  - Hydride generation atomic absorption spectrometry
KW  - Laser-induced fluorescence
UR  - https://doi.org/10.1016/j.sab.2020.105819
L2  - https://doi.org/10.1016/j.sab.2020.105819
N2  - Atomization of lead hydride in a plane-parallel volume dielectric barrier discharge (DBD) atomizer coupled to a high voltage power supply source with sinusoidal waveform (28.5 kHz) was optimized with detection by atomic absorption spectrometry. Argon was found as the best discharge gas under a flow rate of 175 mL min(-1) while the DBD optimum peak-to-peak high voltage was 25 kV. The performance of the novel DBD atomizer was compared to that of a conventional externally heated quartz tube atomizer (QTA) operating at 900 degrees C and 100 mL min(-1) Ar carrier gas flow rate. Sensitivity and limit of detection (LOD) in QTA reached 0.21 s ng(-1) Pb and 0.6 ng mL(-1) Pb, respectively, while they reached 0.04 s ng(-1) Pb and 2.3 ng mL(-1) Pb in DBD. Laser-induced fluorescence (LIF) was employed to investigate the spatial distribution of free Pb atoms as well as to quantify lead hydride atomization efficiency in both atomizers. Free Pb atoms were present only in a central region of DBD atomizer. Atomization efficiency of lead hydride was quantified by LIF to be 23 +/- 7%. On the contrary, free Pb atoms were distributed homogeneously along the whole optical arm in the QTA with atomization efficiency reaching 88 +/- 18%.
ER  -

ALBRECHT, Michal; Martina MRKVIČKOVÁ; Milan SVOBODA; Jakub HRANÍČEK; Jan VORÁČ; Pavel DVOŘÁK; Jiří DĚDINA a Jan KRATZER. Atomization of lead hydride in a dielectric barrier discharge atomizer: Optimized for atomic absorption spectrometry and studied by laser-induced fluorescence. \textit{Spectrochimica Acta, Part B: Atomic Spectroscopy}. Oxford: Pergamon-Elsevier Science Ltd, 2020, roč.~166, APR 2020, s.~1-8. ISSN~0584-8547. Dostupné z: https://doi.org/10.1016/j.sab.2020.105819.

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