Laser ablation synthesis of metal-doped gold clusters from
composites of gold nanoparticles with metal organic frameworks

J 2021

Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks

PEČINKA, Lukáš; Eladia Maria PENA-MENDEZ; Jose Elias CONDE a Josef HAVEL

Základní údaje

Originální název

Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks

Autoři

PEČINKA, Lukáš; Eladia Maria PENA-MENDEZ; Jose Elias CONDE a Josef HAVEL

Vydání

Scientific Reports, Nature Research, 2021, 2045-2322

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10403 Physical chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.997

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/21:00118806

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Mass spectrometry; Nanoparticles; Nanoscience and technology

Štítky

14313010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 19. 4. 2021 17:39, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Metal-doped gold clusters, mainly cages, are receiving rapidly increasing attention due to their tunable catalytic properties. Their synthesis is mostly based on complex procedures, including several steps. In this work, via adsorption of gold nanoparticles (AuNPs) from aqueous solution to MOF (metal organic frameworks) of M=Co, Cu, Ni, and Zn with various linkers the {AuNPs, MOF} composites were prepared. These composites were used for laser ablation synthesis (LAS) using a common mass spectrometer. Several series of positively and negatively charged AumMn+/- clusters were observed in mass spectra and their stoichiometry (m=1-35, n=1-5) was determined. For each dopant (Co, Cu, Ni, and Zn) similar to 50 different clusters were identified in positive, as well as in negative ion modes. About 100 of these clusters were proposed to be endohedral metal-doped gold cages (for m>12). The developed approach represents a simple procedure for generating metal-doped gold clusters or endohedral metal-doped gold cages materials with potential applications in medicine and/or electronics.

Návaznosti

GA18-03823S, projekt VaV

Název: Pokročilé metody přípravy tenkých vrstev chalkogenidů a jejich modifikace

Investor: Grantová agentura ČR, Pokročilé metody přípravy tenkých vrstev chalkogenidů a jejich modifikace

MUNI/A/1421/2019, interní kód MU

Název: Analytické a fyzikálně-chemické metody ve výzkumu geologických, biologických a syntetických materiálů (Akronym: AFCHMAT)

Investor: Masarykova univerzita, Analytické a fyzikálně-chemické metody ve výzkumu geologických, biologických a syntetických materiálů, DO R. 2020_Kategorie A - Specifický výzkum - Studentské výzkumné projekty

Citovat

PEČINKA, Lukáš; Eladia Maria PENA-MENDEZ; Jose Elias CONDE a Josef HAVEL. Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks. Scientific Reports. Nature Research, 2021, roč. 11, č. 1, s. "4656", 6 s. ISSN 2045-2322. Dostupné z: https://doi.org/10.1038/s41598-021-83836-3.

@article{1718536,
   author = {Pečinka, Lukáš and PenaandMendez, Eladia Maria and Conde, Jose Elias and Havel, Josef},
   article_number = {1},
   doi = {https://doi.org/10.1038/s41598-021-83836-3},
   keywords = {Mass spectrometry; Nanoparticles; Nanoscience and technology},
   language = {eng},
   issn = {2045-2322},
   journal = {Scientific Reports},
   title = {Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks},
   url = {https://doi.org/10.1038/s41598-021-83836-3},
   volume = {11},
   year = {2021}
}

TY  - JOUR
ID  - 1718536
AU  - Pečinka, Lukáš - Pena-Mendez, Eladia Maria - Conde, Jose Elias - Havel, Josef
PY  - 2021
TI  - Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks
JF  - Scientific Reports
VL  - 11
IS  - 1
SP  - "4656"
EP  - "4656"
PB  - Nature Research
SN  - 20452322
KW  - Mass spectrometry
KW  - Nanoparticles
KW  - Nanoscience and technology
UR  - https://doi.org/10.1038/s41598-021-83836-3
N2  - Metal-doped gold clusters, mainly cages, are receiving rapidly increasing attention due to their tunable catalytic properties. Their synthesis is mostly based on complex procedures, including several steps. In this work, via adsorption of gold nanoparticles (AuNPs) from aqueous solution to MOF (metal organic frameworks) of M=Co, Cu, Ni, and Zn with various linkers the {AuNPs, MOF} composites were prepared. These composites were used for laser ablation synthesis (LAS) using a common mass spectrometer. Several series of positively and negatively charged AumMn+/- clusters were observed in mass spectra and their stoichiometry (m=1-35, n=1-5) was determined. For each dopant (Co, Cu, Ni, and Zn) similar to 50 different clusters were identified in positive, as well as in negative ion modes. About 100 of these clusters were proposed to be endohedral metal-doped gold cages (for m>12). The developed approach represents a simple procedure for generating metal-doped gold clusters or endohedral metal-doped gold cages materials with potential applications in medicine and/or electronics.
ER  -

PEČINKA, Lukáš; Eladia Maria PENA-MENDEZ; Jose Elias CONDE a Josef HAVEL. Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks. \textit{Scientific Reports}. Nature Research, 2021, roč.~11, č.~1, s.~''4656'', 6 s. ISSN~2045-2322. Dostupné z: https://doi.org/10.1038/s41598-021-83836-3.

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