Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species
Isostructural with Fianelite

J 2020

Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species Isostructural with Fianelite

ROTH, Philippe; Nicolas MEISSER; Fabrizio NESTOLA; Radek ŠKODA; Fernando CÁMARA et. al.

Základní údaje

Originální název

Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species Isostructural with Fianelite

Autoři

ROTH, Philippe; Nicolas MEISSER; Fabrizio NESTOLA; Radek ŠKODA; Fernando CÁMARA; Ferdinando BOSI; Marco E. CIRIOTTI; Ulf HÅLENIUS; Cédric SCHNYDER a Roberto BRACCO

Vydání

Minerals, Basel, MDPI, 2020, 2075-163X

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.644

Kód RIV

RIV/00216224:14310/20:00117568

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.3390/min10110960

UT WoS

000593412500001

EID Scopus

2-s2.0-85094902366

Klíčová slova anglicky

rüdlingerite; new mineral species; fianelite; vanadium; arsenic; crystal structure; Fianel mine; Switzerland; Valletta mine; Italy

Štítky

14315010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 5. 1. 2021 14:53, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

The new mineral species rudlingerite, ideally Mn22+V5+As5+O7 center dot 2H(2)O, occurs in the Fianel mine, in Val Ferrera, Grisons, Switzerland, a small Alpine metamorphic Mn deposit. It is associated with ansermetite and Fe oxyhydroxide in thin fractures in Triassic dolomitic marbles. Rudlingerite was also found in specimens recovered from the dump of the Valletta mine, Canosio, Cuneo, Piedmont, Italy, where it occurs together with massive braccoite and several other As- and V-rich phases in richly mineralized veins crossing the quartz-hematite ore. The new mineral displays at both localities yellow to orange, flattened elongated prismatic, euhedral crystals measuring up to 300 mu m in length. Electron-microprobe analysis of rudlingerite from Fianel gave (in wt%): MnO 36.84, FeO 0.06, As2O5, 25.32, V2O5 28.05, SiO2 0.13, H2Ocalc 9.51, total 99.91. On the basis of 9 O anions per formula unit, the chemical formula of rudlingerite is Mn-1.97(V-1.17(5+) As0.83Si0.01)(sigma 2.01)O-7 center dot 2H(2)O. The main diffraction lines are [d(obs) in angstrom (I-obs) hkl]: 3.048 (100) 022, 5.34 (80) 120, 2.730 (60) 231, 2.206 (60) 16-1, 7.28 (50) 020, 2.344 (50) 250, 6.88 (40) 110, and 2.452 (40) 320. Study of the crystal structure showcases a monoclinic unit cell, space group P2(1)/n, with a = 7.8289(2) angstrom, b = 14.5673(4) angstrom, c = 6.7011(2) angstrom, beta = 93.773(2)degrees, V = 762.58(4) angstrom(3), Z = 4. The crystal structure has been solved and refined to R-1 = 0.041 on the basis of 3784 reflections with F-o > 4 sigma(F). It shows Mn2+ hosted in chains of octahedra that are subparallel to [-101] and bound together by pairs of tetrahedra hosted by V5+ and As5+, building up a framework. Additional linkage is provided by hydrogen-bonding through H2O coordinating Mn2+ at the octahedra. One tetrahedrally coordinated site is dominated by V5+, (T)((1))(V0.88As0.12), corresponding to an observed site scattering of 24.20 electrons per site (eps), whereas the second site is strongly dominated by As5+,(T)((2))(As0.74V0.26), with, accordingly, a higher observed site scattering of 30.40 eps. The new mineral has been approved by the IMA-CNMNC and named for Gottfried Rudlinger (born 1919), a pioneer in the 1960-1980s, in the search and study of the small minerals from the Alpine manganese mineral deposits of Grisons.

Citovat

ROTH, Philippe; Nicolas MEISSER; Fabrizio NESTOLA; Radek ŠKODA; Fernando CÁMARA; Ferdinando BOSI; Marco E. CIRIOTTI; Ulf HÅLENIUS; Cédric SCHNYDER a Roberto BRACCO. Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species Isostructural with Fianelite. Minerals. Basel: MDPI, 2020, roč. 10, č. 11, s. 1-15. ISSN 2075-163X. Dostupné z: https://doi.org/10.3390/min10110960.

@article{1719256,
   author = {Roth, Philippe and Meisser, Nicolas and Nestola, Fabrizio and Škoda, Radek and Cámara, Fernando and Bosi, Ferdinando and Ciriotti, Marco E. and Hålenius, Ulf and Schnyder, Cédric and Bracco, Roberto},
   article_location = {Basel},
   article_number = {11},
   doi = {https://doi.org/10.3390/min10110960},
   keywords = {rüdlingerite; new mineral species; fianelite; vanadium; arsenic; crystal structure; Fianel mine; Switzerland; Valletta mine; Italy},
   language = {eng},
   issn = {2075-163X},
   journal = {Minerals},
   title = {Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species Isostructural with Fianelite},
   url = {https://doi.org/10.3390/min10110960},
   volume = {10},
   year = {2020}
}

TY  - JOUR
ID  - 1719256
AU  - Roth, Philippe - Meisser, Nicolas - Nestola, Fabrizio - Škoda, Radek - Cámara, Fernando - Bosi, Ferdinando - Ciriotti, Marco E. - Hålenius, Ulf - Schnyder, Cédric - Bracco, Roberto
PY  - 2020
TI  - Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species Isostructural with Fianelite
JF  - Minerals
VL  - 10
IS  - 11
SP  - 1-15
EP  - 1-15
PB  - MDPI
SN  - 2075163X
KW  - rüdlingerite
KW  - new mineral species
KW  - fianelite
KW  - vanadium
KW  - arsenic
KW  - crystal structure
KW  - Fianel mine
KW  - Switzerland
KW  - Valletta mine
KW  - Italy
UR  - https://doi.org/10.3390/min10110960
L2  - https://doi.org/10.3390/min10110960
N2  - The new mineral species rudlingerite, ideally Mn22+V5+As5+O7 center dot 2H(2)O, occurs in the Fianel mine, in Val Ferrera, Grisons, Switzerland, a small Alpine metamorphic Mn deposit. It is associated with ansermetite and Fe oxyhydroxide in thin fractures in Triassic dolomitic marbles. Rudlingerite was also found in specimens recovered from the dump of the Valletta mine, Canosio, Cuneo, Piedmont, Italy, where it occurs together with massive braccoite and several other As- and V-rich phases in richly mineralized veins crossing the quartz-hematite ore. The new mineral displays at both localities yellow to orange, flattened elongated prismatic, euhedral crystals measuring up to 300 mu m in length. Electron-microprobe analysis of rudlingerite from Fianel gave (in wt%): MnO 36.84, FeO 0.06, As2O5, 25.32, V2O5 28.05, SiO2 0.13, H2Ocalc 9.51, total 99.91. On the basis of 9 O anions per formula unit, the chemical formula of rudlingerite is Mn-1.97(V-1.17(5+) As0.83Si0.01)(sigma 2.01)O-7 center dot 2H(2)O. The main diffraction lines are [d(obs) in angstrom (I-obs) hkl]: 3.048 (100) 022, 5.34 (80) 120, 2.730 (60) 231, 2.206 (60) 16-1, 7.28 (50) 020, 2.344 (50) 250, 6.88 (40) 110, and 2.452 (40) 320. Study of the crystal structure showcases a monoclinic unit cell, space group P2(1)/n, with a = 7.8289(2) angstrom, b = 14.5673(4) angstrom, c = 6.7011(2) angstrom, beta = 93.773(2)degrees, V = 762.58(4) angstrom(3), Z = 4. The crystal structure has been solved and refined to R-1 = 0.041 on the basis of 3784 reflections with F-o > 4 sigma(F). It shows Mn2+ hosted in chains of octahedra that are subparallel to [-101] and bound together by pairs of tetrahedra hosted by V5+ and As5+, building up a framework. Additional linkage is provided by hydrogen-bonding through H2O coordinating Mn2+ at the octahedra. One tetrahedrally coordinated site is dominated by V5+, (T)((1))(V0.88As0.12), corresponding to an observed site scattering of 24.20 electrons per site (eps), whereas the second site is strongly dominated by As5+,(T)((2))(As0.74V0.26), with, accordingly, a higher observed site scattering of 30.40 eps. The new mineral has been approved by the IMA-CNMNC and named for Gottfried Rudlinger (born 1919), a pioneer in the 1960-1980s, in the search and study of the small minerals from the Alpine manganese mineral deposits of Grisons.
ER  -

ROTH, Philippe; Nicolas MEISSER; Fabrizio NESTOLA; Radek ŠKODA; Fernando CÁMARA; Ferdinando BOSI; Marco E. CIRIOTTI; Ulf HÅLENIUS; Cédric SCHNYDER a Roberto BRACCO. Rüdlingerite, Mn22+V5+As5+O7 center dot 2H(2)O, a New Species Isostructural with Fianelite. \textit{Minerals}. Basel: MDPI, 2020, roč.~10, č.~11, s.~1-15. ISSN~2075-163X. Dostupné z: https://doi.org/10.3390/min10110960.

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