The parisite-(Ce) enigma: challenges in the identification of
fluorcarbonate minerals

J 2021

The parisite-(Ce) enigma: challenges in the identification of fluorcarbonate minerals

ZEUG, Manuela; Lutz NASDALA; Martin ENDE; Gerlinde HABLER; Christoph HAUZENBERGER et. al.

Základní údaje

Originální název

The parisite-(Ce) enigma: challenges in the identification of fluorcarbonate minerals

Autoři

ZEUG, Manuela; Lutz NASDALA; Martin ENDE; Gerlinde HABLER; Christoph HAUZENBERGER; N. Chutimun CHANMUANG; Radek ŠKODA; Dan TOPA; Manfred WILDNER a Richard WIRTH

Vydání

Mineralogy and Petrology, Wien, Springer Wien, 2021, 0930-0708

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10504 Mineralogy

Stát vydavatele

Rakousko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 2.011

Kód RIV

RIV/00216224:14310/21:00120913

Organizační jednotka

Přírodovědecká fakulta

DOI

https://doi.org/10.1007/s00710-020-00723-x

UT WoS

000578513600001

EID Scopus

2-s2.0-85092411997

Klíčová slova anglicky

Parisite-(Ce); Rontgenite-(Ce); Fluorcarbonate; Polycrystal; Raman spectroscopy; Stacking pattern

Štítky

14315010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 18. 1. 2021 12:24, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

A multi-methodological study was conducted in order to provide further insight into the structural and compositional complexity of rare earth element (REE) fluorcarbonates, with particular attention to their correct assignment to a mineral species. Polycrystals from La Pita Mine, Municipality de Maripi, Boyaca Department, Colombia, show syntaxic intergrowth of parisite-(Ce) with rontgenite-(Ce) and a phase which is assigned toB(3)S(4)(i.e., bastnasite-3-synchisite-4; still unnamed) fluorcarbonate. Transmission electron microscope (TEM) images reveal well-ordered stacking patterns of two monoclinic polytypes of parisite-(Ce) as well as heavily disordered layer sequences with varying lattice fringe spacings. The crystal structure refinement from single crystal X-ray diffraction data - impeded by twinning, complex stacking patterns, sequential and compositional faults - indicates that the dominant parisite-(Ce) polytypeM(1)has space groupCc. Parisite-(Ce), theB(3)S(4)phase and rontgenite-(Ce) show different BSE intensities from high to low. Raman spectroscopic analyses of parisite-(Ce), theB(3)S(4)phase and rontgenite-(Ce) reveal different intensity ratios of the three symmetric CO(3)stretching bands at around 1100 cm(-1). We propose to non-destructively differentiate parisite-(Ce) and rontgenite-(Ce) by their 1092 cm(-1)/ 1081 cm(-1)nu(1)(CO3) band height ratio.

Citovat

ZEUG, Manuela; Lutz NASDALA; Martin ENDE; Gerlinde HABLER; Christoph HAUZENBERGER; N. Chutimun CHANMUANG; Radek ŠKODA; Dan TOPA; Manfred WILDNER a Richard WIRTH. The parisite-(Ce) enigma: challenges in the identification of fluorcarbonate minerals. Mineralogy and Petrology. Wien: Springer Wien, 2021, roč. 115, č. 1, s. 1-19. ISSN 0930-0708. Dostupné z: https://doi.org/10.1007/s00710-020-00723-x.

@article{1719297,
   author = {Zeug, Manuela and Nasdala, Lutz and Ende, Martin and Habler, Gerlinde and Hauzenberger, Christoph and Chanmuang, N. Chutimun and Škoda, Radek and Topa, Dan and Wildner, Manfred and Wirth, Richard},
   article_location = {Wien},
   article_number = {1},
   doi = {https://doi.org/10.1007/s00710-020-00723-x},
   keywords = {Parisite-(Ce); Rontgenite-(Ce); Fluorcarbonate; Polycrystal; Raman spectroscopy; Stacking pattern},
   language = {eng},
   issn = {0930-0708},
   journal = {Mineralogy and Petrology},
   title = {The parisite-(Ce) enigma: challenges in the identification of fluorcarbonate minerals},
   url = {https://doi.org/10.1007/s00710-020-00723-x},
   volume = {115},
   year = {2021}
}

TY  - JOUR
ID  - 1719297
AU  - Zeug, Manuela - Nasdala, Lutz - Ende, Martin - Habler, Gerlinde - Hauzenberger, Christoph - Chanmuang, N. Chutimun - Škoda, Radek - Topa, Dan - Wildner, Manfred - Wirth, Richard
PY  - 2021
TI  - The parisite-(Ce) enigma: challenges in the identification of fluorcarbonate minerals
JF  - Mineralogy and Petrology
VL  - 115
IS  - 1
SP  - 1-19
EP  - 1-19
PB  - Springer Wien
SN  - 09300708
KW  - Parisite-(Ce)
KW  - Rontgenite-(Ce)
KW  - Fluorcarbonate
KW  - Polycrystal
KW  - Raman spectroscopy
KW  - Stacking pattern
UR  - https://doi.org/10.1007/s00710-020-00723-x
L2  - https://doi.org/10.1007/s00710-020-00723-x
N2  - A multi-methodological study was conducted in order to provide further insight into the structural and compositional complexity of rare earth element (REE) fluorcarbonates, with particular attention to their correct assignment to a mineral species. Polycrystals from La Pita Mine, Municipality de Maripi, Boyaca Department, Colombia, show syntaxic intergrowth of parisite-(Ce) with rontgenite-(Ce) and a phase which is assigned toB(3)S(4)(i.e., bastnasite-3-synchisite-4; still unnamed) fluorcarbonate. Transmission electron microscope (TEM) images reveal well-ordered stacking patterns of two monoclinic polytypes of parisite-(Ce) as well as heavily disordered layer sequences with varying lattice fringe spacings. The crystal structure refinement from single crystal X-ray diffraction data - impeded by twinning, complex stacking patterns, sequential and compositional faults - indicates that the dominant parisite-(Ce) polytypeM(1)has space groupCc. Parisite-(Ce), theB(3)S(4)phase and rontgenite-(Ce) show different BSE intensities from high to low. Raman spectroscopic analyses of parisite-(Ce), theB(3)S(4)phase and rontgenite-(Ce) reveal different intensity ratios of the three symmetric CO(3)stretching bands at around 1100 cm(-1). We propose to non-destructively differentiate parisite-(Ce) and rontgenite-(Ce) by their 1092 cm(-1)/ 1081 cm(-1)nu(1)(CO3) band height ratio.
ER  -

ZEUG, Manuela; Lutz NASDALA; Martin ENDE; Gerlinde HABLER; Christoph HAUZENBERGER; N. Chutimun CHANMUANG; Radek ŠKODA; Dan TOPA; Manfred WILDNER a Richard WIRTH. The parisite-(Ce) enigma: challenges in the identification of fluorcarbonate minerals. \textit{Mineralogy and Petrology}. Wien: Springer Wien, 2021, roč.~115, č.~1, s.~1-19. ISSN~0930-0708. Dostupné z: https://doi.org/10.1007/s00710-020-00723-x.

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