An analysis of residue alkylphenols and bisphenol A using
liquid chromatography-tandem mass spectrometry

D 2019

An analysis of residue alkylphenols and bisphenol A using liquid chromatography-tandem mass spectrometry

PERNICA, Marek a Zdeněk ŠIMEK

Základní údaje

Originální název

An analysis of residue alkylphenols and bisphenol A using liquid chromatography-tandem mass spectrometry

Autoři

PERNICA, Marek (203 Česká republika, garant, domácí) a Zdeněk ŠIMEK (203 Česká republika, domácí)

Vydání

Brno, MENDELNET 2019: PROCEEDINGS OF 26TH INTERNATIONAL PHD STUDENTS CONFERENCE, od s. 601-605, 5 s. 2019

Nakladatel

MENDEL UNIV BRNO

Další údaje

Jazyk

angličtina

Typ výsledku

Stať ve sborníku

Obor

10618 Ecology

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Forma vydání

elektronická verze "online"

Odkazy

URL

Kód RIV

RIV/00216224:14310/19:00114631

Organizační jednotka

Přírodovědecká fakulta

ISBN

978-80-7509-688-3

UT WoS

000576735500108

Klíčová slova anglicky

blank; blank contamination; LC-MS; alkylphenols; bisphenol A

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 8. 1. 2021 11:06, Mgr. Marie Šípková, DiS.

Anotace

V originále

Bisphenol A (BPA) and alkylphenols (APs) such as 4-tert-octylphenol (4-t-OP) and mixture of nonylphenol isomers (iso-NP) are frequent contaminants of various environmental analyses. Analyse of various blanks is a serious problem in the residue analysis. Secondary contamination of analysed samples can come from laboratory air, septa vials, solvents and other chemicals used. Plastic tubes and connections could be another important source of sample contamination. This can be a problem especially in determination of alkylphenols and bisphenol A at low environmentally relevant concentrations. The analytical method for determination of residues of pollutants in water samples using solid phase extraction (SPE) followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS) is presented here. In principle, alkylphenols can be analysed without derivatization. However, pre-column derivatization with 5-(dimethylamino) naphthalene-1-sulfonyl chloride (dansylchloride, DNSC) improves the sensitivity and selectivity of LC-MS/MS analysis. The instrumental blank for all compounds is under the limit of detection (LOD). The system contamination was maintained about 0.5 ng (reagent blank), and below 0.05 mu g/L for the glass SPE columns and below 0.1 mu g/L for the plastic columns (procedure blank).

Návaznosti

GA13-20357S, projekt VaV

Název: Studium distribuce steroidních látek ve složkách pevných environmentálních matric.

Investor: Grantová agentura ČR, Studium distribuce steroidních látek ve složkách pevných environmentálních matric

LM2011028, projekt VaV

Název: RECETOX ? Národní infrastruktura pro výzkum toxických látek v prostředí

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, RECETOX Národní infrastruktura pro výzkum toxických látek v prostředí

LO1214, projekt VaV

Název: Centrum pro výzkum toxických látek v prostředí (Akronym: RECETOX)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Centrum pro výzkum toxických látek v prostředí

Citovat

PERNICA, Marek a Zdeněk ŠIMEK. An analysis of residue alkylphenols and bisphenol A using liquid chromatography-tandem mass spectrometry. Online. In Cerkal, R Belcredi, NB Prokesova, L Pilatova, A. MENDELNET 2019: PROCEEDINGS OF 26TH INTERNATIONAL PHD STUDENTS CONFERENCE. Brno: MENDEL UNIV BRNO, 2019, s. 601-605. ISBN 978-80-7509-688-3.

@inproceedings{1722179,
   author = {Pernica, Marek and Šimek, Zdeněk},
   address = {Brno},
   booktitle = {MENDELNET 2019: PROCEEDINGS OF 26TH INTERNATIONAL PHD STUDENTS CONFERENCE},
   editor = {Cerkal, R Belcredi, NB Prokesova, L Pilatova, A},
   keywords = {blank; blank contamination; LC-MS; alkylphenols; bisphenol A},
   howpublished = {elektronická verze "online"},
   language = {eng},
   location = {Brno},
   isbn = {978-80-7509-688-3},
   pages = {601-605},
   publisher = {MENDEL UNIV BRNO},
   title = {An analysis of residue alkylphenols and bisphenol A using liquid chromatography-tandem mass spectrometry},
   url = {https://mendelnet.cz/artkey/mnt-201901-0116_An-analysis-of-residue-alkylphenols-and-bisphenol-A-using-liquid-chromatography-tandem-mass-spectrometry.php?back=/magno/mnt/2019/mn1.php?secid=4},
   year = {2019}
}

TY  - JOUR
ID  - 1722179
AU  - Pernica, Marek - Šimek, Zdeněk
PY  - 2019
TI  - An analysis of residue alkylphenols and bisphenol A using liquid chromatography-tandem mass spectrometry
PB  - MENDEL UNIV BRNO
CY  - Brno
SN  - 9788075096883
KW  - blank
KW  - blank contamination
KW  - LC-MS
KW  - alkylphenols
KW  - bisphenol A
UR  - https://mendelnet.cz/artkey/mnt-201901-0116_An-analysis-of-residue-alkylphenols-and-bisphenol-A-using-liquid-chromatography-tandem-mass-spectrometry.php?back=/magno/mnt/2019/mn1.php?secid=4
L2  - https://mendelnet.cz/artkey/mnt-201901-0116_An-analysis-of-residue-alkylphenols-and-bisphenol-A-using-liquid-chromatography-tandem-mass-spectrometry.php?back=/magno/mnt/2019/mn1.php?secid=4
N2  - Bisphenol A (BPA) and alkylphenols (APs) such as 4-tert-octylphenol (4-t-OP) and mixture of nonylphenol isomers (iso-NP) are frequent contaminants of various environmental analyses. Analyse of various blanks is a serious problem in the residue analysis. Secondary contamination of analysed samples can come from laboratory air, septa vials, solvents and other chemicals used. Plastic tubes and connections could be another important source of sample contamination. This can be a problem especially in determination of alkylphenols and bisphenol A at low environmentally relevant concentrations. The analytical method for determination of residues of pollutants in water samples using solid phase extraction (SPE) followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS) is presented here. In principle, alkylphenols can be analysed without derivatization. However, pre-column derivatization with 5-(dimethylamino) naphthalene-1-sulfonyl chloride (dansylchloride, DNSC) improves the sensitivity and selectivity of LC-MS/MS analysis. The instrumental blank for all compounds is under the limit of detection (LOD). The system contamination was maintained about 0.5 ng (reagent blank), and below 0.05 mu g/L for the glass SPE columns and below 0.1 mu g/L for the plastic columns (procedure blank).
ER  -

PERNICA, Marek a Zdeněk ŠIMEK. An analysis of residue alkylphenols and bisphenol A using liquid chromatography-tandem mass spectrometry. Online. In Cerkal, R Belcredi, NB Prokesova, L Pilatova, A. \textit{MENDELNET 2019: PROCEEDINGS OF 26TH INTERNATIONAL PHD STUDENTS CONFERENCE}. Brno: MENDEL UNIV BRNO, 2019, s.~601-605. ISBN~978-80-7509-688-3.

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