Ultrafast excited state dynamics, direct and back
[2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge
transfer complex

J 2021

Ultrafast excited state dynamics, direct and back [2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge transfer complex

VOLCHKOV, Valery V.; Timofey P. MARTYANOV; Mikhail N. KHIMICH; Mikhail V. RUSALOV; Daria NEZNAEVA et al.

Základní údaje

Originální název

Ultrafast excited state dynamics, direct and back [2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge transfer complex

Autoři

Vydání

Dyes and Pigments, Oxford, Elsevier, 2021, 0143-7208

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10406 Analytical chemistry

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.122

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/21:00120962

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Styryl dyes; E-Z photoisomerization; [2+2] photocycloaddition; Cyclobutanes; Bis-crown ethers; Intrasupramolecular photo-driven electron transfer

Štítky

14313010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 13. 1. 2021 15:19, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

This research is dedicated to the study of bis(ammoniopropyl) derivative of (E)-4-(4-mercaptostyryl)pyridine dye (2), forming a highly stable bimolecular complex with a bis(18-crown-6 ether) derivative of (E)-stilbene (1) in solution owing to ditopic coordination via hydrogen bonds. The spectral-kinetic parameters of E isomer of the dye and its complex were obtained using steady-state absorption, fluorescence, and time-resolved absorption spectroscopy. The stability constant of the complex, quantum yields of cross-PCA and retro-PCA reactions were determined by spectrophotometric titration methods. According to density functional theory calculations, E-Z photoisomerization of dye 2 occurs via non-radiative deactivation from intermediate twisted (TICT) state. The detailed study of stereospecific [2 + 2]-cross-photocycloaddition (cross-PCA) of complex (E)-1.(E)-2 and back reaction of cross-PCA product (rctt-3) was carried out. The complexation reaction of cyclobutane rctt-3 with Ba2+ ions has been investigated. A highly efficient direct intrasupramolecular photoelectron transfer and the back electron transfer of a moderate efficiency were found for the complex (E)-1.(E)-2.

Citovat

VOLCHKOV, Valery V.; Timofey P. MARTYANOV; Mikhail N. KHIMICH; Mikhail V. RUSALOV; Daria NEZNAEVA; Fedor E. GOSTEV; Ivan V. SHELAEV; Victor A. NADTOCHENKO; Mikhail Ya MELNIKOV; Anna A. MOISEEVA; Evgeny N. USHAKOV a Sergey P. GROMOV. Ultrafast excited state dynamics, direct and back [2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge transfer complex. Dyes and Pigments. Oxford: Elsevier, 2021, roč. 185, February 2021, s. 1-10. ISSN 0143-7208. Dostupné z: https://doi.org/10.1016/j.dyepig.2020.108952.

@article{1727675,
   author = {Volchkov, Valery V. and Martyanov, Timofey P. and Khimich, Mikhail N. and Rusalov, Mikhail V. and Neznaeva, Daria and Gostev, Fedor E. and Shelaev, Ivan V. and Nadtochenko, Victor A. and Melnikov, Mikhail Ya and Moiseeva, Anna A. and Ushakov, Evgeny N. and Gromov, Sergey P.},
   article_location = {Oxford},
   article_number = {February 2021},
   doi = {https://doi.org/10.1016/j.dyepig.2020.108952},
   keywords = {Styryl dyes; E-Z photoisomerization; [2+2] photocycloaddition; Cyclobutanes; Bis-crown ethers; Intrasupramolecular photo-driven electron transfer},
   language = {eng},
   issn = {0143-7208},
   journal = {Dyes and Pigments},
   title = {Ultrafast excited state dynamics, direct and back [2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge transfer complex},
   url = {https://doi.org/10.1016/j.dyepig.2020.108952},
   volume = {185},
   year = {2021}
}

TY  - JOUR
ID  - 1727675
AU  - Volchkov, Valery V. - Martyanov, Timofey P. - Khimich, Mikhail N. - Rusalov, Mikhail V. - Neznaeva, Daria - Gostev, Fedor E. - Shelaev, Ivan V. - Nadtochenko, Victor A. - Melnikov, Mikhail Ya - Moiseeva, Anna A. - Ushakov, Evgeny N. - Gromov, Sergey P.
PY  - 2021
TI  - Ultrafast excited state dynamics, direct and back [2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge transfer complex
JF  - Dyes and Pigments
VL  - 185
IS  - February 2021
SP  - 1-10
EP  - 1-10
PB  - Elsevier
SN  - 01437208
KW  - Styryl dyes
KW  - E-Z photoisomerization
KW  - [2+2] photocycloaddition
KW  - Cyclobutanes
KW  - Bis-crown ethers
KW  - Intrasupramolecular photo-driven electron transfer
UR  - https://doi.org/10.1016/j.dyepig.2020.108952
L2  - https://doi.org/10.1016/j.dyepig.2020.108952
N2  - This research is dedicated to the study of bis(ammoniopropyl) derivative of (E)-4-(4-mercaptostyryl)pyridine dye (2), forming a highly stable bimolecular complex with a bis(18-crown-6 ether) derivative of (E)-stilbene (1) in solution owing to ditopic coordination via hydrogen bonds. The spectral-kinetic parameters of E isomer of the dye and its complex were obtained using steady-state absorption, fluorescence, and time-resolved absorption spectroscopy. The stability constant of the complex, quantum yields of cross-PCA and retro-PCA reactions were determined by spectrophotometric titration methods. According to density functional theory calculations, E-Z photoisomerization of dye 2 occurs via non-radiative deactivation from intermediate twisted (TICT) state. The detailed study of stereospecific [2 + 2]-cross-photocycloaddition (cross-PCA) of complex (E)-1.(E)-2 and back reaction of cross-PCA product (rctt-3) was carried out. The complexation reaction of cyclobutane rctt-3 with Ba2+ ions has been investigated. A highly efficient direct intrasupramolecular photoelectron transfer and the back electron transfer of a moderate efficiency were found for the complex (E)-1.(E)-2.
ER  -

VOLCHKOV, Valery V.; Timofey P. MARTYANOV; Mikhail N. KHIMICH; Mikhail V. RUSALOV; Daria NEZNAEVA; Fedor E. GOSTEV; Ivan V. SHELAEV; Victor A. NADTOCHENKO; Mikhail Ya MELNIKOV; Anna A. MOISEEVA; Evgeny N. USHAKOV a Sergey P. GROMOV. Ultrafast excited state dynamics, direct and back [2+2]-cross-photocy-cloaddition of a styryl dye-stilbene charge transfer complex. \textit{Dyes and Pigments}. Oxford: Elsevier, 2021, roč.~185, February 2021, s.~1-10. ISSN~0143-7208. Dostupné z: https://doi.org/10.1016/j.dyepig.2020.108952.

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