Detailed Information on Publication Record
2021
Fluorinated Bambus[6]urils for Anion Binding in Water
LAPEŠOVÁ, Jana, Jan SOKOLOV and Vladimír ŠINDELÁŘBasic information
Original name
Fluorinated Bambus[6]urils for Anion Binding in Water
Authors
LAPEŠOVÁ, Jana, Jan SOKOLOV and Vladimír ŠINDELÁŘ
Edition
55th Conference: Advances in Organic, Bioorganic and Pharmaceutical Chemistry – Liblice 2021, Špindlerův Mlýn, Czech Republic, 3 - 6 November 2021, 2021
Other information
Type of outcome
Konferenční abstrakt
Confidentiality degree
není předmětem státního či obchodního tajemství
Změněno: 19/1/2022 10:03, Mgr. Jana Lapešová
Abstract
V originále
Anion binding in water can be beneficial for many reasons, e.g., simple anion analysis, removal of toxic anions, or anion transport. However, development of synthetic anion receptors is a complex problem due to very competitive character of aqueous media. Bambus[6]urils have been recognized as potent anion receptors in various media. Water-solubility was successfully achieved by introducing carboxylate groups onto the macrocycle. Affinity of bambus[6]urils toward anions was enhanced introducing electron withdrawing groups to their structure. The aim of this project is to synthesize a water-soluble bambus[6]urils with high affinity toward anions. We suggest several strategies for preparation of water soluble fluorinated bambus[6]uril including than one in which the macrocycle is prepared from glycoluril monomers bearing both polar and fluorinated groups. Synthesis of these glycoluril derivatives and resulting bambus[6]urils will be presented.
Links
| MUNI/C/1841/2020, interní kód MU |
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