Phase formation, thermal stability and mechanical properties of
Nb-B-C coatings prepared by combinatorial magnetron sputtering

J 2022

Phase formation, thermal stability and mechanical properties of Nb-B-C coatings prepared by combinatorial magnetron sputtering

DEBNÁROVÁ, Stanislava; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Marcus HANS; Damian HOLZAPFEL et al.

Základní údaje

Originální název

Phase formation, thermal stability and mechanical properties of Nb-B-C coatings prepared by combinatorial magnetron sputtering

Autoři

DEBNÁROVÁ, Stanislava ; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Marcus HANS; Damian HOLZAPFEL; Stanislav MRÁZ; Jochen M. SCHNEIDER a Petr VAŠINA

Vydání

Surface & Coatings Technology, Elsevier, 2022, 0257-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

20506 Coating and films

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.400

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/22:00119610

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Nb-B-C; Coatings; Combinatorial magnetron sputtering; Protective coatings; Thermal stability; Mechanical properties

Štítky

14312030, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 27. 2. 2024 13:28, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

In this study, combinatorial magnetron sputtering was used to deposit Nb-B-C coatings in a wide composition range. The phase formation, thermal stability and mechanical properties of these coatings were investigated in relation to their composition and deposition conditions. The studied coatings were amorphous, short range ordered or exhibited crystalline phases such as Nb, NbC and NbB2. Higher energy flux to the coating achieved by the use of bias and heating during deposition resulted in coatings being crystalline over a wider composition range. Annealing of the coatings after deposition resulted in a higher degree of crystallinity as well as an increase in hardness and effective elastic modulus. The hardness of the coatings was up to 22.5 ± 0.7 GPa before and up to 35.0 ± 0.6 GPa after annealing. The effective elastic modulus was up to 240 ± 10 GPa before and up to 310 ± 7 GPa after annealing. Coatings with a high B content exhibited the highest hardness and elastic modulus in both cases. Coating powder was prepared by sputtering a Nb2BC target and studied using differential scanning calorimetry. The powder exhibited a crystalline NbC phase before and after annealing up to 900 °C. The material was stable in an Ar atmosphere in the studied temperature range. In an Ar + O2 mixture, the powder was stable up to ~580 °C. At this temperature, an oxidation reaction started, resulting in the formation of Nb2O5.

Návaznosti

EF19_073/0016943, projekt VaV

Název: Interní grantová agentura Masarykovy univerzity

GA19-03899S, projekt VaV

Název: Nanolaminátní vrstvy připravené magnetronovým naprašováním - perspektivní tvrdý materiál se zvýšenou lomovou houževnatostí

Investor: Grantová agentura ČR, Nanolaminátní vrstvy připravené magnetronovým naprašováním - perspektivní tvrdý materiál se zvýšenou lomovou houževnatostí

90097, velká výzkumná infrastruktura

Název: CEPLANT

Citovat

DEBNÁROVÁ, Stanislava; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Marcus HANS; Damian HOLZAPFEL; Stanislav MRÁZ; Jochen M. SCHNEIDER a Petr VAŠINA. Phase formation, thermal stability and mechanical properties of Nb-B-C coatings prepared by combinatorial magnetron sputtering. Surface & Coatings Technology. Elsevier, 2022, roč. 433, March, s. 1-9. ISSN 0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2022.128137.

@article{1826441,
   author = {Debnárová, Stanislava and Souček, Pavel and Buršíková, Vilma and Hans, Marcus and Holzapfel, Damian and Mráz, Stanislav and Schneider, Jochen M. and Vašina, Petr},
   article_number = {March},
   doi = {https://doi.org/10.1016/j.surfcoat.2022.128137},
   keywords = {Nb-B-C; Coatings; Combinatorial magnetron sputtering; Protective coatings; Thermal stability; Mechanical properties},
   language = {eng},
   issn = {0257-8972},
   journal = {Surface & Coatings Technology},
   title = {Phase formation, thermal stability and mechanical properties of Nb-B-C coatings prepared by combinatorial magnetron sputtering},
   url = {https://www.sciencedirect.com/science/article/pii/S0257897222000585},
   volume = {433},
   year = {2022}
}

TY  - JOUR
ID  - 1826441
AU  - Debnárová, Stanislava - Souček, Pavel - Buršíková, Vilma - Hans, Marcus - Holzapfel, Damian - Mráz, Stanislav - Schneider, Jochen M. - Vašina, Petr
PY  - 2022
TI  - Phase formation, thermal stability and mechanical properties of Nb-B-C coatings prepared by combinatorial magnetron sputtering
JF  - Surface & Coatings Technology
VL  - 433
IS  - March
SP  - 1-9
EP  - 1-9
PB  - Elsevier
SN  - 02578972
KW  - Nb-B-C
KW  - Coatings
KW  - Combinatorial magnetron sputtering
KW  - Protective coatings
KW  - Thermal stability
KW  - Mechanical properties
UR  - https://www.sciencedirect.com/science/article/pii/S0257897222000585
N2  - In this study, combinatorial magnetron sputtering was used to deposit Nb-B-C coatings in a wide composition range. The phase formation, thermal stability and mechanical properties of these coatings were investigated in relation to their composition and deposition conditions. The studied coatings were amorphous, short range ordered or exhibited crystalline phases such as Nb, NbC and NbB2. Higher energy flux to the coating achieved by the use of bias and heating during deposition resulted in coatings being crystalline over a wider composition range. Annealing of the coatings after deposition resulted in a higher degree of crystallinity as well as an increase in hardness and effective elastic modulus. The hardness of the coatings was up to 22.5 ± 0.7 GPa before and up to 35.0 ± 0.6 GPa after annealing. The effective elastic modulus was up to 240 ± 10 GPa before and up to 310 ± 7 GPa after annealing. Coatings with a high B content exhibited the highest hardness and elastic modulus in both cases. Coating powder was prepared by sputtering a Nb2BC target and studied using differential scanning calorimetry. The powder exhibited a crystalline NbC phase before and after annealing up to 900 °C. The material was stable in an Ar atmosphere in the studied temperature range. In an Ar + O2 mixture, the powder was stable up to ~580 °C. At this temperature, an oxidation reaction started, resulting in the formation of Nb2O5.
ER  -

DEBNÁROVÁ, Stanislava; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Marcus HANS; Damian HOLZAPFEL; Stanislav MRÁZ; Jochen M. SCHNEIDER a Petr VAŠINA. Phase formation, thermal stability and mechanical properties of Nb-B-C coatings prepared by combinatorial magnetron sputtering. \textit{Surface \&{} Coatings Technology}. Elsevier, 2022, roč.~433, March, s.~1-9. ISSN~0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2022.128137.

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