Revelation of high-adsorption-performance activated carbon for
removal of fluoroquinolone antibiotics from water

J 2024

Revelation of high-adsorption-performance activated carbon for removal of fluoroquinolone antibiotics from water

BEDNÁREK, Jan; Lenka MATĚJOVÁ; Ivan KOUTNÍK; Martina VRÁBLOVÁ; Francisco Gerardo Juan CRUZ et al.

Základní údaje

Originální název

Revelation of high-adsorption-performance activated carbon for removal of fluoroquinolone antibiotics from water

Autoři

BEDNÁREK, Jan; Lenka MATĚJOVÁ; Ivan KOUTNÍK; Martina VRÁBLOVÁ; Francisco Gerardo Juan CRUZ; Tomáš STRAŠÁK; Pavel ŠILER a Jan HRBÁČ

Vydání

Biomass Conversion and Biorefinery, Springer, 2024, 2190-6815

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10403 Physical chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.100

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/24:00135016

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Activated carbon; Agricultural waste; Antibiotics; Adsorption; Water treatment

Štítky

14313010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 9. 2. 2025 18:48, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

The preparation of carbonaceous sorbents can combine the use of waste material and the improvement of water quality. Six activated carbons prepared from different agricultural waste biomasses were tested for adsorption of norfloxacin and ofloxacin fluoroquinolone antibiotics from water. Activated carbons were prepared by conventional pyrolysis at 600 degrees C in a nitrogen atmosphere of ZnCl2-activated red mombin seeds (RMS), corn cob (CC), coffee husk (CH), internal and external parts of mango seeds (MSEP, MSIP), and ice cream beans (GS), which are widely available as agro-industrial biomass wastes in Latin America. The textural and surface properties of prepared activated carbons were thoroughly investigated, and the sorption mechanism was described through proper kinetic and adsorption isotherm models. Moreover, the molecular dimensions of norfloxacin and ofloxacin were estimated to consider the possible sterical shielding of micropores of the investigated activated carbons. Norfloxacin and ofloxacin were strongly adsorbed onto all investigated activated carbons. Adsorption kinetics fitted best to Elovich model; adsorption isotherms correlated best with Redlich-Peterson model. Maximum adsorption capacities, obtained from Langmuir model, were 404 mg.g(-1) for norfloxacin and 380 mg.g(-1) for ofloxacin. The best adsorption performance was observed for RMS-based activated carbon. A comparison of prepared materials led to the conclusion that high micropore volume and net pore volume are the determining properties of good adsorption performance in the case of removal of fluoroquinolone antibiotics from water.

Návaznosti

90098, velká výzkumná infrastruktura

Název: ENREGAT

Citovat

BEDNÁREK, Jan; Lenka MATĚJOVÁ; Ivan KOUTNÍK; Martina VRÁBLOVÁ; Francisco Gerardo Juan CRUZ; Tomáš STRAŠÁK; Pavel ŠILER a Jan HRBÁČ. Revelation of high-adsorption-performance activated carbon for removal of fluoroquinolone antibiotics from water. Biomass Conversion and Biorefinery. Springer, 2024, roč. 14, č. 2, s. 2585-2599. ISSN 2190-6815. Dostupné z: https://doi.org/10.1007/s13399-022-02577-z.

@article{1855518,
   author = {Bednárek, Jan and Matějová, Lenka and Koutník, Ivan and Vráblová, Martina and Cruz, Francisco Gerardo Juan and Strašák, Tomáš and Šiler, Pavel and Hrbáč, Jan},
   article_number = {2},
   doi = {https://doi.org/10.1007/s13399-022-02577-z},
   keywords = {Activated carbon; Agricultural waste; Antibiotics; Adsorption; Water treatment},
   language = {eng},
   issn = {2190-6815},
   journal = {Biomass Conversion and Biorefinery},
   title = {Revelation of high-adsorption-performance activated carbon for removal of fluoroquinolone antibiotics from water},
   url = {https://link.springer.com/article/10.1007/s13399-022-02577-z},
   volume = {14},
   year = {2024}
}

TY  - JOUR
ID  - 1855518
AU  - Bednárek, Jan - Matějová, Lenka - Koutník, Ivan - Vráblová, Martina - Cruz, Francisco Gerardo Juan - Strašák, Tomáš - Šiler, Pavel - Hrbáč, Jan
PY  - 2024
TI  - Revelation of high-adsorption-performance activated carbon for removal of fluoroquinolone antibiotics from water
JF  - Biomass Conversion and Biorefinery
VL  - 14
IS  - 2
SP  - 2585-2599
EP  - 2585-2599
PB  - Springer
SN  - 21906815
KW  - Activated carbon
KW  - Agricultural waste
KW  - Antibiotics
KW  - Adsorption
KW  - Water treatment
UR  - https://link.springer.com/article/10.1007/s13399-022-02577-z
N2  - The preparation of carbonaceous sorbents can combine the use of waste material and the improvement of water quality. Six activated carbons prepared from different agricultural waste biomasses were tested for adsorption of norfloxacin and ofloxacin fluoroquinolone antibiotics from water. Activated carbons were prepared by conventional pyrolysis at 600 degrees C in a nitrogen atmosphere of ZnCl2-activated red mombin seeds (RMS), corn cob (CC), coffee husk (CH), internal and external parts of mango seeds (MSEP, MSIP), and ice cream beans (GS), which are widely available as agro-industrial biomass wastes in Latin America. The textural and surface properties of prepared activated carbons were thoroughly investigated, and the sorption mechanism was described through proper kinetic and adsorption isotherm models. Moreover, the molecular dimensions of norfloxacin and ofloxacin were estimated to consider the possible sterical shielding of micropores of the investigated activated carbons. Norfloxacin and ofloxacin were strongly adsorbed onto all investigated activated carbons. Adsorption kinetics fitted best to Elovich model; adsorption isotherms correlated best with Redlich-Peterson model. Maximum adsorption capacities, obtained from Langmuir model, were 404 mg.g(-1) for norfloxacin and 380 mg.g(-1) for ofloxacin. The best adsorption performance was observed for RMS-based activated carbon. A comparison of prepared materials led to the conclusion that high micropore volume and net pore volume are the determining properties of good adsorption performance in the case of removal of fluoroquinolone antibiotics from water.
ER  -

BEDNÁREK, Jan; Lenka MATĚJOVÁ; Ivan KOUTNÍK; Martina VRÁBLOVÁ; Francisco Gerardo Juan CRUZ; Tomáš STRAŠÁK; Pavel ŠILER a Jan HRBÁČ. Revelation of high-adsorption-performance activated carbon for removal of fluoroquinolone antibiotics from water. \textit{Biomass Conversion and Biorefinery}. Springer, 2024, roč.~14, č.~2, s.~2585-2599. ISSN~2190-6815. Dostupné z: https://doi.org/10.1007/s13399-022-02577-z.

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