NOVOSAD, David, Miroslava HRENÁKOVÁ, Jan VACEK, Jan STORCH, Jakub STYSKALA a Jan HRBÁČ. Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization. Journal of Electroanalytical Chemistry. Lausanne: Elsevier, 2022, roč. 912, May, s. 1-10. ISSN 1572-6657. Dostupné z: https://dx.doi.org/10.1016/j.jelechem.2022.116261. |
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@article{1855519, author = {Novosad, David and Hrenáková, Miroslava and Vacek, Jan and Storch, Jan and Styskala, Jakub and Hrbáč, Jan}, article_location = {Lausanne}, article_number = {May}, doi = {http://dx.doi.org/10.1016/j.jelechem.2022.116261}, keywords = {Electropolymerization; Cyclopentenedione; Thin layer; Carbon electrode; dopamine sensing}, language = {eng}, issn = {1572-6657}, journal = {Journal of Electroanalytical Chemistry}, title = {Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization}, url = {https://www.sciencedirect.com/science/article/pii/S1572665722002533}, volume = {912}, year = {2022} }
TY - JOUR ID - 1855519 AU - Novosad, David - Hrenáková, Miroslava - Vacek, Jan - Storch, Jan - Styskala, Jakub - Hrbáč, Jan PY - 2022 TI - Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization JF - Journal of Electroanalytical Chemistry VL - 912 IS - May SP - 1-10 EP - 1-10 PB - Elsevier SN - 15726657 KW - Electropolymerization KW - Cyclopentenedione KW - Thin layer KW - Carbon electrode KW - dopamine sensing UR - https://www.sciencedirect.com/science/article/pii/S1572665722002533 N2 - This work focuses on the preparation and optimization of organic functional layers based on 4-cyclopentene1,3-dione. Hybrid molecules composed of 4-cyclopentene-1,3-dione anchored to a polymerizable moiety based either on pyrrole or methoxybenzene derivatives were synthesized and used for the preparation of thin films by electropolymerization. It is shown that the cyclopentenedione-containing films suppress the ascorbate (negatively charged) electrochemical response when deposited on glassy carbon electrodes, while the response connected to dopamine (positively charged) electrooxidation remains unaffected or is only slightly suppressed. The ascorbate-dopamine selectivity was studied in detail by voltammetry with stationary and rotating disk electrodes. ER -
NOVOSAD, David, Miroslava HRENÁKOVÁ, Jan VACEK, Jan STORCH, Jakub STYSKALA a Jan HRBÁČ. Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization. \textit{Journal of Electroanalytical Chemistry}. Lausanne: Elsevier, 2022, roč.~912, May, s.~1-10. ISSN~1572-6657. Dostupné z: https://dx.doi.org/10.1016/j.jelechem.2022.116261.
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