Cyclopentenedione-based ascorbate-rejecting permselective
layers prepared by electropolymerization

J 2022

Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization

NOVOSAD, David; Miroslava HRENÁKOVÁ; Jan VACEK; Jan STORCH; Jakub STYSKALA et al.

Základní údaje

Originální název

Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization

Autoři

NOVOSAD, David; Miroslava HRENÁKOVÁ; Jan VACEK; Jan STORCH; Jakub STYSKALA a Jan HRBÁČ

Vydání

Journal of Electroanalytical Chemistry, Lausanne, Elsevier, 2022, 1572-6657

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10405 Electrochemistry

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 4.500

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/22:00125868

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Electropolymerization; Cyclopentenedione; Thin layer; Carbon electrode; dopamine sensing

Štítky

14313010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 9. 1. 2023 16:59, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

This work focuses on the preparation and optimization of organic functional layers based on 4-cyclopentene1,3-dione. Hybrid molecules composed of 4-cyclopentene-1,3-dione anchored to a polymerizable moiety based either on pyrrole or methoxybenzene derivatives were synthesized and used for the preparation of thin films by electropolymerization. It is shown that the cyclopentenedione-containing films suppress the ascorbate (negatively charged) electrochemical response when deposited on glassy carbon electrodes, while the response connected to dopamine (positively charged) electrooxidation remains unaffected or is only slightly suppressed. The ascorbate-dopamine selectivity was studied in detail by voltammetry with stationary and rotating disk electrodes.

Citovat

NOVOSAD, David; Miroslava HRENÁKOVÁ; Jan VACEK; Jan STORCH; Jakub STYSKALA a Jan HRBÁČ. Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization. Journal of Electroanalytical Chemistry. Lausanne: Elsevier, 2022, roč. 912, May, s. 1-10. ISSN 1572-6657. Dostupné z: https://doi.org/10.1016/j.jelechem.2022.116261.

@article{1855519,
   author = {Novosad, David and Hrenáková, Miroslava and Vacek, Jan and Storch, Jan and Styskala, Jakub and Hrbáč, Jan},
   article_location = {Lausanne},
   article_number = {May},
   doi = {https://doi.org/10.1016/j.jelechem.2022.116261},
   keywords = {Electropolymerization; Cyclopentenedione; Thin layer; Carbon electrode; dopamine sensing},
   language = {eng},
   issn = {1572-6657},
   journal = {Journal of Electroanalytical Chemistry},
   title = {Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization},
   url = {https://www.sciencedirect.com/science/article/pii/S1572665722002533},
   volume = {912},
   year = {2022}
}

TY  - JOUR
ID  - 1855519
AU  - Novosad, David - Hrenáková, Miroslava - Vacek, Jan - Storch, Jan - Styskala, Jakub - Hrbáč, Jan
PY  - 2022
TI  - Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization
JF  - Journal of Electroanalytical Chemistry
VL  - 912
IS  - May
SP  - 1-10
EP  - 1-10
PB  - Elsevier
SN  - 15726657
KW  - Electropolymerization
KW  - Cyclopentenedione
KW  - Thin layer
KW  - Carbon electrode
KW  - dopamine sensing
UR  - https://www.sciencedirect.com/science/article/pii/S1572665722002533
N2  - This work focuses on the preparation and optimization of organic functional layers based on 4-cyclopentene1,3-dione. Hybrid molecules composed of 4-cyclopentene-1,3-dione anchored to a polymerizable moiety based either on pyrrole or methoxybenzene derivatives were synthesized and used for the preparation of thin films by electropolymerization. It is shown that the cyclopentenedione-containing films suppress the ascorbate (negatively charged) electrochemical response when deposited on glassy carbon electrodes, while the response connected to dopamine (positively charged) electrooxidation remains unaffected or is only slightly suppressed. The ascorbate-dopamine selectivity was studied in detail by voltammetry with stationary and rotating disk electrodes.
ER  -

NOVOSAD, David; Miroslava HRENÁKOVÁ; Jan VACEK; Jan STORCH; Jakub STYSKALA a Jan HRBÁČ. Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization. \textit{Journal of Electroanalytical Chemistry}. Lausanne: Elsevier, 2022, roč.~912, May, s.~1-10. ISSN~1572-6657. Dostupné z: https://doi.org/10.1016/j.jelechem.2022.116261.

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