Synthesis and Structure of Cyclic Selenium Oxide
Se(IV)Se2(IV)O7.

J 1996

Synthesis and Structure of Cyclic Selenium Oxide Se(IV)Se2(IV)O7.

TOUŽÍN, Jiří, Petr KILIÁN a Zdirad ŽÁK

Základní údaje

Originální název

Synthesis and Structure of Cyclic Selenium Oxide Se(IV)Se2(IV)O7.

Autoři

TOUŽÍN, Jiří (203 Česká republika, garant), Petr KILIÁN (203 Česká republika) a Zdirad ŽÁK (203 Česká republika)

Vydání

Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -], Heidelberg, Johan Ambrosius Barth Verlag, 1996, 0044-2313

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Kód RIV

RIV/00216224:14310/96:00003775

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

Seleniumoxide; nitrosylhydrogenoligoselenate; nitrosylhydrogenselenatoselenite; preparation; crystal structure; molecular structure; vibrational spectra

Štítky

Crystal Structure, molecular structure, nitrosylhydrogenoligoselenate, nitrosylhydrogenselenatoselenite, Preparation, Seleniumoxide, vibrational spectra

Změněno: 21. 5. 2003 13:56, doc. RNDr. Jiří Toužín, CSc.

Anotace

V originále

Nitromethane is the only presently known organic solvent for highly reactive selenium trioxide (SeO3)4. The stability of the solutions is limited and the beginning of the reaction between both components depends significantly on concentration and tem perature. The nitromethane solvate of cyclic triselenium heptoxide Se3O7.CH3NO2 is the major solid product at the temperature 20 - 30 oC and concentration range 3 - 20 % SeO3. Crystal and molecular structure of this compound was determined by X-ray structure analysis and vibrational spectroscopy. The solvating molecule CH3NO2 is removable from Se3O7.CH3NO2 in vacuo. If reaction temperature does not exceed 10 oC, selenium pentoxide (Se2O5)n is formed instead of Se3O7.CH3NO2. Dinitrosyl triselenate (NO)2Se3O10, nitrosyl hydrogendiselenate NOHSe2O7, nitrosyl hyd rogenselenate NOHSeO4, nitrosyl hydrogenselenatoselenite NOHSe2O6 and selenium dioxide (SeO2)n were further identified in the solid reaction products. The selenic and/or oligoselenic acids remains in the nitromethane solution. CO2 and N2O3 were found as gaseous products.

Návaznosti

GA203/95/1190, projekt VaV

Název: Struktura a vazba ve sloučeninách dusíku, fosforu, síry a selenu a v komplexech kovů triády železa s N,P,S-ligandy

Investor: Grantová agentura ČR, Struktura a vazba ve sloučeninách dusíku, fosforu, síry a selenu a v komplexech kovů triády železa s N,P,S-ligandy

Citovat

TOUŽÍN, Jiří, Petr KILIÁN a Zdirad ŽÁK. Synthesis and Structure of Cyclic Selenium Oxide Se(IV)Se2(IV)O7. Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]. Heidelberg: Johan Ambrosius Barth Verlag, 1996, roč. 1996, č. 622, s. 1617-1622. ISSN 0044-2313.

@article{197534,
   author = {Toužín, Jiří and Kilián, Petr and Žák, Zdirad},
   article_location = {Heidelberg},
   article_number = {622},
   keywords = {Seleniumoxide; nitrosylhydrogenoligoselenate; nitrosylhydrogenselenatoselenite; preparation; crystal structure; molecular structure; vibrational spectra},
   language = {eng},
   issn = {0044-2313},
   journal = {Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]},
   title = {Synthesis and Structure of Cyclic Selenium Oxide Se(IV)Se2(IV)O7.},
   volume = {1996},
   year = {1996}
}

TY  - JOUR
ID  - 197534
AU  - Toužín, Jiří - Kilián, Petr - Žák, Zdirad
PY  - 1996
TI  - Synthesis and Structure of Cyclic Selenium Oxide Se(IV)Se2(IV)O7.
JF  - Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]
VL  - 1996
IS  - 622
SP  - 1617
EP  - 1617
PB  - Johan Ambrosius Barth Verlag
SN  - 00442313
KW  - Seleniumoxide
KW  - nitrosylhydrogenoligoselenate
KW  - nitrosylhydrogenselenatoselenite
KW  - preparation
KW  - crystal structure
KW  - molecular structure
KW  - vibrational spectra
N2  - Nitromethane is the only presently known organic solvent for highly reactive selenium trioxide (SeO3)4. The stability of the solutions is limited and the beginning of the reaction between both components depends significantly on concentration and tem perature. The nitromethane solvate of cyclic triselenium heptoxide Se3O7.CH3NO2 is the major solid product at the temperature 20 - 30 oC and concentration range 3 - 20 % SeO3. Crystal and molecular structure of this compound was determined by X-ray structure analysis and vibrational spectroscopy. The solvating molecule CH3NO2 is removable from Se3O7.CH3NO2 in vacuo. If reaction temperature does not exceed 10 oC, selenium pentoxide (Se2O5)n is formed instead of Se3O7.CH3NO2. Dinitrosyl triselenate (NO)2Se3O10, nitrosyl hydrogendiselenate NOHSe2O7, nitrosyl hyd rogenselenate NOHSeO4, nitrosyl hydrogenselenatoselenite NOHSe2O6 and selenium dioxide (SeO2)n were further identified in the solid reaction products. The selenic and/or oligoselenic acids remains in the nitromethane solution. CO2 and N2O3 were found as gaseous products.
ER  -

TOUŽÍN, Jiří, Petr KILIÁN a Zdirad ŽÁK. Synthesis and Structure of Cyclic Selenium Oxide Se(IV)Se2(IV)O7. \textit{Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]}. Heidelberg: Johan Ambrosius Barth Verlag, 1996, roč.~1996, č.~622, s.~1617-1622. ISSN~0044-2313.

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