The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure
of P3N3Cl5(NH2).

J 1997

The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).

ALBERTI, Milan, Josef BŘÍNEK, Jaromír MAREK and Jiří TOUŽÍN

Basic information

Original name

The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).

Name in Czech

Reakce P3N3Cl4(NH2)2 s HCl: krystalová struktura P3N3Cl5(NH2).

Authors

ALBERTI, Milan (203 Czech Republic, guarantor), Josef BŘÍNEK (203 Czech Republic), Jaromír MAREK (203 Czech Republic) and Jiří TOUŽÍN (203 Czech Republic)

Edition

Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -], Heidelberg, Johan Ambrosius Barth Verlag, 1997, 0044-2313

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Germany

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.109

RIV identification code

RIV/00216224:14310/97:00003795

Organization unit

Faculty of Science

Keywords in English

preparation; crystal structure; molecular structure; vibrational spectra

Abstract

ORIG CZ

V originále

P3N3Cl5(NH2) in high purity and good yield can be obtained by the reaction of P3N3Cl4(NH2)2 with gaseous HCl in acetonitrile If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)2+Cl- is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2)was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2)and [P3N3Cl4H(NH2)2+Cl- are also briefly discussed.

In Czech

Reakcí P3N3Cl4(NH2)2 s HCl v acetonitrilu lze připravit ve vysokém výtěžku P3N3Cl5(NH2), jehož krystalová struktura byla určena RTG strukturní analýzou. Při použití diethyletheru nebo dichlormethanu vzniká při této reakci fosfazeniová sůl [P3N3Cl4H(NH2)2]+Cl-. Diskutována byla vibrační spektra obou látek a studováno jejich termické chování.

Links

GA203/95/1190, research and development project

Name: Struktura a vazba ve sloučeninách dusíku, fosforu, síry a selenu a v komplexech kovů triády železa s N,P,S-ligandy

Investor: Czech Science Foundation, Structure and Bonding in the Compounds of Nitrogen,Phosphorus,Sulfur and Selenium and in the Complexes of Fe,Co,and Ni with N,P,S-Ligands

Citovat

ALBERTI, Milan, Josef BŘÍNEK, Jaromír MAREK and Jiří TOUŽÍN. The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2). (The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.). Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]. Heidelberg: Johan Ambrosius Barth Verlag, 1997, vol. 1997, No 623, p. 637-641. ISSN 0044-2313.

@article{197886,
   author = {Alberti, Milan and Břínek, Josef and Marek, Jaromír and Toužín, Jiří},
   article_location = {Heidelberg},
   article_number = {623},
   keywords = {preparation; crystal structure; molecular structure; vibrational spectra},
   language = {eng},
   issn = {0044-2313},
   journal = {Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]},
   title = {The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).},
   volume = {1997},
   year = {1997}
}

TY  - JOUR
ID  - 197886
AU  - Alberti, Milan - Břínek, Josef - Marek, Jaromír - Toužín, Jiří
PY  - 1997
TI  - The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).
JF  - Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]
VL  - 1997
IS  - 623
SP  - 637
EP  - 637
PB  - Johan Ambrosius Barth Verlag
SN  - 00442313
KW  - preparation
KW  - crystal structure
KW  - molecular structure
KW  - vibrational spectra
N2  - P3N3Cl5(NH2) in high purity and good yield can be obtained by the reaction of P3N3Cl4(NH2)2 with gaseous HCl in acetonitrile If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)2+Cl- is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2)was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2)and [P3N3Cl4H(NH2)2+Cl- are also briefly discussed.
ER  -

ALBERTI, Milan, Josef BŘÍNEK, Jaromír MAREK and Jiří TOUŽÍN. The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2). (The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.). \textit{Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]}. Heidelberg: Johan Ambrosius Barth Verlag, 1997, vol.~1997, No~623, p.~637-641. ISSN~0044-2313.

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