Syntheses, Structures and Thermal Behavior of Cu hfacac
Complexes Derived from Ethanolamines

J 1997

Syntheses, Structures and Thermal Behavior of Cu hfacac Complexes Derived from Ethanolamines

PINKAS, Jiří, J. C. HUFFMAN, J. C. BOLLINGER, W. E. STREIB, D. V. BAXTER et. al.

Basic information

Original name

Syntheses, Structures and Thermal Behavior of Cu hfacac Complexes Derived from Ethanolamines

Authors

PINKAS, Jiří, J. C. HUFFMAN, J. C. BOLLINGER, W. E. STREIB, D. V. BAXTER, M. H. CHISHOLM and K. G. CAULTON

Edition

Inorg. Chem. Spojené státy americké, American Chemical Society, 1997, 0020-1669

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United States of America

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.736

Organization unit

Faculty of Science

Keywords in English

copper; MOCVD; ethanolamines; thin films

Abstract

V originále

A series of novel precursors for MOCVD of metallic copper have been synthesized and structurally characterized. The mechanism of their transformation was studied by XRD, MS, NMR, DSC, and TGA-MS techniques. These precursors are formed from Cu(hfacac)2, which serves as a volatile source of Cu, and aminoalcohols, which act as reductants and anchor firmly to the copper center through the amine unit. In some cases, a proton transfer from the coordinated alcohol to the hfacac ligand results in the formation of an alkoxide unit and the release of the free Hhfacac. Metallic copper films can be deposited by MOCVD at 300 oC without any external reductant. Crystal data: Cu(hfacac)2.C7H8 (-103 oC); a = 6.510(6) A, b = 8.594(7) A, c = 18.478(15) A, orthorhombic space group Pmnn, Z = 2. Cu(hfacac)2(H2NCH2CH2OH) (-158 oC); a = 13.145(1) A, b = 13.418(1) A, c = 11.245(1) A, alpha = 110.39(1), beta = 99.12(1), gamma = 97.90(1) deg, triclinic space group P1bar, Z = 4. [Cu(hfacac)(Me2NCH2CH2O)]2 (-153 oC); a = 9.259(2) A, b = 12.011(3) A, c = 6.304(1) A, alpha = 91.19(1), beta = 106.66(1), gamma = 74.83(1) deg, triclinic space group P1bar, Z = 1. Cu(hfacac)[N(CH2CH2OH)2(CH2CH2O)].1/2MeOH (-168 oC); a = 10.075(4) A, b = 8.611(4) A, c = 19.259(9) A, beta = 99.82(2) deg, monoclinic space group P21/m, Z = 4.

Citovat

PINKAS, Jiří, J. C. HUFFMAN, J. C. BOLLINGER, W. E. STREIB, D. V. BAXTER, M. H. CHISHOLM and K. G. CAULTON. Syntheses, Structures and Thermal Behavior of Cu hfacac Complexes Derived from Ethanolamines. Inorg. Chem. Spojené státy americké: American Chemical Society, 1997, vol. 36, No 14, p. 2930-2937. ISSN 0020-1669.

@article{203300,
   author = {Pinkas, Jiří and Huffman, J. C. and Bollinger, J. C. and Streib, W. E. and Baxter, D. V. and Chisholm, M. H. and Caulton, K. G.},
   article_location = {Spojené státy americké},
   article_number = {14},
   keywords = {copper; MOCVD; ethanolamines; thin films},
   language = {eng},
   issn = {0020-1669},
   journal = {Inorg. Chem.},
   title = {Syntheses, Structures and Thermal Behavior of Cu hfacac Complexes Derived from Ethanolamines},
   volume = {36},
   year = {1997}
}

TY  - JOUR
ID  - 203300
AU  - Pinkas, Jiří - Huffman, J. C. - Bollinger, J. C. - Streib, W. E. - Baxter, D. V. - Chisholm, M. H. - Caulton, K. G.
PY  - 1997
TI  - Syntheses, Structures and Thermal Behavior of Cu hfacac Complexes Derived from Ethanolamines
JF  - Inorg. Chem.
VL  - 36
IS  - 14
SP  - 2930
EP  - 2930
PB  - American Chemical Society
SN  - 00201669
KW  - copper
KW  - MOCVD
KW  - ethanolamines
KW  - thin films
N2  - A series of novel precursors for MOCVD of metallic copper have been synthesized and structurally characterized. The mechanism of their transformation was studied by XRD, MS, NMR, DSC, and TGA-MS techniques. These precursors are formed from Cu(hfacac)2, which serves as a volatile source of Cu, and aminoalcohols, which act as reductants and anchor firmly to the copper center through the amine unit. In some cases, a proton transfer from the coordinated alcohol to the hfacac ligand results in the formation of an alkoxide unit and the release of the free Hhfacac. Metallic copper films can be deposited by MOCVD at 300 oC without any external reductant. Crystal data: Cu(hfacac)2.C7H8 (-103 oC); a = 6.510(6) A, b = 8.594(7) A, c = 18.478(15) A, orthorhombic space group Pmnn, Z = 2. Cu(hfacac)2(H2NCH2CH2OH) (-158 oC); a = 13.145(1) A, b = 13.418(1) A, c = 11.245(1) A, alpha = 110.39(1), beta = 99.12(1), gamma = 97.90(1) deg, triclinic space group P1bar, Z = 4. [Cu(hfacac)(Me2NCH2CH2O)]2 (-153 oC); a = 9.259(2) A, b = 12.011(3) A, c = 6.304(1) A, alpha = 91.19(1), beta = 106.66(1), gamma = 74.83(1) deg, triclinic space group P1bar, Z = 1. Cu(hfacac)[N(CH2CH2OH)2(CH2CH2O)].1/2MeOH (-168 oC); a = 10.075(4) A, b = 8.611(4) A, c = 19.259(9) A, beta = 99.82(2) deg, monoclinic space group P21/m, Z = 4.
ER  -

PINKAS, Jiří, J. C. HUFFMAN, J. C. BOLLINGER, W. E. STREIB, D. V. BAXTER, M. H. CHISHOLM and K. G. CAULTON. Syntheses, Structures and Thermal Behavior of Cu hfacac Complexes Derived from Ethanolamines. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, 1997, vol.~36, No~14, p.~2930-2937. ISSN~0020-1669.

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