Dimethylamino Gallatrane: Solution and Gas Phase Behavior

PINKAS, Jiří and J. G. VERKADE. Dimethylamino Gallatrane: Solution and Gas Phase Behavior. Polyhedron. Velká Británie: PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 1996, vol. 15, No 9, p. 1567-1569. ISSN 0277-5387.

Basic information

Original name

Dimethylamino Gallatrane: Solution and Gas Phase Behavior

Authors

PINKAS, Jiří and J. G. VERKADE

Edition

Polyhedron, Velká Británie, PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 1996, 0277-5387

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Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Organization unit

Faculty of Science

Keywords in English

tautomerism; gallium; atranes

Tags

ATRANES, gallium, tautomerism

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Abstract

V originále

The gallatrane Ga(OCH2CH2)(3)N (1) forms a dimethylamine adduct, which exists in solutions in two tautomeric forms : a tricyclic cage, Me(2)NHGa(OCH2CH2)(3)N, and an open-cage bicyclic species Me(2)NGa(OCH2CH2)(2)NCH2CH2OH, which were identified by H-1, C-13 and Ga-71 NMR spectroscopy. The mass spectrum of the adduct revealed a homologous series of oligomers of 1(n), where n = 1, 2, 3 and 4.