Dimethylamino Gallatrane: Solution and Gas Phase Behavior

PINKAS, Jiří and J. G. VERKADE. Dimethylamino Gallatrane: Solution and Gas Phase Behavior. Polyhedron. Velká Británie: PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 1996, vol. 15, No 9, p. 1567-1569. ISSN 0277-5387.

Basic information

Original name

Dimethylamino Gallatrane: Solution and Gas Phase Behavior

Authors

PINKAS, Jiří and J. G. VERKADE

Edition

Polyhedron, Velká Británie, PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 1996, 0277-5387

---

Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

is not subject to a state or trade secret

Organization unit

Faculty of Science

Keywords in English

tautomerism; gallium; atranes

Tags

ATRANES, gallium, tautomerism

---

Abstract

V originále

The gallatrane Ga(OCH2CH2)(3)N (1) forms a dimethylamine adduct, which exists in solutions in two tautomeric forms : a tricyclic cage, Me(2)NHGa(OCH2CH2)(3)N, and an open-cage bicyclic species Me(2)NGa(OCH2CH2)(2)NCH2CH2OH, which were identified by H-1, C-13 and Ga-71 NMR spectroscopy. The mass spectrum of the adduct revealed a homologous series of oligomers of 1(n), where n = 1, 2, 3 and 4.