The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-

ALBERTI, Milan, Aleš MAREČEK, Zdirad ŽÁK and Petr PASTERA. The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-. Zeitschrift für Anorganische und Allgemeine Chemie. Heidelberg: Johan Ambrosius Barth Verlag, 1995, vol. 1995, No 621, p. 1771-1774. ISSN 0044-2313.

Basic information

• Original name: The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-
• Name in Czech: Reakce [P3N3Cl4(NH2)2] s [HN(POCl2)2]; krystalová struktura fosfazeniové soli [P3N3HCl4(NH2)2]+ [N(POCl2)2]-
• Authors: ALBERTI, Milan (203 Czech Republic, guarantor), Aleš MAREČEK (203 Czech Republic), Zdirad ŽÁK (203 Czech Republic) and Petr PASTERA (203 Czech Republic).
• Edition: Zeitschrift für Anorganische und Allgemeine Chemie, Heidelberg, Johan Ambrosius Barth Verlag, 1995, 0044-2313.

Other information

• Original language: English
• Type of outcome: Article in a journal
• Field of Study: 10402 Inorganic and nuclear chemistry
• Country of publisher: Germany
• Confidentiality degree: is not subject to a state or trade secret
• RIV identification code: RIV/00216224:14310/95:00011261
• Organization unit: Faculty of Science
• Keywords in English: phosphazenium salt; crystal structure; preparation
• Tags: Crystal Structure, phosphazenium salt, Preparation

Abstract

The reaction of diaminotetrachloro-cyclotriphosphazene with tetrachloride of imino-diphosphoric acid lead to the formation of the salt-like compound [P3N3HCl4(NH2)2]+[N(POCl2)2]-, which identity was unambiguously established by means of X-ray structure analysis.

Abstract (in Czech)

Reakce diamidotetrachloro-cyklotrifosfazenu s tetrachloridem imidodifosforečné kyseliny vede k formování fosfazeniové soli [P3N3HCl4(NH2)2]+[N(POCl2)2], jejíž molekulová struktura byla jednoznačně určena RTG difrakcí na monokrystalu.

Links

• GA203/95/1190, research and development project: Name: Struktura a vazba ve sloučeninách dusíku, fosforu, síry a selenu a v komplexech kovů triády železa s N,P,S-ligandy

Investor: Czech Science Foundation, Structure and Bonding in the Compounds of Nitrogen,Phosphorus,Sulfur and Selenium and in the Complexes of Fe,Co,and Ni with N,P,S-Ligands