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@article{211951,
author = {Cea Oliveras, R. and García Montalvo, V. and Novosad, J. and Kilián, P. and Woollins, JD and Slawin, AMZ},
article_number = {124&125},
keywords = {phosphazene metallacycles; selenium ligands; main group complexes; Sn(II) square planar},
language = {eng},
issn = {1042-6507},
journal = {Phosphorus, Sulfur Silicon Rel. Elem.},
title = {Structural Diversity of [M{N(SePPh2)2/Se,Se'}2,3] [M(II)=Sn, Pb, Cd, Hg, Se; M(III)=In, Sb, Bi].},
volume = {1997},
year = {1997}
}
TY - JOUR
ID - 211951
AU - Cea Oliveras, R. - García Montalvo, V. - Novosad, J. - Kilián, P. - Woollins, JD - Slawin, AMZ
PY - 1997
TI - Structural Diversity of [M{N(SePPh2)2/Se,Se'}2,3] [M(II)=Sn, Pb, Cd, Hg, Se; M(III)=In, Sb, Bi].
JF - Phosphorus, Sulfur Silicon Rel. Elem.
VL - 1997
IS - 124&125
SP - 347-354
EP - 347-354
SN - 10426507
KW - phosphazene metallacycles
KW - selenium ligands
KW - main group complexes
KW - Sn(II) square planar
N2 - The anion [N(SePPh2)(2)](-) forms stable complexes with cations M(II, III); [M(II) = Sn, Se, Cd, Hg; M(III) = In, Sb, Bi], they exhibit a large diversity of structural arrangements around the metal centre. Tin(II) complex crystallizes dimorphically, as square planar and distorted tetragonal pyramidal, Pb(II) is also distorted tetragonal pyramidal, Cd(II) and Hg(II) are tetrahedral, but the Se(II) is square planar. The coordination geometry in the M(III) complexes can be described as a distorted octahedron. The structural situation around the Sb(III) and Bi(III) suggests a stereochemically non-active electron lone pair.
ER -
CEA OLIVERAS, R., V. GARCÍA MONTALVO, J. NOVOSAD, P. KILIÁN, JD WOOLLINS a AMZ SLAWIN. Structural Diversity of [M$\{$N(SePPh2)2/Se,Se'$\}$2,3] [M(II)=Sn, Pb, Cd, Hg, Se; M(III)=In, Sb, Bi]. \textit{Phosphorus, Sulfur Silicon Rel. Elem.}. 1997, roč.~1997, 124\&{}125, s.~347-354. ISSN~1042-6507.
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