New inorganic metallacycles and the first six-membered covalent

J 1999

New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry

BIRDSALL, David J.; Jason GREEN; Tuan Q. LY; Josef NOVOSAD; Marek NEČAS et al.

Základní údaje

Originální název

New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry

Autoři

BIRDSALL, David J.; Jason GREEN; Tuan Q. LY; Josef NOVOSAD; Marek NEČAS; A. M. Z. SLAWIN; J. D. WOOLLINS a Zdirad ŽÁK

Vydání

Eur. J. Inorg. Chem. Germany, Wiley-VCH Verlag GMBH, 1999, 1434-1948

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/99:00001176

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000083540900007

Klíčová slova anglicky

metallacycles; solid-state structures; heterocycles; oxidations

Štítky

heterocycles, metallacycles, oxidations, solid-state structures

Změněno: 25. 6. 2009 12:01, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

Direct oxidation of PhC(O)NHPPh2, H2NC(S)NHPPh2, (CSH4N)C(S)NHPPh2 with O-2, S-8, or Se gives [PhC(O)NHP(O)Ph-2] (1), [H2NC(S)NHP(S)Ph-2] (2), [H2NC(O)NHP(S)Ph-2] (3), [PhC(O)NHP(S)Ph-2] (4), [(C5H4N)C(S)NHP(S)Ph-2] (5), and [H2NC(S)NHP(Se)Ph-2] (6). Deprotonation of 1, 2, 4-6 with potassium tert-butoxide gives K[PhC(O)NP(O)Ph-2] (7), K[H2NC(S)NP(S)Ph-2] (8), K[PhC(O)NP(S)Ph-2] (9), K[(C5H4N)C(S)NP(S)Ph-2] (10), and K[H2NC(S)NP(Se)Ph-2] (11). Reaction of 4 with KOBu and [Cu(Ph3P)(2)][NO3] gives [Cu(Ph3P)(PhC(O)NP(S)Ph-2)] (12) which is the first crystallographically characterised example of a non-ionic six-membered "true" heterocycle (i.e. a ring in which every heterocatom is different). 9 and 10 were treated with [PdCl2(COD)] to give [Pd{PhC(O)NP(S)Ph-2}(2)] (13) and [Pd{(C5H4N)C(O)NP(S)Ph-2}(2)] (14), respectively The anion of 8 coordinates to zinc forming [Zn{H2NC(S)NP(S)Ph-2}(2)] (15). Treatment of 2 or 8 with [PtCl2(COD)] gives [Pt{H2NC(S)NP(S)Ph-2}{H2NC(S)NHP(S)Ph-2}]Cl-+(-) (16) and [Pt{H2NC(S)NP(S)Ph-2}(2)] (17), respectively. The X-ray structures of 12, 15-17 are reported.

Návaznosti

GA203/97/0955, projekt VaV

Název: Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

Investor: Grantová agentura ČR, Studium syntézy, struktury a vazebných poměrů ve sloučeninách obsahujících současně dusík, fosfor, chalkogen a/nebo halogen

GA203/98/0676, projekt VaV

Název: Krystalová struktura a vazebné poměry sloučenin nekovů V., VI. a VII. grupy periodického systému

Investor: Grantová agentura ČR, Krystalová struktura a vazebné poměry sloučenin nekovů V., VI. a VII. grupy periodického systému

GA203/99/0067, projekt VaV

Název: Pronájem krystalografických databází

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

BIRDSALL, David J.; Jason GREEN; Tuan Q. LY; Josef NOVOSAD; Marek NEČAS; A. M. Z. SLAWIN; J. D. WOOLLINS a Zdirad ŽÁK. New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry. Eur. J. Inorg. Chem. Germany: Wiley-VCH Verlag GMBH, 1999, roč. 1999, č. 9, s. 1445-1452. ISSN 1434-1948.

@article{212091,
   author = {Birdsall, David J. and Green, Jason and Ly, Tuan Q. and Novosad, Josef and Nečas, Marek and Slawin, A. M. Z. and Woollins, J. D. and Žák, Zdirad},
   article_location = {Germany},
   article_number = {9},
   keywords = {metallacycles; solid-state structures; heterocycles; oxidations},
   language = {eng},
   issn = {1434-1948},
   journal = {Eur. J. Inorg. Chem.},
   title = {New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry},
   volume = {1999},
   year = {1999}
}

TY  - JOUR
ID  - 212091
AU  - Birdsall, David J. - Green, Jason - Ly, Tuan Q. - Novosad, Josef - Nečas, Marek - Slawin, A. M. Z. - Woollins, J. D. - Žák, Zdirad
PY  - 1999
TI  - New inorganic metallacycles and the first six-membered covalent "true" heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry
JF  - Eur. J. Inorg. Chem.
VL  - 1999
IS  - 9
SP  - 1445
EP  - 1445
PB  - Wiley-VCH Verlag GMBH
SN  - 14341948
KW  - metallacycles
KW  - solid-state structures
KW  - heterocycles
KW  - oxidations
N2  - Direct oxidation of PhC(O)NHPPh2, H2NC(S)NHPPh2, (CSH4N)C(S)NHPPh2 with O-2, S-8, or Se gives [PhC(O)NHP(O)Ph-2] (1), [H2NC(S)NHP(S)Ph-2] (2), [H2NC(O)NHP(S)Ph-2] (3), [PhC(O)NHP(S)Ph-2] (4), [(C5H4N)C(S)NHP(S)Ph-2] (5), and [H2NC(S)NHP(Se)Ph-2] (6). Deprotonation of 1, 2, 4-6 with potassium tert-butoxide gives K[PhC(O)NP(O)Ph-2] (7), K[H2NC(S)NP(S)Ph-2] (8), K[PhC(O)NP(S)Ph-2] (9), K[(C5H4N)C(S)NP(S)Ph-2] (10), and K[H2NC(S)NP(Se)Ph-2] (11). Reaction of 4 with KOBu and [Cu(Ph3P)(2)][NO3] gives [Cu(Ph3P)(PhC(O)NP(S)Ph-2)] (12) which is the first crystallographically characterised example of a non-ionic six-membered "true" heterocycle (i.e. a ring in which every heterocatom is different). 9 and 10 were treated with [PdCl2(COD)] to give [Pd{PhC(O)NP(S)Ph-2}(2)] (13) and [Pd{(C5H4N)C(O)NP(S)Ph-2}(2)] (14), respectively The anion of 8 coordinates to zinc forming [Zn{H2NC(S)NP(S)Ph-2}(2)] (15). Treatment of 2 or 8 with [PtCl2(COD)] gives [Pt{H2NC(S)NP(S)Ph-2}{H2NC(S)NHP(S)Ph-2}]Cl-+(-) (16) and [Pt{H2NC(S)NP(S)Ph-2}(2)] (17), respectively. The X-ray structures of 12, 15-17 are reported.
ER  -

BIRDSALL, David J.; Jason GREEN; Tuan Q. LY; Josef NOVOSAD; Marek NEČAS; A. M. Z. SLAWIN; J. D. WOOLLINS a Zdirad ŽÁK. New inorganic metallacycles and the first six-membered covalent ''true'' heterocycle - Oxidation of RC(E)NHPPh2 (E = O or S; R = H2N, Ph, or Py) with O, S, or Se to give RC(E)NHP(E ')Ph-2 (E ' = O, S, Se) and their coordination chemistry. \textit{Eur. J. Inorg. Chem.}. Germany: Wiley-VCH Verlag GMBH, 1999, roč.~1999, č.~9, s.~1445-1452. ISSN~1434-1948.

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