Synthesis and Characterization of [Te2(-Cl)2{(SPPh2)2N}2],
[(4-MeOC6H4TeCl3)2 {-Ph2P(S)CH2CH2P(S)Ph2}] and Te2(-S2PPh2)2
Representing Novel Types of Tellurium Complexes.

J 1999

Synthesis and Characterization of [Te2(-Cl)2{(SPPh2)2N}2], [(4-MeOC6H4TeCl3)2 {-Ph2P(S)CH2CH2P(S)Ph2}] and Te2(-S2PPh2)2 Representing Novel Types of Tellurium Complexes.

NOVOSAD, Josef; K. W. TORNROOS; Marek NEČAS; A. M. Z. SLAWIN; J. D. WOOLLINS et. al.

Základní údaje

Originální název

Synthesis and Characterization of [Te2(-Cl)2{(SPPh2)2N}2], [(4-MeOC6H4TeCl3)2 {-Ph2P(S)CH2CH2P(S)Ph2}] and Te2(-S2PPh2)2 Representing Novel Types of Tellurium Complexes.

Autoři

NOVOSAD, Josef (203 Česká republika, garant); K. W. TORNROOS; Marek NEČAS (203 Česká republika); A. M. Z. SLAWIN; J. D. WOOLLINS a S. HUSEBYE

Vydání

Polyhedron, Velká Británie, Pergamon-Elsevier Science LTD, 1999, 0277-5387

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10402 Inorganic and nuclear chemistry

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Impakt faktor

Impact factor: 1.116

Kód RIV

RIV/00216224:14310/99:00001177

Organizační jednotka

Přírodovědecká fakulta

UT WoS

000083330100006

Klíčová slova anglicky

tellurium complexes; basicity and trans influence of ligands

Štítky

tellurium complexes

Změněno: 25. 6. 2009 12:03, doc. Mgr. Marek Nečas, Ph.D.

Anotace

V originále

The three title compounds have been synthesized and their structures determined by X-ray crystallography. [Te-2(mu-Cl)(2){(SPPh2)(2)N}(2)], 1, is a dinuclear square planar Te(II) complex where each Te atom is coordinated to the two sulfur atoms of the bidentate dithiolate ligand and to the two bridging chloride ligands. The Te-S bond lengths are 2.4980(8) and 2.5054(8) Angstrom, while the Te-Cl bond lengths are 2.9065(9) and 2.9230(9) Angstrom. In [(4-MeOC6H4TeCl3)(2){mu-Ph2P(S)CH2CH2P(S)Ph-2}], 2, the dithio ligand is neutral and adds a molecule of [4-MeOC6H4TeCl3] at each sulfur atom, thus bridging the two Te(IV) atoms. The coordination of both tellurium atoms is psi-octahedral with the anisyl group and a lone pair of electrons in axial positions. The Te-S bonds, 2.7747(6) and 2.8198(5) Angstrom, are surprisingly weak while the Te-Cl bonds lie in the range 2.4247(5) to 2.5343(6) Angstrom, those trans to Te-S being shortest. [Te-2(mu-Ph2PS2)(2)], 3, is a binuclear Te(I) complex, mainly held together by a Te-Te bond of 2.7298(5) Angstrom. Both anisobidentate diphenyldithiophosphinate ligands bridge the two tellurium atoms. The resulting coordination around each tellurium is best described as T-shaped with the Te-Te bond along the stem. In the asymmetric near linear S-Te-S system, the short Te-S bonds are 2.487(2) and 2.495(2) Angstrom while the long bonds are 2.947(2) and 3.033(2) Angstrom, respectively. The strongly different trans influences of the dithio ligands of 1 and 2 are discussed and it is suggested that they are dependent upon the basicity of the sulfur atoms.

Návaznosti

MSM 143100011, záměr

Název: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Citovat

NOVOSAD, Josef; K. W. TORNROOS; Marek NEČAS; A. M. Z. SLAWIN; J. D. WOOLLINS a S. HUSEBYE. Synthesis and Characterization of [Te2(-Cl)2{(SPPh2)2N}2], [(4-MeOC6H4TeCl3)2 {-Ph2P(S)CH2CH2P(S)Ph2}] and Te2(-S2PPh2)2 Representing Novel Types of Tellurium Complexes. Polyhedron. Velká Británie: Pergamon-Elsevier Science LTD, 1999, roč. 18, č. 22, s. 2861-2865. ISSN 0277-5387.

@article{212151,
   author = {Novosad, Josef and Tornroos, K. W. and Nečas, Marek and Slawin, A. M. Z. and Woollins, J. D. and Husebye, S.},
   article_location = {Velká Británie},
   article_number = {22},
   keywords = {tellurium complexes; basicity and trans influence of ligands},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {Synthesis and Characterization of [Te2(-Cl)2{(SPPh2)2N}2], [(4-MeOC6H4TeCl3)2 {-Ph2P(S)CH2CH2P(S)Ph2}] and Te2(-S2PPh2)2 Representing Novel Types of Tellurium Complexes.},
   volume = {18},
   year = {1999}
}

TY  - JOUR
ID  - 212151
AU  - Novosad, Josef - Tornroos, K. W. - Nečas, Marek - Slawin, A. M. Z. - Woollins, J. D. - Husebye, S.
PY  - 1999
TI  - Synthesis and Characterization of [Te2(-Cl)2{(SPPh2)2N}2], [(4-MeOC6H4TeCl3)2 {-Ph2P(S)CH2CH2P(S)Ph2}] and Te2(-S2PPh2)2 Representing Novel Types of Tellurium Complexes.
JF  - Polyhedron
VL  - 18
IS  - 22
SP  - 2861
EP  - 2861
PB  - Pergamon-Elsevier Science LTD
SN  - 02775387
KW  - tellurium complexes
KW  - basicity and trans influence of ligands
N2  - The three title compounds have been synthesized and their structures determined by X-ray crystallography. [Te-2(mu-Cl)(2){(SPPh2)(2)N}(2)], 1, is a dinuclear square planar Te(II) complex where each Te atom is coordinated to the two sulfur atoms of the bidentate dithiolate ligand and to the two bridging chloride ligands. The Te-S bond lengths are 2.4980(8) and 2.5054(8) Angstrom, while the Te-Cl bond lengths are 2.9065(9) and 2.9230(9) Angstrom. In [(4-MeOC6H4TeCl3)(2){mu-Ph2P(S)CH2CH2P(S)Ph-2}], 2, the dithio ligand is neutral and adds a molecule of [4-MeOC6H4TeCl3] at each sulfur atom, thus bridging the two Te(IV) atoms. The coordination of both tellurium atoms is psi-octahedral with the anisyl group and a lone pair of electrons in axial positions. The Te-S bonds, 2.7747(6) and 2.8198(5) Angstrom, are surprisingly weak while the Te-Cl bonds lie in the range 2.4247(5) to 2.5343(6) Angstrom, those trans to Te-S being shortest. [Te-2(mu-Ph2PS2)(2)], 3, is a binuclear Te(I) complex, mainly held together by a Te-Te bond of 2.7298(5) Angstrom. Both anisobidentate diphenyldithiophosphinate ligands bridge the two tellurium atoms. The resulting coordination around each tellurium is best described as T-shaped with the Te-Te bond along the stem. In the asymmetric near linear S-Te-S system, the short Te-S bonds are 2.487(2) and 2.495(2) Angstrom while the long bonds are 2.947(2) and 3.033(2) Angstrom, respectively. The strongly different trans influences of the dithio ligands of 1 and 2 are discussed and it is suggested that they are dependent upon the basicity of the sulfur atoms.
ER  -

NOVOSAD, Josef; K. W. TORNROOS; Marek NEČAS; A. M. Z. SLAWIN; J. D. WOOLLINS a S. HUSEBYE. Synthesis and Characterization of [Te2(-Cl)2$\{$(SPPh2)2N$\}$2], [(4-MeOC6H4TeCl3)2 $\{$-Ph2P(S)CH2CH2P(S)Ph2$\}$] and Te2(-S2PPh2)2 Representing Novel Types of Tellurium Complexes. \textit{Polyhedron}. Velká Británie: Pergamon-Elsevier Science LTD, 1999, roč.~18, č.~22, s.~2861-2865. ISSN~0277-5387.

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