Synthesis and characterization of the ceramic refractory metal
high entropy nitride thin films from Cr-Hf-Mo-Ta-W system

J 2022

Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system

STASIAK, Tomasz; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Nikola KOUTNÁ; Zsolt CZIGÁNY et al.

Základní údaje

Originální název

Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system

Autoři

STASIAK, Tomasz; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Nikola KOUTNÁ; Zsolt CZIGÁNY; Katalin BALÁZSI a Petr VAŠINA

Vydání

Surface and Coatings Technology, Elsevier, 2022, 0257-8972

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Švýcarsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.400

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/22:00127020

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

High entropy alloy; High entropy nitride; Multicomponent material; Magnetron sputtering; Microstructural characterization; Ab-initio calculation

Štítky

14312030, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 27. 2. 2024 13:23, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

High entropy alloy and nitride coatings from the Cr-Hf-Mo-Ta-W system were deposited by reactive magnetron sputtering from elemental segmented targets. The study aimed to investigate the effects of deposition parameters on the microstructure and mechanical properties of this novel multicomponent material. Samples without nitrogen flow and under different nitrogen flows were prepared in two series of samples prepared at ambient temperature and at 750 °C. The proportion of metallic elements varied with increasing nitrogen flow. The nitrogen content revealed saturation below 50 % under high flow. The thin films showed a different microstructure depending on the deposition conditions, from a single nanocrystalline bcc phase (a = 3.174 Å) in the metallic sample prepared at 750 °C without nitrogen flow, through an amorphous structure under low nitrogen flow to a major nanocrystalline NaCl-type fcc nitride phase (a = 4.186–4.268 Å, in agreement with the ab-initio predicted values) in samples deposited under high nitrogen flow. The cross-section morphology of the amorphous sample was very homogeneous, while the samples with a major fcc nitride phase showed a typical columnar morphology. Overall, the films revealed hardness and Young's modulus up to 20.3 GPa and 471 GPa, respectively, for the fcc nitride coating. The experimental values of Young's modulus were in good agreement with the values of directional [100] Young's modulus obtained by ab-initio calculations. The results of our research showed that coatings consisting of bcc and fcc phases could be produced by magnetron sputtering with interesting mechanical properties such as high Young's modulus. Moreover, the results contribute to the understanding of the influence of the nitrogen flow on the microstructural features such as crystallite size, vacancies in the lattice, and lattice parameter change.

Návaznosti

90097, velká výzkumná infrastruktura

Název: CEPLANT

Citovat

STASIAK, Tomasz; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Nikola KOUTNÁ; Zsolt CZIGÁNY; Katalin BALÁZSI a Petr VAŠINA. Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system. Surface and Coatings Technology. Elsevier, 2022, roč. 449, November, s. 1-13. ISSN 0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2022.128987.

@article{2227326,
   author = {Stasiak, Tomasz and Souček, Pavel and Buršíková, Vilma and Koutná, Nikola and Czigány, Zsolt and Balázsi, Katalin and Vašina, Petr},
   article_number = {November},
   doi = {https://doi.org/10.1016/j.surfcoat.2022.128987},
   keywords = {High entropy alloy; High entropy nitride; Multicomponent material; Magnetron sputtering; Microstructural characterization; Ab-initio calculation},
   language = {eng},
   issn = {0257-8972},
   journal = {Surface and Coatings Technology},
   title = {Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system},
   url = {https://www.sciencedirect.com/science/article/pii/S0257897222009082?dgcid=coauthor#!},
   volume = {449},
   year = {2022}
}

TY  - JOUR
ID  - 2227326
AU  - Stasiak, Tomasz - Souček, Pavel - Buršíková, Vilma - Koutná, Nikola - Czigány, Zsolt - Balázsi, Katalin - Vašina, Petr
PY  - 2022
TI  - Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system
JF  - Surface and Coatings Technology
VL  - 449
IS  - November
SP  - 1-13
EP  - 1-13
PB  - Elsevier
SN  - 02578972
KW  - High entropy alloy
KW  - High entropy nitride
KW  - Multicomponent material
KW  - Magnetron sputtering
KW  - Microstructural characterization
KW  - Ab-initio calculation
UR  - https://www.sciencedirect.com/science/article/pii/S0257897222009082?dgcid=coauthor#!
N2  - High entropy alloy and nitride coatings from the Cr-Hf-Mo-Ta-W system were deposited by reactive magnetron sputtering from elemental segmented targets. The study aimed to investigate the effects of deposition parameters on the microstructure and mechanical properties of this novel multicomponent material. Samples without nitrogen flow and under different nitrogen flows were prepared in two series of samples prepared at ambient temperature and at 750 °C. The proportion of metallic elements varied with increasing nitrogen flow. The nitrogen content revealed saturation below 50 % under high flow. The thin films showed a different microstructure depending on the deposition conditions, from a single nanocrystalline bcc phase (a = 3.174 Å) in the metallic sample prepared at 750 °C without nitrogen flow, through an amorphous structure under low nitrogen flow to a major nanocrystalline NaCl-type fcc nitride phase (a = 4.186–4.268 Å, in agreement with the ab-initio predicted values) in samples deposited under high nitrogen flow. The cross-section morphology of the amorphous sample was very homogeneous, while the samples with a major fcc nitride phase showed a typical columnar morphology. Overall, the films revealed hardness and Young's modulus up to 20.3 GPa and 471 GPa, respectively, for the fcc nitride coating. The experimental values of Young's modulus were in good agreement with the values of directional [100] Young's modulus obtained by ab-initio calculations. The results of our research showed that coatings consisting of bcc and fcc phases could be produced by magnetron sputtering with interesting mechanical properties such as high Young's modulus. Moreover, the results contribute to the understanding of the influence of the nitrogen flow on the microstructural features such as crystallite size, vacancies in the lattice, and lattice parameter change.
ER  -

STASIAK, Tomasz; Pavel SOUČEK; Vilma BURŠÍKOVÁ; Nikola KOUTNÁ; Zsolt CZIGÁNY; Katalin BALÁZSI a Petr VAŠINA. Synthesis and characterization of the ceramic refractory metal high entropy nitride thin films from Cr-Hf-Mo-Ta-W system. \textit{Surface and Coatings Technology}. Elsevier, 2022, roč.~449, November, s.~1-13. ISSN~0257-8972. Dostupné z: https://doi.org/10.1016/j.surfcoat.2022.128987.

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