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@article{2246571,
author = {Rando, Carola and Vazquez Gonzalvez, Julian and Sokolov, Jan and Kokan, Zoran and Nečas, Marek and Šindelář, Vladimír},
article_location = {WEINHEIM (GERMANY)},
article_number = {43},
doi = {http://dx.doi.org/10.1002/anie.202210184},
keywords = {Anion Binding; Bambusurils; Dicyanoaurate; Gold Extraction; Host-Guest Complexes},
language = {eng},
issn = {1433-7851},
journal = {Angewandte Chemie International Edition},
title = {Highly Efficient and Selective Recognition of Dicyanoaurate(I) by a Bambusuril Macrocycle in Water},
url = {https://onlinelibrary.wiley.com/doi/10.1002/anie.202210184},
volume = {61},
year = {2022}
}
TY - JOUR
ID - 2246571
AU - Rando, Carola - Vazquez Gonzalvez, Julian - Sokolov, Jan - Kokan, Zoran - Nečas, Marek - Šindelář, Vladimír
PY - 2022
TI - Highly Efficient and Selective Recognition of Dicyanoaurate(I) by a Bambusuril Macrocycle in Water
JF - Angewandte Chemie International Edition
VL - 61
IS - 43
SP - 1-5
EP - 1-5
PB - Verlag Chemie
SN - 14337851
KW - Anion Binding
KW - Bambusurils
KW - Dicyanoaurate
KW - Gold Extraction
KW - Host-Guest Complexes
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.202210184
N2 - Dicyanoaurate(I) anion, [Au(CN)(2)](-), plays a central role in the current industrial production of gold, as its extraction from crude ore samples represents the most money-consuming step. Herein, we present the strongest host-guest recognition of dicyanoaurate anion using the bambusuril receptor in water, a highly competitive solvent. The micromolar stability of such a complex facilitated the up to date most efficient supramolecular stripping of dicyanoaurate from activated carbon at ambient temperature. Thermodynamic characteristics of bambusuril binding with [Au(CN)(2)](-) differing from binding of other inorganic chaotropic anions are rationalized, as well as the bambusuril selectivity for [Au(CN)(2)](-) over [Ag(CN)(2)](-).
ER -
RANDO, Carola, Julian VAZQUEZ GONZALVEZ, Jan SOKOLOV, Zoran KOKAN, Marek NEČAS a Vladimír ŠINDELÁŘ. Highly Efficient and Selective Recognition of Dicyanoaurate(I) by a Bambusuril Macrocycle in Water. \textit{Angewandte Chemie International Edition}. WEINHEIM (GERMANY): Verlag Chemie, 2022, roč.~61, č.~43, s.~1-5. ISSN~1433-7851. Dostupné z: https://dx.doi.org/10.1002/anie.202210184.
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