Material aspects in laser-induced breakdown  spectroscopy
analysis of algae on filters

a 2023

Material aspects in laser-induced breakdown spectroscopy analysis of algae on filters

HRDLIČKA, Aleš; Jana HORSKÁ; Jitka HEGROVÁ; David PROCHÁZKA; Jakub BUDAY et. al.

Základní údaje

Originální název

Material aspects in laser-induced breakdown spectroscopy analysis of algae on filters

Autoři

HRDLIČKA, Aleš (203 Česká republika, domácí); Jana HORSKÁ (203 Česká republika, domácí); Jitka HEGROVÁ (203 Česká republika); David PROCHÁZKA (203 Česká republika); Jakub BUDAY (703 Slovensko); Pavel POŘÍZKA (203 Česká republika); Jozef KAISER (203 Česká republika); Karel NOVOTNÝ (203 Česká republika, domácí) a Viktor KANICKÝ (203 Česká republika, domácí)

Vydání

12th Euro-Mediterranean Symposium on Laser-induced Breakdown Spectroscopy, 2023

Další údaje

Jazyk

angličtina

Typ výsledku

Konferenční abstrakt

Obor

10406 Analytical chemistry

Stát vydavatele

Česká republika

Utajení

není předmětem státního či obchodního tajemství

Odkazy

odkaz na konferenční stránky

Kód RIV

RIV/00216224:14310/23:00131711

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova česky

spektroskopie laserem buzeného plazmatu (LIBS); analýza; řasy; kontaminace; stínové zobrazení

Klíčová slova anglicky

laser-induced breakdown spectroscopy; analysis; algae; contamination; shadowgraphy

Příznaky

Mezinárodní význam

Změněno: 20. 9. 2023 15:14, Mgr. Aleš Hrdlička, Ph.D.

Anotace

V originále

Determination of heavy metals in algae is an important environmental issue. The typical employed instrumentation is Inductively Coupled Plasma Mass Spectrometry (ICP-MS) [1]. However, the algae must be filtered from a parent solution and the filter is consequently decomposed and analysed. On the other hand, Laser-induced Breakdown Spectroscopy (LIBS) can directly analyse dried and/or pelletized algae [2] or just ablate an algae sediment on the filter [3]. Quantitative analysis of the algae on the filter is, beside others, complicated by different intensities of spectra depending on the deposit and the hardness of the filter underlay. The whole filter area is fixed to a microscopic glass with a double adhesive tape. The fixation must be done very precisely. The emission signal will decrease and the filter is perforated if it does not touch the glass properly. Also the concentration of the contaminants in the solution influences the total plasma emission. The character of the system filter-tape-glass is investigated in dependence on the sticking layers and filtered solution. It is shown how the total spectral emission, plasma parameters and lines intensities change (e.g. ionic-to-atomic line ration decrease) in dependence on the hardness of the sticking. The observed intensities changes are supported with shadowgraphic studies of shockwaves and crater depths at 1064 nm LIBS. The shockwave is slightly decreased on a softer or more impregnated filter system. It can be concluded that a lower contamination, low number of dead algae cells and a thin tape on a hard glass base provide higher emission signals but blank filter emission is lower on a sufficiently hard base. An appropriate combination of the total emissivity, lines ratios and shadowgraphy can then be used for internal standardization. The correction for the aforementioned effects can improve the trueness of the quantification.

Návaznosti

MUNI/A/1298/2022, interní kód MU

Název: Základní a aplikovaný výzkum a vývoj metod chemické a fyzikálně chemické analýzy pro studium přírody a pokročilé technologie

Investor: Masarykova univerzita, Základní a aplikovaný výzkum a vývoj metod chemické a fyzikálně chemické analýzy pro studium přírody a pokročilé technologie

Citovat

HRDLIČKA, Aleš; Jana HORSKÁ; Jitka HEGROVÁ; David PROCHÁZKA; Jakub BUDAY; Pavel POŘÍZKA; Jozef KAISER; Karel NOVOTNÝ a Viktor KANICKÝ. Material aspects in laser-induced breakdown spectroscopy analysis of algae on filters. In 12th Euro-Mediterranean Symposium on Laser-induced Breakdown Spectroscopy. 2023.

@proceedings{2312038,
   author = {Hrdlička, Aleš and Horská, Jana and Hegrová, Jitka and Procházka, David and Buday, Jakub and Pořízka, Pavel and Kaiser, Jozef and Novotný, Karel and Kanický, Viktor},
   booktitle = {12th Euro-Mediterranean Symposium on Laser-induced Breakdown Spectroscopy},
   keywords = {laser-induced breakdown spectroscopy; analysis; algae; contamination; shadowgraphy},
   language = {eng},
   title = {Material aspects in laser-induced breakdown spectroscopy analysis of algae on filters},
   url = {https://emslibs2023.inesctec.pt/},
   year = {2023}
}

TY  - CONF
ID  - 2312038
AU  - Hrdlička, Aleš - Horská, Jana - Hegrová, Jitka - Procházka, David - Buday, Jakub - Pořízka, Pavel - Kaiser, Jozef - Novotný, Karel - Kanický, Viktor
PY  - 2023
TI  - Material aspects in laser-induced breakdown spectroscopy analysis of algae on filters
KW  - laser-induced breakdown spectroscopy
KW  - analysis
KW  - algae
KW  - contamination
KW  - shadowgraphy
UR  - https://emslibs2023.inesctec.pt/
N2  - Determination of heavy metals in algae is an important environmental issue. The typical employed instrumentation is Inductively Coupled Plasma Mass Spectrometry (ICP-MS) [1]. However, the algae must be filtered from a parent solution and the filter is consequently decomposed and analysed. On the other hand, Laser-induced Breakdown Spectroscopy (LIBS) can directly analyse dried and/or pelletized algae [2] or just ablate an algae sediment on the filter [3]. Quantitative analysis of the algae on the filter is, beside others, complicated by different intensities of spectra depending on the deposit and the hardness of the filter underlay. The whole filter area is fixed to a microscopic glass with a double adhesive tape. The fixation must be done very precisely. The emission signal will decrease and the filter is perforated if it does not touch the glass properly. Also the concentration of the contaminants in the solution influences the total plasma emission. The character of the system filter-tape-glass is investigated in dependence on the sticking layers and filtered solution. It is shown how the total spectral emission, plasma parameters and lines intensities change (e.g. ionic-to-atomic line ration decrease) in dependence on the hardness of the sticking. The observed intensities changes are supported with shadowgraphic studies of shockwaves and crater depths at 1064 nm LIBS. The shockwave is slightly decreased on a softer or more impregnated filter system. It can be concluded that a lower contamination, low number of dead algae cells and a thin tape on a hard glass base provide higher emission signals but blank filter emission is lower on a sufficiently hard base. An appropriate combination of the total emissivity, lines ratios and shadowgraphy can then be used for internal standardization. The correction for the aforementioned effects can improve the trueness of the quantification.
ER  -

HRDLIČKA, Aleš; Jana HORSKÁ; Jitka HEGROVÁ; David PROCHÁZKA; Jakub BUDAY; Pavel POŘÍZKA; Jozef KAISER; Karel NOVOTNÝ a Viktor KANICKÝ. Material aspects in laser-induced breakdown spectroscopy analysis of algae on filters. In \textit{12th Euro-Mediterranean Symposium on Laser-induced Breakdown Spectroscopy}. 2023.

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