WS2 fullerene/plate nanofibers: The tunable crossroad between
dimensionalities

J 2024

WS2 fullerene/plate nanofibers: The tunable crossroad between dimensionalities

KUNDRÁT, Vojtěch, Zdeněk KRÁL, Iddo PINKAS, Jiří PINKAS, Lena YADGAROV et. al.

Základní údaje

Originální název

WS2 fullerene/plate nanofibers: The tunable crossroad between dimensionalities

Autoři

KUNDRÁT, Vojtěch (203 Česká republika, domácí), Zdeněk KRÁL (203 Česká republika, domácí), Iddo PINKAS, Jiří PINKAS (203 Česká republika, domácí) a Lena YADGAROV

Vydání

Ceramics International, Elsevier, 2024, 0272-8842

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Velká Británie a Severní Irsko

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 5.200 v roce 2022

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.ceramint.2023.11.345

UT WoS

001170762400001

Klíčová slova anglicky

Electrospinning; Exciton-polaritons; Fullerenes; Nanofibers; Tungsten disulfide

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 22. 3. 2024 10:48, Mgr. Pavla Foltynová, Ph.D.

Anotace

V originále

Our work describes the nanofibrous materials of tungsten disulfide, which can be tuned by the precursor's crystallinity degree. The carefully formulated nanofibers create the morphological crossroad between fullerenes (0D), nanotubes (1D), plates (2D), and a nonwoven web of nanofibers (3D), containing all the advantageous properties of the presented material categories. Our synthetic methodology (electrospinning, reductive sulfidation) allows scale-up to industrial production. In addition, we studied the optical properties of the WS2 nanofibers using extinction and absolute absorption measurements. The results of the optical analysis further indicate the higher crystallinity of the closed stacked fullerene-based structure. By comparing the extinction with the absorbance, we find that all the examined nanostructures display typical polaritonic spectra. However, the open plate structure exhibits a stronger scattering and thus better pronounced polaritonic features. Moreover, the ability to control the morphology allows for variating polaritonic features of the final nanofibrous material, which can directly impact the potential optoelectronic and photocatalytic applications.

Návaznosti

EH22_008/0004572, projekt VaV

Název: Kvantové materiály pro aplikace v udržitelných technologiích

LM2018127, projekt VaV

Název: Česká infrastruktura pro integrativní strukturní biologii (Akronym: CIISB)

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, Czech Infrastructure for Integrative Structural Biology

90110, velká výzkumná infrastruktura

Název: CzechNanoLab

Citovat

KUNDRÁT, Vojtěch, Zdeněk KRÁL, Iddo PINKAS, Jiří PINKAS a Lena YADGAROV. WS2 fullerene/plate nanofibers: The tunable crossroad between dimensionalities. Ceramics International. Elsevier, 2024, roč. 50, č. 5, s. 7314-7322. ISSN 0272-8842. Dostupné z: https://dx.doi.org/10.1016/j.ceramint.2023.11.345.

@article{2371477,
   author = {Kundrát, Vojtěch and Král, Zdeněk and Pinkas, Iddo and Pinkas, Jiří and Yadgarov, Lena},
   article_number = {5},
   doi = {http://dx.doi.org/10.1016/j.ceramint.2023.11.345},
   keywords = {Electrospinning; Exciton-polaritons; Fullerenes; Nanofibers; Tungsten disulfide},
   language = {eng},
   issn = {0272-8842},
   journal = {Ceramics International},
   title = {WS2 fullerene/plate nanofibers: The tunable crossroad between dimensionalities},
   url = {https://www.sciencedirect.com/science/article/pii/S0272884223038300},
   volume = {50},
   year = {2024}
}

TY  - JOUR
ID  - 2371477
AU  - Kundrát, Vojtěch - Král, Zdeněk - Pinkas, Iddo - Pinkas, Jiří - Yadgarov, Lena
PY  - 2024
TI  - WS2 fullerene/plate nanofibers: The tunable crossroad between dimensionalities
JF  - Ceramics International
VL  - 50
IS  - 5
SP  - 7314-7322
EP  - 7314-7322
PB  - Elsevier
SN  - 02728842
KW  - Electrospinning
KW  - Exciton-polaritons
KW  - Fullerenes
KW  - Nanofibers
KW  - Tungsten disulfide
UR  - https://www.sciencedirect.com/science/article/pii/S0272884223038300
N2  - Our work describes the nanofibrous materials of tungsten disulfide, which can be tuned by the precursor's crystallinity degree. The carefully formulated nanofibers create the morphological crossroad between fullerenes (0D), nanotubes (1D), plates (2D), and a nonwoven web of nanofibers (3D), containing all the advantageous properties of the presented material categories. Our synthetic methodology (electrospinning, reductive sulfidation) allows scale-up to industrial production. In addition, we studied the optical properties of the WS2 nanofibers using extinction and absolute absorption measurements. The results of the optical analysis further indicate the higher crystallinity of the closed stacked fullerene-based structure. By comparing the extinction with the absorbance, we find that all the examined nanostructures display typical polaritonic spectra. However, the open plate structure exhibits a stronger scattering and thus better pronounced polaritonic features. Moreover, the ability to control the morphology allows for variating polaritonic features of the final nanofibrous material, which can directly impact the potential optoelectronic and photocatalytic applications.
ER  -

KUNDRÁT, Vojtěch, Zdeněk KRÁL, Iddo PINKAS, Jiří PINKAS a Lena YADGAROV. WS2 fullerene/plate nanofibers: The tunable crossroad between dimensionalities. \textit{Ceramics International}. Elsevier, 2024, roč.~50, č.~5, s.~7314-7322. ISSN~0272-8842. Dostupné z: https://dx.doi.org/10.1016/j.ceramint.2023.11.345.

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