J 2024

UiO-66-based metal-organic frameworks for CO2 catalytic conversion, adsorption and separation

ADEGOKE, Kayode A., Kovo G. AKPOMIE, Emmanuel S. OKEKE, Chijioke OLISAH, Alhadji MALLOUM et. al.

Basic information

Original name

UiO-66-based metal-organic frameworks for CO2 catalytic conversion, adsorption and separation

Authors

ADEGOKE, Kayode A., Kovo G. AKPOMIE, Emmanuel S. OKEKE, Chijioke OLISAH (566 Nigeria, guarantor, belonging to the institution), Alhadji MALLOUM, Nobanathi W. MAXAKATO, Joshua O. IGHALO, Jeanet CONRADIE, Chinemerem R. OHORO, James F. AMAKU and Kabir O. OYEDOTUN

Edition

SEPARATION AND PURIFICATION TECHNOLOGY, AMSTERDAM, ELSEVIER SCIENCE BV, 2024, 1383-5866

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

20400 2.4 Chemical engineering

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 8.600 in 2022

Organization unit

Faculty of Science

DOI

UT WoS

001113054100001

Keywords in English

Carbon dioxide; Adsorption; Separation; Fuels/chemicals; UiO-66 metal -organic frameworks

Tags

Tags

International impact, Reviewed
Změněno: 22/3/2024 10:14, Mgr. Michaela Hylsová, Ph.D.

Abstract

V originále

UiO-66 (UiO denotes the Oslo University where it was first reported) is an archetypical Zr-based metal-organic framework with numerous exceptional attributes, including larger surface area, well-ordered porous structures, stability, and flexible tailorability. It has found extensive applications in carbon dioxide (CO2) adsorption and separation and CO2 conversion to value-added chemicals/fuels. This study presents a detailed combined application of UiO-66 for CO2 utilization covering adsorption, separation, and conversion to important chemical products. Prior to these, various aspects, including structural integrity, design and defect engineering of UiO-66 materials, and challenges associated with structural and morphology controls, were discussed. The study further discussed the corresponding performance of UiO-66 as adsorbents for CO2 uptakes, as membranes for CO2 separation, and as catalyst and photocatalysts for CO2 conversion to various alcohol and hydrocarbons, light olefins, and oxygenates, thereby suggesting the current research advancements in the implementation of UiO-66 materials for these applications. This was followed by the insight into integrated approaches for CO2 separation/ adsorption onto UiO-66 materials. Finally, this study identifies the associated weaknesses and strengths and treatment strategies, challenges/knowledge gaps to enable fostering and exploring new dimensions and directing specific research for large/industrial-scale applications.