Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes

J 2024

Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes

KUNDRÁT, Vojtěch; Hagai COHEN; Anna KOSSOY; Walter BONANI; Lothar HOUBEN et al.

Základní údaje

Originální název

Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes

Autoři

KUNDRÁT, Vojtěch; Hagai COHEN; Anna KOSSOY; Walter BONANI; Lothar HOUBEN; Jakub ZALESAK; Bing WU; Zdenek SOFER; Karin POPA a Reshef TENNE

Vydání

Small, Wiley-VCH GmbH, 2024, 1613-6810

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10400 1.4 Chemical sciences

Stát vydavatele

Německo

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 12.100

Označené pro přenos do RIV

Ano

Kód RIV

RIV/00216224:14310/24:00135714

Organizační jednotka

Přírodovědecká fakulta

Klíčová slova anglicky

entrapment; nanocapillary effect; uranium oxide; uranyl nitrate hydrate; WS2 nanotubes

Štítky

14313010, rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 24. 1. 2025 13:01, Mgr. Marie Novosadová Šípková, DiS.

Anotace

V originále

Uranium is a high-value energy element, yet also poses an appreciable environmental burden. The demand for a straightforward, low energy, and environmentally friendly method for encapsulating uranium species can be beneficial for long-term storage of spent uranium fuel and a host of other applications. Leveraging on the low melting point (60 degrees C) of uranyl nitrate hexahydrate and nanocapillary effect, a uranium compound is entrapped in the hollow core of WS2 nanotubes. Followingly, the product is reduced at elevated temperatures in a hydrogen atmosphere. Nanocrystalline UO2 nanoparticles anchor within the WS2 nanotube lumen are obtained through this procedure. Such methodology can find utilization in the processing of spent nuclear fuel or other highly active radionuclides as well as a fuel for deep space missions. Moreover, the low melting temperatures of different heavy metal-nitrate hydrates, pave the way for their encapsulation within the hollow core of the WS2 nanotubes, as demonstrated herein.

Citovat

KUNDRÁT, Vojtěch; Hagai COHEN; Anna KOSSOY; Walter BONANI; Lothar HOUBEN; Jakub ZALESAK; Bing WU; Zdenek SOFER; Karin POPA a Reshef TENNE. Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes. Small. Wiley-VCH GmbH, 2024, roč. 20, č. 14, s. 1-9. ISSN 1613-6810. Dostupné z: https://doi.org/10.1002/smll.202307684.

@article{2386805,
   author = {Kundrát, Vojtěch and Cohen, Hagai and Kossoy, Anna and Bonani, Walter and Houben, Lothar and Zalesak, Jakub and Wu, Bing and Sofer, Zdenek and Popa, Karin and Tenne, Reshef},
   article_number = {14},
   doi = {https://doi.org/10.1002/smll.202307684},
   keywords = {entrapment; nanocapillary effect; uranium oxide; uranyl nitrate hydrate; WS2 nanotubes},
   language = {eng},
   issn = {1613-6810},
   journal = {Small},
   title = {Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes},
   url = {https://onlinelibrary.wiley.com/doi/10.1002/smll.202307684},
   volume = {20},
   year = {2024}
}

TY  - JOUR
ID  - 2386805
AU  - Kundrát, Vojtěch - Cohen, Hagai - Kossoy, Anna - Bonani, Walter - Houben, Lothar - Zalesak, Jakub - Wu, Bing - Sofer, Zdenek - Popa, Karin - Tenne, Reshef
PY  - 2024
TI  - Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes
JF  - Small
VL  - 20
IS  - 14
SP  - 1-9
EP  - 1-9
PB  - Wiley-VCH GmbH
SN  - 16136810
KW  - entrapment
KW  - nanocapillary effect
KW  - uranium oxide
KW  - uranyl nitrate hydrate
KW  - WS2 nanotubes
UR  - https://onlinelibrary.wiley.com/doi/10.1002/smll.202307684
N2  - Uranium is a high-value energy element, yet also poses an appreciable environmental burden. The demand for a straightforward, low energy, and environmentally friendly method for encapsulating uranium species can be beneficial for long-term storage of spent uranium fuel and a host of other applications. Leveraging on the low melting point (60 degrees C) of uranyl nitrate hexahydrate and nanocapillary effect, a uranium compound is entrapped in the hollow core of WS2 nanotubes. Followingly, the product is reduced at elevated temperatures in a hydrogen atmosphere. Nanocrystalline UO2 nanoparticles anchor within the WS2 nanotube lumen are obtained through this procedure. Such methodology can find utilization in the processing of spent nuclear fuel or other highly active radionuclides as well as a fuel for deep space missions. Moreover, the low melting temperatures of different heavy metal-nitrate hydrates, pave the way for their encapsulation within the hollow core of the WS2 nanotubes, as demonstrated herein.
ER  -

KUNDRÁT, Vojtěch; Hagai COHEN; Anna KOSSOY; Walter BONANI; Lothar HOUBEN; Jakub ZALESAK; Bing WU; Zdenek SOFER; Karin POPA a Reshef TENNE. Encapsulation of Uranium Oxide in Multiwall WS2 Nanotubes. \textit{Small}. Wiley-VCH GmbH, 2024, roč.~20, č.~14, s.~1-9. ISSN~1613-6810. Dostupné z: https://doi.org/10.1002/smll.202307684.

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