Low-cost carbon-based sorbents for the removal of
pharmaceuticals from wastewaters

J 2024

Low-cost carbon-based sorbents for the removal of pharmaceuticals from wastewaters

IMREOVÁ, Zuzana, Andrea VOJS STAŇOVÁ, František ZAŽÍMAL, Stanislava DEBNÁROVÁ, Lukáš VRÁNA et. al.

Základní údaje

Originální název

Low-cost carbon-based sorbents for the removal of pharmaceuticals from wastewaters

Autoři

IMREOVÁ, Zuzana, Andrea VOJS STAŇOVÁ, František ZAŽÍMAL (203 Česká republika, domácí), Stanislava DEBNÁROVÁ (703 Slovensko, domácí), Lukáš VRÁNA (203 Česká republika, domácí), Nina PETROVIČOVÁ, Alexandra TULIPÁNOVÁ, Tomáš LUKÁČ, Daniel VÉGH, Aleš STÝSKALÍK (203 Česká republika, domácí), Tomáš MACKUĽAK a Tomáš HOMOLA (703 Slovensko, garant, domácí)

Vydání

Journal of Water Process Engineering, Elsevier Ltd, 2024, 2214-7144

Další údaje

Jazyk

angličtina

Typ výsledku

Článek v odborném periodiku

Obor

10305 Fluids and plasma physics

Stát vydavatele

Nizozemské království

Utajení

není předmětem státního či obchodního tajemství

Odkazy

URL

Impakt faktor

Impact factor: 7.000 v roce 2022

Organizační jednotka

Přírodovědecká fakulta

DOI

http://dx.doi.org/10.1016/j.jwpe.2024.105181

UT WoS

001227706300001

Klíčová slova anglicky

Wastewater treatment; Pharmaceuticals; Adsorption; Biochar; Graphitic carbon nitride; X-ray photoelectron spectroscopy (XPS)

Štítky

rivok

Příznaky

Mezinárodní význam, Recenzováno

Změněno: 4. 6. 2024 11:20, Mgr. Marie Šípková, DiS.

Anotace

V originále

The increasing occurrence of pharmaceuticals in wastewater poses environmental and health risks. This study focuses on developing and evaluating cost-effective carbon sorbents, specifically biochar and graphitic carbon nitride, for efficiently removing pharmaceutical contaminants from 2023 wastewater samples from a treatment plant serving around 300,000 people. The adsorptive capabilities of these materials were evaluated using liquid chromatography-tandem mass spectrometry (LC-MS/MS) for the quantification of pharmaceuticals and their metabolites. Characterization of these sorbents encompassed analyses of their physical and chemical attributes, such as specific surface area, porosity, and functional group composition, thereby aiding in elucidating their adsorption mechanisms. The study revealed a direct correlation between sorption efficacy and specific surface area. The most effective sorbent was identified as a biochar blend, comprising both commercially available corn and wood-derived biochar and laboratory-synthesized biochar from conifer cones. Notably, this sorbent demonstrated exceptional efficiency in reducing concentrations of major pharmaceutical pollutants. The levels of clarithromycin were reduced from 320 ng/L to 30 ng/L, trimethoprim from 160 ng/L to 8.6 ng/L, telmisartan from 1600 ng/L to 66 ng/L, and diclofenac from 880 ng/L to 260 ng/L.

Návaznosti

LM2023039, projekt VaV

Název: Centrum výzkumu a vývoje plazmatu a nanotechnologických povrchových úprav

Investor: Ministerstvo školství, mládeže a tělovýchovy ČR, R&D centre for plasma and nanotechnology surface modifications

90238, velká výzkumná infrastruktura

Název: CENAKVA II

90251, velká výzkumná infrastruktura

Název: CzechNanoLab II

Citovat

IMREOVÁ, Zuzana, Andrea VOJS STAŇOVÁ, František ZAŽÍMAL, Stanislava DEBNÁROVÁ, Lukáš VRÁNA, Nina PETROVIČOVÁ, Alexandra TULIPÁNOVÁ, Tomáš LUKÁČ, Daniel VÉGH, Aleš STÝSKALÍK, Tomáš MACKUĽAK a Tomáš HOMOLA. Low-cost carbon-based sorbents for the removal of pharmaceuticals from wastewaters. Journal of Water Process Engineering. Elsevier Ltd, 2024, roč. 61, May 2024, s. 1-13. ISSN 2214-7144. Dostupné z: https://dx.doi.org/10.1016/j.jwpe.2024.105181.

@article{2392941,
   author = {Imreová, Zuzana and Vojs Staňová, Andrea and Zažímal, František and Debnárová, Stanislava and Vrána, Lukáš and Petrovičová, Nina and Tulipánová, Alexandra and Lukáč, Tomáš and Végh, Daniel and Stýskalík, Aleš and Mackuľak, Tomáš and Homola, Tomáš},
   article_number = {May 2024},
   doi = {http://dx.doi.org/10.1016/j.jwpe.2024.105181},
   keywords = {Wastewater treatment; Pharmaceuticals; Adsorption; Biochar; Graphitic carbon nitride; X-ray photoelectron spectroscopy (XPS)},
   language = {eng},
   issn = {2214-7144},
   journal = {Journal of Water Process Engineering},
   title = {Low-cost carbon-based sorbents for the removal of pharmaceuticals from wastewaters},
   url = {https://www.sciencedirect.com/science/article/pii/S2214714424004136},
   volume = {61},
   year = {2024}
}

TY  - JOUR
ID  - 2392941
AU  - Imreová, Zuzana - Vojs Staňová, Andrea - Zažímal, František - Debnárová, Stanislava - Vrána, Lukáš - Petrovičová, Nina - Tulipánová, Alexandra - Lukáč, Tomáš - Végh, Daniel - Stýskalík, Aleš - Mackuľak, Tomáš - Homola, Tomáš
PY  - 2024
TI  - Low-cost carbon-based sorbents for the removal of pharmaceuticals from wastewaters
JF  - Journal of Water Process Engineering
VL  - 61
IS  - May 2024
SP  - 1-13
EP  - 1-13
PB  - Elsevier Ltd
SN  - 22147144
KW  - Wastewater treatment
KW  - Pharmaceuticals
KW  - Adsorption
KW  - Biochar
KW  - Graphitic carbon nitride
KW  - X-ray photoelectron spectroscopy (XPS)
UR  - https://www.sciencedirect.com/science/article/pii/S2214714424004136
N2  - The increasing occurrence of pharmaceuticals in wastewater poses environmental and health risks. This study focuses on developing and evaluating cost-effective carbon sorbents, specifically biochar and graphitic carbon nitride, for efficiently removing pharmaceutical contaminants from 2023 wastewater samples from a treatment plant serving around 300,000 people. The adsorptive capabilities of these materials were evaluated using liquid chromatography-tandem mass spectrometry (LC-MS/MS) for the quantification of pharmaceuticals and their metabolites. Characterization of these sorbents encompassed analyses of their physical and chemical attributes, such as specific surface area, porosity, and functional group composition, thereby aiding in elucidating their adsorption mechanisms. The study revealed a direct correlation between sorption efficacy and specific surface area. The most effective sorbent was identified as a biochar blend, comprising both commercially available corn and wood-derived biochar and laboratory-synthesized biochar from conifer cones. Notably, this sorbent demonstrated exceptional efficiency in reducing concentrations of major pharmaceutical pollutants. The levels of clarithromycin were reduced from 320 ng/L to 30 ng/L, trimethoprim from 160 ng/L to 8.6 ng/L, telmisartan from 1600 ng/L to 66 ng/L, and diclofenac from 880 ng/L to 260 ng/L.
ER  -

IMREOVÁ, Zuzana, Andrea VOJS STAŇOVÁ, František ZAŽÍMAL, Stanislava DEBNÁROVÁ, Lukáš VRÁNA, Nina PETROVIČOVÁ, Alexandra TULIPÁNOVÁ, Tomáš LUKÁČ, Daniel VÉGH, Aleš STÝSKALÍK, Tomáš MACKUĽAK a Tomáš HOMOLA. Low-cost carbon-based sorbents for the removal of pharmaceuticals from wastewaters. \textit{Journal of Water Process Engineering}. Elsevier Ltd, 2024, roč.~61, May 2024, s.~1-13. ISSN~2214-7144. Dostupné z: https://dx.doi.org/10.1016/j.jwpe.2024.105181.

Podrobný výpis o publikaci